(a) Interpretation: To indicate the carbon atoms in the given molecule absorbs farther downfield. Concept introduction: NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of 1 H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons. The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

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Answer 1

Question

Chapter 14, Problem 14.29P

Interpretation Introduction

(a)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(b)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(c)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(d)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

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Answer 2

Question

Chapter 14, Problem 14.29P

Interpretation Introduction

(a)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(b)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(c)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(d)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Expert Solution & Answer

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Answer 3

Question

Chapter 14, Problem 14.29P

Interpretation Introduction

(a)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(b)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(c)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(d)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 14.29P

Interpretation Introduction

(a)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(b)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(c)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(d)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 14.29P

Interpretation Introduction

(a)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(b)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(c)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Interpretation Introduction

(d)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Answer 6

Chapter 14, Problem 14.29P

Interpretation Introduction

(a)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Answer 7

Chapter 14, Problem 14.29P

Interpretation Introduction

(a)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Answer 8

Interpretation Introduction

(b)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Answer 9

Interpretation Introduction

(b)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Answer 10

Interpretation Introduction

(c)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Answer 11

Interpretation Introduction

(c)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Answer 12

Interpretation Introduction

(d)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Answer 13

Interpretation Introduction

(d)

Interpretation:

To indicate the carbon atoms in the given molecule absorbs farther downfield.

Concept introduction:

NMR is the spectroscopic technique to observe the local magnetic fields around the atomic nuclei. The relative intensity of ¹H NMR signals provide the information about the compound structure. The area under the NMR signal is proportional to the number of absorbing protons.

The height of each step is proportional to the area under the peak, which is in turn proportional to the number of absorbing protons.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 14 - Problem 14.1 The NMR spectrum of recorded on a ...Ch. 14 - Prob. 14.2P Ch. 14 - How many 1H NMR signals does each compound show?Ch. 14 - How many 1H NMR signals does each...Ch. 14 - Label the protons in each highlighted CH2 group as...Ch. 14 - How many 1H NMR signals would you expect for each...Ch. 14 - Prob. 14.7P Ch. 14 - For each compound, first label each different type...Ch. 14 - Prob. 14.9P Ch. 14 - Which compound give a 1H NMR spectrum with two...

Solution Summary: The author explains that the CH 2 group indicated by "a" is close to the oxygen atom in the given structure will be the farther downfield.

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Chapter 14 Solutions