Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
7th Edition
ISBN: 9781305081086
Author: STOKER, H. Stephen
Publisher: Brooks Cole
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Question
Chapter 15, Problem 15.102EP
(a)
Interpretation Introduction
Interpretation:
The acetal carbon atom in the given structure has to be identified.
Concept Introduction:
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Acetal is formed when the formed hemiacetal reacts with further alcohol molecule so that the hydroxyl group in the hemiacetal is converted into alkoxy group. This can be shown as given below,
Acetal contains two alkoxy groups substituted on the same carbon atom. This carbon atom is known as acetal carbon atom.
(b)
Interpretation Introduction
Interpretation:
The acetal carbon atom in the given structure has to be identified.
Concept Introduction:
Aldehydes contain a carbonyl group that is bonded to a hydrogen atom and a carbon atom. Ketones are compounds that contain a carbonyl group bonded to two carbon atoms. Aldehydes and ketones undergo addition reaction across the carbonyl group.
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Acetal is formed when the formed hemiacetal reacts with further alcohol molecule so that the hydroxyl group in the hemiacetal is converted into alkoxy group. This can be shown as given below,
Acetal contains two alkoxy groups substituted on the same carbon atom. This carbon atom is known as acetal carbon atom.
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Chapter 15 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
Ch. 15.1 - Prob. 1QQCh. 15.1 - Prob. 2QQCh. 15.2 - Prob. 1QQCh. 15.2 - Prob. 2QQCh. 15.2 - Prob. 3QQCh. 15.3 - Prob. 1QQCh. 15.3 - Prob. 2QQCh. 15.3 - Prob. 3QQCh. 15.4 - Prob. 1QQCh. 15.4 - Prob. 2QQ
Ch. 15.4 - Prob. 3QQCh. 15.4 - Prob. 4QQCh. 15.4 - Prob. 5QQCh. 15.5 - Prob. 1QQCh. 15.5 - Prob. 2QQCh. 15.5 - Prob. 3QQCh. 15.5 - Prob. 4QQCh. 15.5 - Prob. 5QQCh. 15.6 - Prob. 1QQCh. 15.6 - Prob. 2QQCh. 15.6 - Prob. 3QQCh. 15.7 - Prob. 1QQCh. 15.7 - Prob. 2QQCh. 15.8 - Prob. 1QQCh. 15.8 - Prob. 2QQCh. 15.9 - Prob. 1QQCh. 15.9 - Prob. 2QQCh. 15.10 - Prob. 1QQCh. 15.10 - Prob. 2QQCh. 15.10 - Prob. 3QQCh. 15.10 - Prob. 4QQCh. 15.11 - Prob. 1QQCh. 15.11 - Prob. 2QQCh. 15.11 - Prob. 3QQCh. 15.11 - Prob. 4QQCh. 15.11 - Prob. 5QQCh. 15.12 - Prob. 1QQCh. 15.12 - Prob. 2QQCh. 15 - Prob. 15.1EPCh. 15 - Prob. 15.2EPCh. 15 - Prob. 15.3EPCh. 15 - In terms of polarity, which carbonyl group atom...Ch. 15 - Prob. 15.5EPCh. 15 - What is the geometrical arrangement for the atoms...Ch. 15 - Prob. 15.7EPCh. 15 - Prob. 15.8EPCh. 15 - Prob. 15.9EPCh. 15 - Prob. 15.10EPCh. 15 - Prob. 15.11EPCh. 15 - Classify each of the following structures as an...Ch. 15 - Prob. 15.13EPCh. 15 - Prob. 15.14EPCh. 15 - Prob. 15.15EPCh. 15 - Prob. 15.16EPCh. 15 - Prob. 15.17EPCh. 15 - Prob. 15.18EPCh. 15 - Prob. 15.19EPCh. 15 - Prob. 15.20EPCh. 15 - Prob. 15.21EPCh. 15 - Prob. 15.22EPCh. 15 - Prob. 15.23EPCh. 15 - Prob. 15.24EPCh. 15 - Prob. 15.25EPCh. 15 - Prob. 15.26EPCh. 15 - Prob. 15.27EPCh. 15 - Prob. 15.28EPCh. 15 - Prob. 15.29EPCh. 15 - Prob. 15.30EPCh. 15 - Prob. 15.31EPCh. 15 - Prob. 15.32EPCh. 15 - Prob. 15.33EPCh. 15 - Prob. 15.34EPCh. 15 - Prob. 15.35EPCh. 15 - Prob. 15.36EPCh. 15 - Prob. 15.37EPCh. 15 - Prob. 15.38EPCh. 15 - Prob. 15.39EPCh. 15 - Prob. 15.40EPCh. 15 - Draw a structural formula for each of the...Ch. 15 - Prob. 15.42EPCh. 15 - Prob. 15.43EPCh. 15 - Prob. 15.44EPCh. 15 - Prob. 15.45EPCh. 15 - Prob. 15.46EPCh. 15 - Prob. 15.47EPCh. 15 - Prob. 15.48EPCh. 15 - Prob. 15.49EPCh. 15 - Prob. 15.50EPCh. 15 - Prob. 15.51EPCh. 15 - Prob. 15.52EPCh. 15 - Prob. 15.53EPCh. 15 - Prob. 15.54EPCh. 15 - Prob. 15.55EPCh. 15 - Prob. 15.56EPCh. 15 - Prob. 15.57EPCh. 15 - Prob. 15.58EPCh. 15 - Prob. 15.59EPCh. 15 - Prob. 15.60EPCh. 15 - Prob. 15.61EPCh. 15 - Prob. 15.62EPCh. 15 - Prob. 15.63EPCh. 15 - Prob. 15.64EPCh. 15 - Prob. 15.65EPCh. 15 - Prob. 15.66EPCh. 15 - Prob. 15.67EPCh. 15 - Which member in each of the following pairs of...Ch. 15 - Prob. 15.69EPCh. 15 - Prob. 15.70EPCh. 15 - Prob. 15.71EPCh. 15 - Prob. 15.72EPCh. 15 - Prob. 15.73EPCh. 15 - Prob. 15.74EPCh. 15 - Prob. 15.75EPCh. 15 - Prob. 15.76EPCh. 15 - Prob. 15.77EPCh. 15 - Prob. 15.78EPCh. 15 - Prob. 15.79EPCh. 15 - What is the chemical formula of the inorganic...Ch. 15 - Prob. 15.81EPCh. 15 - Which of the following compounds would react with...Ch. 15 - Prob. 15.83EPCh. 15 - Prob. 15.84EPCh. 15 - Which of the three compounds pentanal,...Ch. 15 - Prob. 15.86EPCh. 15 - Prob. 15.87EPCh. 15 - Prob. 15.88EPCh. 15 - Prob. 15.89EPCh. 15 - Prob. 15.90EPCh. 15 - Prob. 15.91EPCh. 15 - Prob. 15.92EPCh. 15 - Which carbon atom is the hemiacetal carbon atom in...Ch. 15 - Prob. 15.94EPCh. 15 - Prob. 15.95EPCh. 15 - Prob. 15.96EPCh. 15 - Prob. 15.97EPCh. 15 - Prob. 15.98EPCh. 15 - Prob. 15.99EPCh. 15 - Prob. 15.100EPCh. 15 - Prob. 15.101EPCh. 15 - Prob. 15.102EPCh. 15 - Prob. 15.103EPCh. 15 - Prob. 15.104EPCh. 15 - Prob. 15.105EPCh. 15 - Prob. 15.106EPCh. 15 - Prob. 15.107EPCh. 15 - Prob. 15.108EPCh. 15 - Prob. 15.109EPCh. 15 - Prob. 15.110EPCh. 15 - Prob. 15.111EPCh. 15 - Prob. 15.112EPCh. 15 - Prob. 15.113EPCh. 15 - Prob. 15.114EPCh. 15 - Prob. 15.115EPCh. 15 - Prob. 15.116EPCh. 15 - Prob. 15.117EPCh. 15 - Prob. 15.118EP
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