(a) Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified. Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 1

Question

Chapter 14, Problem 14.7P

Interpretation Introduction

(a)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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[Review Topics] [References] The chemical environment of protons can be deduced from their chemical shifts. What are the relative chemical shifts of the protons at the labeled positions? [Protons that are highly shielded have low delta (chemical shift) values.] 1) r The proton with the lowest delta value (the most shielded) is The proton with the highest delta value (the most deshielded) is 2) The proton with the lowest delta value (the most shielded) is The proton with the highest delta value (the most deshielded) is Submit Answer Retry Entire Group 9 more group attempts remaining

Answer 2

Question

Chapter 14, Problem 14.7P

Interpretation Introduction

(a)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 3

Question

Chapter 14, Problem 14.7P

Interpretation Introduction

(a)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 4

Question

Chapter 14, Problem 14.7P

Interpretation Introduction

(a)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 14.7P

Interpretation Introduction

(a)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 6

Chapter 14, Problem 14.7P

Interpretation Introduction

(a)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 7

Chapter 14, Problem 14.7P

Interpretation Introduction

(a)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction:

Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14 - Problem 14.1 The NMR spectrum of recorded on a ...Ch. 14 - Prob. 14.2P Ch. 14 - How many 1H NMR signals does each compound show?Ch. 14 - How many 1H NMR signals does each...Ch. 14 - Label the protons in each highlighted CH2 group as...Ch. 14 - How many 1H NMR signals would you expect for each...Ch. 14 - Prob. 14.7P Ch. 14 - For each compound, first label each different type...Ch. 14 - Prob. 14.9P Ch. 14 - Which compound give a 1H NMR spectrum with two...

Solution Summary: The author explains that the protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

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Chapter 14 Solutions