Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134302386
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 16, Problem 29E
Interpretation Introduction
Interpretation:
To describe the fuel cell along with the equations for the anode and the cathode in a hydrogen-oxygen fuel cell.
Concept introduction:
The buses run in some places of the world are powered by the fuel cells. The fuel cell technology depends on the capability of some of the elements to gain electrons. The hydrogen-oxygen fuel cell is the most common type of fuel cell.
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Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Acid Catalyzed Aromatization of Carvone:
1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown.
H2SO4
HO-
H₂O
2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra?
3. Why does it not matter which enantiomer of carvone is used for this reaction?
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material?
What other impurities are present in your product and how do you know?
Assign this H NMR
Chapter 16 Solutions
Introductory Chemistry (6th Edition)
Ch. 16 - Q1. Which substance is being oxidized in the...Ch. 16 - What always happens to an oxidizing agent during a...Ch. 16 - Q3. What is the oxidation state of carbon in...Ch. 16 - Q4. In which compound does phosphorus have the...Ch. 16 - Sodium reacts with water according to the...Ch. 16 - Q6. How many electrons are exchanged when this...Ch. 16 - Prob. 7SAQCh. 16 - Prob. 8SAQCh. 16 - Prob. 9SAQCh. 16 - Prob. 10SAQ
Ch. 16 - 1. What is a fuel-cell electric vehicle?
Ch. 16 - Prob. 2ECh. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - 20. Any half-reaction in the activity series will...Ch. 16 - How can you use the activity series to determine...Ch. 16 - What is electrical current? Explain how a simple...Ch. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - 38. For each of the reactions in Problem 36,...Ch. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - 45. Assign an oxidation state to each element or...Ch. 16 - Prob. 46ECh. 16 - 47. Assign an oxidation state to each atom in each...Ch. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Assign an oxidation state to each element in each...Ch. 16 - 59. Use oxidation states to identify the oxidizing...Ch. 16 - Prob. 60ECh. 16 - 61. Balance each redox reaction using the...Ch. 16 - Prob. 62ECh. 16 - Classify each half-reaction occurring in acidic...Ch. 16 - 64. Classify each half-reaction occurring in...Ch. 16 - Use the half-reaction method to balance each redox...Ch. 16 - Use the half-reaction method to balance each redox...Ch. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Balance each redox reaction occurring in basic...Ch. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - 77. Determine whether each redox occurs...Ch. 16 - Prob. 78ECh. 16 - 79. Suppose you wanted to cause ions to come out...Ch. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - 82. Which metal in the activity series is oxidized...Ch. 16 - Prob. 83ECh. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - 86. Make a sketch of an electrochemical cell with...Ch. 16 - Prob. 87ECh. 16 - The following reaction occurs at the cathode of an...Ch. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - Prob. 91ECh. 16 - Make a sketch of an electrolysis cell that could...Ch. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - 95. Determine whether each reaction is a redox...Ch. 16 - Prob. 96ECh. 16 - Consider the unbalanced redox reaction....Ch. 16 - Prob. 98ECh. 16 - Prob. 99ECh. 16 - Prob. 100ECh. 16 - Prob. 101ECh. 16 - 102. A 1.012-mL sample of a salt containing is...Ch. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - Determine whether HI can dissolve each metal...Ch. 16 - 106. Determine whether HI can dissolve each metal...Ch. 16 - Prob. 107ECh. 16 - 108. One graduated cylinder containing 1.00 mL of...Ch. 16 - Prob. 109ECh. 16 - Prob. 110ECh. 16 - Prob. 111ECh. 16 - Prob. 112ECh. 16 - 113. Consider the molecular view of an...Ch. 16 - Which of your group’s cells do you think would...Ch. 16 - Data Interpretation and Analysis
116. We can use...
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- Please complete these blanks need that asaparrow_forwardNitration of Methyl Benzoate: 1. Predict the major product for the reaction below AND provide a mechanism. Include ALL resonance structures for the intermediate. C(CH3)3 NO₂* ? 2. Assuming the stoichiometry is 1:1 for the reaction above, what volume of concentrated nitric acid would be required to mononitrate 0.50 grams of the compound above? What product(s) might you expect if you nitrated phenol instead of methyl benzoate? Explain your reasoning. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSodium Borohydride Reduction (continued on the next page): 1. Draw the product of each of the reactions below and give the formula mass to the nearest whole number. ? (1) NaBH (2) acid (1) NaBD4 (2) acid ? 2. In mass spectra, alcohols typically break as shown in equation 8 in chapter 11 (refer to your lab manual). The larger group is generally lost and this gives rise to the base peak in the mass spectrum. For the products of each of the reactions in question # 1, draw the ion corresponding to the base peak for that product and give its mass to charge ratio (m/z). 3. Given the reaction below, calculate how many mg of 1-phenyl-1-butanol that can be produced using 31 mg NaBH4 and an excess of butyrophenone. 4. + NaBH4 OH (after workup with dilute HCI) What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
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- 2. Identify the reagents you would need to achieve the following. You may need to consider using a protecting group. HO 1. 2. 3. 4. 5. OH Br HOarrow_forwardBeF2 exists as a linear molecule. Which kind of hybrid orbitals does Be use in this compound? Use Orbital Diagrams to show how the orbitals are formed. (6)arrow_forwardPlease answer the questions and provide detailed explanations as well as a drawing to show the signals in the molecule.arrow_forward
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