The noncarboxyl functional group that is present in acrylic acid has to be given. Concept Introduction: Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below, If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below, Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid . They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Question

What is the physical state (solid, liquid, or gas) of each of the following carboxylic acids at room temperature? a. Oxalic acid b. Decanoic acid c. Hexanoic acid d. Benzoic acid Classify the two carboxylic acids in each of the following pairs as (A) both dicarboxylic acids, (B) both monocarboxylic acids, or (C) one dicarboxylic and one monocarboxylic acid. 1. Glutaric acid and valeric acid 2. Adipic acid and oxalic acid 3. Caproic acid and formic acid 4. Succinic acid and malonic acid Each of the following acids contains an additional type of functional group besides the carboxyl group. For each acid, specify the non-carboxyl functional group present. 9. Acrylic acid 10. Lactic acid 11. Maleic acid 12. Glycolic acid 13. Fumaric acid 14. Pyruvic acid 15. Malic acid 16. Tartaric acid What type of chemical reaction does carboxylic acid undergo in the following situations? 17. synthesis of methyl salicylate 18. reaction with a strong alkali 19. occurs in aqueous solution 21. release of…

Answer 1

Question

Chapter 16, Problem 16.31EP

(a)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in acrylic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(b)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in lactic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(c)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in maleic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(d)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in glycolic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

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What is the physical state (solid, liquid, or gas) of each of the following carboxylic acids at room temperature? a. Oxalic acid b. Decanoic acid c. Hexanoic acid d. Benzoic acid Classify the two carboxylic acids in each of the following pairs as (A) both dicarboxylic acids, (B) both monocarboxylic acids, or (C) one dicarboxylic and one monocarboxylic acid. 1. Glutaric acid and valeric acid 2. Adipic acid and oxalic acid 3. Caproic acid and formic acid 4. Succinic acid and malonic acid Each of the following acids contains an additional type of functional group besides the carboxyl group. For each acid, specify the non-carboxyl functional group present. 9. Acrylic acid 10. Lactic acid 11. Maleic acid 12. Glycolic acid 13. Fumaric acid 14. Pyruvic acid 15. Malic acid 16. Tartaric acid What type of chemical reaction does carboxylic acid undergo in the following situations? 17. synthesis of methyl salicylate 18. reaction with a strong alkali 19. occurs in aqueous solution 21. release of…

Refer to the structures of carboxylic acid and derivatives. Which of the following statements is TRUE? Compound A is the most reactive. The second most reactive is compound B Compound D is the least reactive Compound E is the most reactive.

Define the structure of a carboxylic acid ?

Answer 2

Question

Chapter 16, Problem 16.31EP

(a)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in acrylic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(b)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in lactic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(c)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in maleic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(d)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in glycolic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

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Answer 3

Question

Chapter 16, Problem 16.31EP

(a)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in acrylic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(b)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in lactic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(c)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in maleic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(d)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in glycolic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

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Answer 4

Question

Chapter 16, Problem 16.31EP

(a)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in acrylic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(b)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in lactic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(c)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in maleic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(d)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in glycolic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

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Answer 5

Chapter 16, Problem 16.31EP

(a)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in acrylic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(b)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in lactic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(c)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in maleic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(d)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in glycolic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Answer 6

Chapter 16, Problem 16.31EP

(a)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in acrylic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Answer 7

Chapter 16, Problem 16.31EP

(a)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in acrylic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in lactic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in lactic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in maleic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in maleic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in glycolic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in glycolic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group. This can be represented as shown below,

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid. They are known as polyfunctional carboxylic acids. These occur naturally also. Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Answer 14

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Answer 25

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains that the noncarboxyl functional group present in acrylic acid is carboncarbon double bond.

Chapter 16 Solutions