Principles of General, Organic, Biological Chemistry
Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Concept explainers

Carbohydrates
Carbohydrates are the organic compounds that are obtained in foods and living matters in the shape of sugars, cellulose, and starch. The general formula of carbohydrates is Cn(H2O)2. The ratio of H and O present in carbohydrates is identical to water.
Starch
Starch is a polysaccharide carbohydrate that belongs to the category of polysaccharide carbohydrates.
Mutarotation
The rotation of a particular structure of the chiral compound because of the epimerization is called mutarotation. It is the repercussion of the ring chain tautomerism. In terms of glucose, this can be defined as the modification in the equilibrium of th…
L Sugar
A chemical compound that is represented with a molecular formula C6H12O6 is called L-(-) sugar. At the carbon’s 5th position, the hydroxyl group is placed to the compound’s left and therefore the sugar is represented as L(-)-sugar. It is capable of rotat…
Question
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Chapter 14.2, Problem 14.9P

(a)

Interpretation Introduction

Interpretation:

Fischer projection for D-galactose has to be drawn.

Concept Introduction:

Fischer projection formula simply uses cross for representing tetrahedral carbon atom.  The carbon atom that is present in the intersection point in cross.  The horizontal bonds means they are coming forward and they are present on wedge bond.  The vertical bonds means they are pointing away and they are present on dashed lines.

(b)

Interpretation Introduction

Interpretation:

Fischer projection for the enantiomer of D-galactose has to be drawn.

Concept Introduction:

Enantiomers are two stereoisomers of a compound that rotate the plane polarized light exactly opposite.  The configuration present in the enantiomers will be exactly opposite to each other.

Fischer projection formula simply uses cross for representing tetrahedral carbon atom.  The carbon atom that is present in the intersection point in cross.  The horizontal bonds means they are coming forward and they are present on wedge bond.  The vertical bonds means they are pointing away and they are present on dashed lines.

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Chapter 14 Solutions

Principles of General, Organic, Biological Chemistry

Ch. 14.1 - Draw a Lewis structure for glucose that clearly...Ch. 14.2 - Prob. 14.2PCh. 14.2 - Prob. 14.3PCh. 14.2 - Prob. 14.4PCh. 14.2 - Rank the following compounds in order of...Ch. 14.2 - Prob. 14.6PCh. 14.2 - Prob. 14.7PCh. 14.2 - Prob. 14.8PCh. 14.2 - Prob. 14.9PCh. 14.3 - Prob. 14.10P
Ch. 14.3 - Prob. 14.11PCh. 14.4 - Prob. 14.12PCh. 14.4 - Prob. 14.13PCh. 14.4 - Prob. 14.14PCh. 14.4 - Prob. 14.15PCh. 14.5 - Prob. 14.16PCh. 14.5 - Prob. 14.17PCh. 14.5 - Prob. 14.18PCh. 14.5 - Prob. 14.19PCh. 14.6 - Prob. 14.20PCh. 14 - Prob. 14.21UKCCh. 14 - Prob. 14.22UKCCh. 14 - Prob. 14.23UKCCh. 14 - Prob. 14.24UKCCh. 14 - Prob. 14.25UKCCh. 14 - Prob. 14.26UKCCh. 14 - Prob. 14.27UKCCh. 14 - Prob. 14.28UKCCh. 14 - Prob. 14.29UKCCh. 14 - Prob. 14.30UKCCh. 14 - Prob. 14.31APCh. 14 - Prob. 14.32APCh. 14 - Prob. 14.33APCh. 14 - Prob. 14.34APCh. 14 - Prob. 14.35APCh. 14 - Prob. 14.36APCh. 14 - Prob. 14.37APCh. 14 - Prob. 14.38APCh. 14 - Prob. 14.39APCh. 14 - Prob. 14.40APCh. 14 - Prob. 14.41APCh. 14 - Prob. 14.42APCh. 14 - Prob. 14.43APCh. 14 - Prob. 14.44APCh. 14 - Prob. 14.45APCh. 14 - Prob. 14.46APCh. 14 - Prob. 14.47APCh. 14 - Prob. 14.48APCh. 14 - Prob. 14.49APCh. 14 - Prob. 14.50APCh. 14 - Prob. 14.51APCh. 14 - Prob. 14.52APCh. 14 - Prob. 14.53APCh. 14 - Prob. 14.54APCh. 14 - Prob. 14.55APCh. 14 - Prob. 14.56APCh. 14 - Prob. 14.57APCh. 14 - Prob. 14.58APCh. 14 - Prob. 14.59APCh. 14 - Prob. 14.60APCh. 14 - Prob. 14.61APCh. 14 - Prob. 14.62APCh. 14 - Prob. 14.63APCh. 14 - Prob. 14.64APCh. 14 - Prob. 14.65APCh. 14 - Prob. 14.66APCh. 14 - Prob. 14.67APCh. 14 - Prob. 14.68APCh. 14 - Prob. 14.69APCh. 14 - Prob. 14.70APCh. 14 - Prob. 14.71APCh. 14 - Prob. 14.72APCh. 14 - Prob. 14.73CPCh. 14 - Prob. 14.74CP
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