
(a)
Interpretation:
Each prduct as a lewis acid or a lewis base is to be stated.
Concept Introduction:
A Lewis acid is a substance that contains an empty orbital which is capable of accepting an electron pair. A Lewis base is a substance that has a filled orbital containing an electron pair which is not involved in bonding but may form a dative bond with a lewis acid.
(a)

Answer to Problem 114IL
On the product side,
Explanation of Solution
A lewis acid can accept a pair of electrons from a lewis base. The boron in
Methyl ether
On the product side,
(b)
Interpretation:
Total pressure at equilibrium, partial pressure of lewis acid and lewis base has to be calculated.
Concept Introduction:
A Lewis acid is a substance that contains an empty orbital which is capable of accepting an electron pair. A Lewis base is a substance that has a filled orbital containing an electron pair which is not involved in bonding but may form a dative bond with a lewis acid.
Ideal gas equation,
Here,
(b)

Answer to Problem 114IL
The total pressure in the flask at Equilibrium is
Explanation of Solution
From ideal gas equation,
Here,
An equilibrium constant
An equilibrium constant
Where, partial pressure of gases is,
Where
Given:
The mass of boron ether complex is
The volume of the flask is
The temperature is
The gas constant
Molecular weight of complex is
Total number of moles is equal to the mass of the complex divided by the molecular weight of the complex,
Total pressure at equilibrium is calculated from equation
Set up an ICE table for the chemical reaction given in equation
Total number moles at Equilibrium is equal to
Substitute these values in equation
Now substitute the value of
Similarly,
The total pressure in the flask at Equilibrium is
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Chapter 16 Solutions
Chemistry & Chemical Reactivity
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