Physical state at room temperature for unbranched saturated monocarboxylic acid that contains four carbon atoms has to be indicated. Concept Introduction: Physical property of carboxylic acid is decided by the carbon chain and the functional group . Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Question

H3C H C=C CH3 H m-chloroperoxybenzoic acid CH2Cl2, rt C-C--. H3CH2CC H H3C CH3 Cl₂ H₂O NaOH H₂O D. S- E. CH3 H₂O₂, H₂O It CH₂O Na + CHI F. HI, H₂O heat G. 4 OH CH3CHCH3 + ICH2CH3 1. NaH (CH3)3COH (CH3)3 COCHCH2CH3 2. CH3

Answer 1

Question

Chapter 16, Problem 16.39EP

(a)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(b)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(c)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains five carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(d)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains six carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

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H3C H C=C CH3 H m-chloroperoxybenzoic acid CH2Cl2, rt C-C--. H3CH2CC H H3C CH3 Cl₂ H₂O NaOH H₂O D. S- E. CH3 H₂O₂, H₂O It CH₂O Na + CHI F. HI, H₂O heat G. 4 OH CH3CHCH3 + ICH2CH3 1. NaH (CH3)3COH (CH3)3 COCHCH2CH3 2. CH3

5. Show how the ether below could be prepared from toluene and any other necessary reagents. Show all reagents and all intermediate structures. H3C- H3C- CI OCH2CH3

Given the major organic product(s) of each of the following reactions. If none is predicted, write "N.R." [answer 61 a. b. H3C C. NO₂ CH3CH2CH2Cl AICI 3 1) NaOH CI 2) H3O+ NO₂ 1. SnCl2, H3O+ 2. NaOH 3

Answer 2

Question

Chapter 16, Problem 16.39EP

(a)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(b)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(c)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains five carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(d)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains six carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

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Answer 3

Question

Chapter 16, Problem 16.39EP

(a)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(b)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(c)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains five carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(d)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains six carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

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Answer 4

Question

Chapter 16, Problem 16.39EP

(a)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(b)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(c)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains five carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(d)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains six carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

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Answer 5

Chapter 16, Problem 16.39EP

(a)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(b)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(c)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains five carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

(d)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains six carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Answer 6

Chapter 16, Problem 16.39EP

(a)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Answer 7

Chapter 16, Problem 16.39EP

(a)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains four carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains five carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated monocarboxylic acid that contains five carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains six carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Physical state at room temperature for unbranched saturated dicarboxylic acid that contains six carbon atoms has to be indicated.

Concept Introduction:

Physical property of carboxylic acid is decided by the carbon chain and the functional group. Carboxylic acids are highly polar, as the carboxyl group is more polar. Due to this polar nature, the melting and boiling point are very high. Monocarboxylic acids that are unsubstituted which contains up to nine carbon atoms are present in liquid state. They have very sharp odor. Monocarboxylic acids that have more than ten carbon atoms in an unbranched fashion are waxy solids. They do not have any odor because of low volatility. Similar to this, dicarboxylic acids and aromatic carboxylic acids do not have any odor and they are solids.

Answer 14

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Answer 25

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains that the physical state of carboxylic acid is determined by the carbon chain and the functional group.

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Chapter 16 Solutions