Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 1.4, Problem 14ATS

 (a)

Interpretation Introduction

Interpretation: For the given set of ions the presence of formal charge of atom should be identified.

Concept Introduction: Formal charge of an atom can be assigned by assuming the electrons which does not correspond to the valence electrons of the respective atom.

Valence electrons represent the electrons present in the outermost shell of an atom.

Non-bonded electrons are the electrons that do not participate in bonding. These electrons are also termed as lone pair of electrons.

Each atom has a specific number of valence electrons.  If the valence electrons in that atom are reduced by one number, it gets positive charge.  If the valence electrons in that atom are increased by one number, it gets negative charge.

Formal charge of an atom can be identified by drawing the molecules in Lewis structures.

The Lewis structure of small molecules can be drawn by combining the Lewis dot structures of the atoms involved in the formation of that compound.

Formal charge of an atom can be calculated by using the formula given below.

Formalcharge(FC)=[numberofvalenceelectronsonatom]-[nonbondedelectrons+numberofbonds]

To find: Establish the total number of valence electrons for each atom in the given molecule (a)

(b)

Interpretation Introduction

Interpretation: For the given set of ions the presence of formal charge of atom should be identified.

Concept Introduction: Formal charge of an atom can be assigned by assuming the electrons which does not correspond to the valence electrons of the respective atom.

Valence electrons represent the electrons present in the outermost shell of an atom.

Non-bonded electrons are the electrons that do not participate in bonding. These electrons are also termed as lone pair of electrons.

Each atom has a specific number of valence electrons.  If the valence electrons in that atom are reduced by one number, it gets positive charge.  If the valence electrons in that atom are increased by one number, it gets negative charge.

Formal charge of an atom can be identified by drawing the molecules in Lewis structures.

The Lewis structure of small molecules can be drawn by combining the Lewis dot structures of the atoms involved in the formation of that compound.

Formal charge of an atom can be calculated by using the formula given below.

Formalcharge(FC)=[numberofvalenceelectronsonatom]-[nonbondedelectrons+numberofbonds]

To find: Establish the total number of valence electrons for each atom in the given molecule (b)

(c)

Interpretation Introduction

Interpretation: For the given set of ions the presence of formal charge of atom should be identified.

Concept Introduction: Formal charge of an atom can be assigned by assuming the electrons which does not correspond to the valence electrons of the respective atom.

Valence electrons represent the electrons present in the outermost shell of an atom.

Non-bonded electrons are the electrons that do not participate in bonding. These electrons are also termed as lone pair of electrons.

Each atom has a specific number of valence electrons.  If the valence electrons in that atom are reduced by one number, it gets positive charge.  If the valence electrons in that atom are increased by one number, it gets negative charge.

Formal charge of an atom can be identified by drawing the molecules in Lewis structures.

The Lewis structure of small molecules can be drawn by combining the Lewis dot structures of the atoms involved in the formation of that compound.

Formal charge of an atom can be calculated by using the formula given below.

Formalcharge(FC)=[numberofvalenceelectronsonatom]-[nonbondedelectrons+numberofbonds]

To find: Establish the total number of valence electrons for each atom in the given molecule (c)

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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…
Please draw, not just describe!
can you draw each step on a piece of a paper please this is very confusing to me

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Organic Chemistry, Binder Ready Version

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