Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Textbook Question
Chapter 14, Problem 14.3E
Identify each of the following compounds as an
a.
d.
b.
e.
c.
f.
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1. Which of the following structural features is possessed by aldehydes but not ketones?
a. At least one hydroxyl group is bonded to the carbonyl carbon atom.
b. At least one hydrogen atom is bonded to the carbonyl carbon atom.
c. The carbonyl carbon atom is bonded to two other carbon atoms.
d. The carbonyl carbon atom is part of a ring structure.
2. What is the IUPAC name of the following compound in the attached photo?
a. 3-chloro-4-nitrobenzoic acid
b. 2-chloro-4-carboxynitrobenzene
c. 2-nitro-5-carboxychlorobenzene
d. 2-chloro-1-nitro-4-benzoic acid
3. Which of the following is the correct bond-line structure for CH3C≡C(CH2)2CH(CH3)2?
a. Structure I
b. Structure II
c. Structure III
d. Structure IV
An acid catalyst in nucleophilic addition of aldehydes and ketones is used for:
Select one:
a. Protonation of carbonyl carbon
b. Making the aldehyde and ketone more susceptible to nucleophiles
c. Increasing the nucleophilicity of the nucleophile
d. To provide a medium for the reaction.
4.
Draw the line structure for the ester that can be formed from the reaction of the acid
anhydride and the alcohol given below.
:0:
:0:
HO
CH3-CH2-C-o-C-CCH2-CH3
acid anhydride
alcohol
Chapter 14 Solutions
Chemistry for Today: General Organic and Biochemistry
Ch. 14 - Prob. 14.1ECh. 14 - Prob. 14.2ECh. 14 - Identify each of the following compounds as an...Ch. 14 - Identify each of the following compounds as an...Ch. 14 - Prob. 14.5ECh. 14 - Prob. 14.6ECh. 14 - Prob. 14.7ECh. 14 - Prob. 14.8ECh. 14 - Draw structural formulas and give IUPAC names for...Ch. 14 - Draw structural formulas and give IUPAC names for...
Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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- Propane, CH3CH2CH3, is a gas at room temperature, whereas propanol, CH3CH2CH2OH, is a liquid. Why the difference?arrow_forwardExplain why propane boils at 42C, whereas ethanal, which has the same molecular weight, boils at 20C.arrow_forwardAssign the IUPAC name to each of the following ethers. Name the smaller alkyl group as the alkoxy group. a. CH3OCH2CH3 b. c. d.arrow_forward
- Give the structure of an alcohol that could be used to prepare each of the following compounds: a. b. c.arrow_forward1. What are the properties of aldehydes and ketones? 2. What will happen to aldehyde and ketones once reduced? Oxidized?arrow_forwardHow do you distinguish each of the following compound using chemical tests.i. Propanone and ethanalii. Phenyl methyl ketone and ethyl phenyl ketonearrow_forward
- Write the complete chemical reaction and correct chemical formula and structure of the following: 1. Autooxidation of benzaldehyde 2. reaction between acetic acid and ethanol 3. reaction between aspirin and sodium hydroxide 4. reaction of acetone with methanolarrow_forward2arrow_forward1. Draw the following compounds a. 2-methyl butanoic acid b. 3-ethyl-2-hexanonearrow_forward
- Which of the following compounds in the simplest ketone? A.) methanone B.) ethanone C.) propanone D.) butanone E.) pentanonearrow_forwardWhat is the physical state (solid, liquid, or gas) of each of the following carboxylic acids at room temperature? a. Oxalic acid b. Decanoic acid c. Hexanoic acid d. Benzoic acid Classify the two carboxylic acids in each of the following pairs as (A) both dicarboxylic acids, (B) both monocarboxylic acids, or (C) one dicarboxylic and one monocarboxylic acid. 1. Glutaric acid and valeric acid 2. Adipic acid and oxalic acid 3. Caproic acid and formic acid 4. Succinic acid and malonic acid Each of the following acids contains an additional type of functional group besides the carboxyl group. For each acid, specify the non-carboxyl functional group present. 9. Acrylic acid 10. Lactic acid 11. Maleic acid 12. Glycolic acid 13. Fumaric acid 14. Pyruvic acid 15. Malic acid 16. Tartaric acid What type of chemical reaction does carboxylic acid undergo in the following situations? 17. synthesis of methyl salicylate 18. reaction with a strong alkali 19. occurs in aqueous solution 21. release of…arrow_forward80 Provide the common name for each of the compounds shown below. Which one is a ketone? group. itrogen a. b. C. 104 em H. H. H.arrow_forward
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