Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 1.4, Problem 4LTS
Interpretation Introduction

Interpretation: For the given molecule the presence of formal charge of nitrogen atom should be identified.

Concept Introduction: Formal charge of an atom can be assigned by assuming the electrons which does not correspond to the valence electrons of the respective atom.

Valence electrons represent the electrons present in the outermost shell of an atom.

Non-bonded electrons are the electrons that do not participate in bonding. These electrons are also termed as lone pair of electrons.

Each atom has a specific number of valence electrons.  If the valence electrons in that atom are reduced by one number, it gets positive charge.  If the valence electrons in that atom are increased by one number, it gets negative charge.

Formal charge of an atom can be identified by drawing the molecules in Lewis structures.

The Lewis structure of small molecules can be drawn by combining the Lewis dot structures of the atoms involved in the formation of that compound.

Formal charge of an atom can be calculated by using the formula given below.

Formalcharge(FC)=[numberofvalenceelectronsonatom]-[nonbondedelectrons+numberofbonds]

To find: Get the formal charge of nitrogen atom in the given molecule

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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