(a)
Interpretation:
Condensed structural formula for acetyl chloride has to be drawn.
Concept Introduction:
General structure of acid chloride can be represented as shown below,
The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent
(b)
Interpretation:
Condensed structural formula for 2-methylbutanoyl chloride has to be drawn.
Concept Introduction:
General structure of acid chloride can be represented as shown below,
The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.
(c)
Interpretation:
Condensed structural formula for propionic anhydride has to be drawn.
Concept Introduction:
General structure of acid anhydride can be represented as shown below,
The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R1” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.
(d)
Interpretation:
Condensed structural formula for ethanoic methanoic anhydride has to be drawn.
Concept Introduction:
General structure of acid anhydride can be represented as shown below,
The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R1” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.
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Chapter 16 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- Part I. Problem solving. Include all necessary calculations 13 provide plots and graphs. Complexation wl diphenyl carbazide (OPC) in acidic media is another type of sensitive photometric method used for the analysis of aqueous. hexavalent chromium. At 540nm the cherry-red complex as a result of DPC reaction w/ chromium can be photometrically measured. at this wavelength. - a 25mL The UV-vis analysis for the determination of nexavalent chromium in ground water sample is given below. The experiment was based on external calibration method w/ each measurement sample prepared are as follows lab sample analysis contained the standard 100 ppb croy cor groundwater sample, volumes used as indicated below), 12.50 mL of 0.02 M H2Soy and 5.50 ml of 100 ppm DPC (wi water to adjust final volume to 25-ml). The main stripping method was square wave voltammetry, following the conditions set in the main ASV experiment. Standard 100 Volumetric Groundwater H2SO4 0.20 M, flask Sample, mL ppb CrO4*, 100…arrow_forwardplease helparrow_forwardPredict the products of the following reactions. Draw mechanism arrows for each step for a, b, and c. a.) HBr b.) HI H₂O H2SO4 d.) C12 HO H2SO4 1.) BH3 2.) H2O2, NaOHarrow_forward
- K for the following reaction is 0.11 at constant temperature. If the equilibrium concentration of HCl is 0.5 M, what is the equilibrium concentration of NH3. NH4CI(s) ⇌ NH3(g) + HCI(g)arrow_forwardplease help by Draw the following structures (Lewis or line-angle drawing).arrow_forwardplease helparrow_forward
- Consider the reaction: 2 A (aq) ⇌ B(aq) Given the following KC values and starting with the initial concentration of A = 4.00 M, complete ICE diagram(s)and find the equilibrium concentrations for A and B.A) KC = 4.00B) KC = 200C) KC = 8.00 x10-3arrow_forward5) Consider the reaction: Cl2 (g) + F2 (g) ⟷ 2 ClF (g) KP=? The partial pressure of 203 kPa for Cl2 and a partial pressure of 405 kPa for F2. Upon reaching equilibrium, thepartial pressure of ClF is 180 kPa. Calculate the equilibrium concentrations and then find the value for KP.arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- (9 Pts) In one of the two Rare Earth element rows of the periodic table, identify an exception tothe general ionization energy (IE) trend. For the two elements involved, answer the followingquestions. Be sure to cite sources for all physical data that you use.a. (2 pts) Identify the two elements and write their electronic configurations.b. (2 pts) Based on their configurations, propose a reason for the IE trend exception.c. (5 pts) Calculate effective nuclear charges for the last electron in each element and theAllred-Rochow electronegativity values for the two elements. Can any of these valuesexplain the IE trend exception? Explain how (not) – include a description of how IErelates to electronegativity.arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardDon't use AIarrow_forward
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