Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Textbook Question
Chapter 14, Problem 14.16E
Explain why propane boils at
the same molecular weight, boils at
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What is the description of a phenol and what is the description of a thiol? Which one contains either an alcohol or ether? and which one has a -SH functional group?
1. Explain the following
- why stearic acid has higher melting point than decanoic acid.
- why benzoic acid has higher melting point than stearic acid.
- why salicylic acid has higher melting point than benzoic acid.
- why octane has a higher melting point than isooctane.
- why 2,2,3,3-tetramethylbutane has the highest melting point among the three isomers of C8H18.
There are two compounds with the formula C3H6, one of which does not have a multiple bond. Draw its structure and explain why it is much less stable than the isomer with the double bond.
Chapter 14 Solutions
Chemistry for Today: General Organic and Biochemistry
Ch. 14 - Prob. 14.1ECh. 14 - Prob. 14.2ECh. 14 - Identify each of the following compounds as an...Ch. 14 - Identify each of the following compounds as an...Ch. 14 - Prob. 14.5ECh. 14 - Prob. 14.6ECh. 14 - Prob. 14.7ECh. 14 - Prob. 14.8ECh. 14 - Draw structural formulas and give IUPAC names for...Ch. 14 - Draw structural formulas and give IUPAC names for...
Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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- Identify these structures.arrow_forwardDraw three isomers of C5H10O2C5H10O2. At least one should contain an an ester, one should contain a carboxylic acid, and one should contain an etherarrow_forwardWhat type of isomers is shown in C2H2Cl2? Explain Do constitutional isomers have the same physical properties? Do geometric isomers have the same physical properties? Explainarrow_forward
- 19.arrow_forwardExplain why, at room temperature, methane (CH4) is a gas but octane (C3H18) is a liquid.arrow_forwardVanillin, C8H8O3, is the active ingredient in vanilla flavoring. It contains a six-membered aromatic ring with an aldehyde group on carbon 1, an alkoxy group (ether) on carbon 3, and a hydroxyl group (alcohol) on carbon 4. Draw the structure of vanillin.arrow_forward
- There are seven structures with the formula C3H7NO in which the O is part of a carbonyl group. Draw the structures and identify the functional groups in each.arrow_forwardIllustrate this phenomenon, compare ethane (CH3CH3), ethylene (CH2=CH2), and acetylene (HC=CH).arrow_forwardThere are 11 structures (ignoring stereoisomerism) with the formula C4H8O that have no carbon branches. Draw the structures and identify the functional groups in each.arrow_forward
- 1-bromo-3-ethylcyclopentane exhibits geometrical isomerism. Draw structures of the two geometrical isomersarrow_forwardOrganic compounds may have characteristic odors as well as other characteristic physical properties. For example, the distinct odor of the seashore at low tide results in part from the presence of dimethyl sulfide (CH3SCH3), a molecule with a similar structure to dimethyl ether (CH3OCH3). Ethanethiol (CH3CH2SH), also called mercaptan, is an isomer of dimethyl sulfide with a much less pleasant odor.The table lists four related compounds and their enthalpies of vaporization (ΔH°vap) in kJ/mol. Compound ΔH°vap (kJ/mol) CH3OCH3 23 CH3SCH3 28 CH3CH2SH 27.5 CH3CH2OH 42 Rank the following compounds in order of increasing strength of their intermolecular forces, given the ΔH°vap listed for each. Place the compound with the strongest intermolecular forces (IMFs) at the top of the list. (Strongest to weaknest). Why is ΔHºvap for CH3SCH3 greater than ΔHºvap for CH3OCH3? A. CH3OCH3 is more polar. B. CH3SCH3 has stronger dipole–dipole attractions. C. CH3OCH3 can form…arrow_forwardExplain why stearic acid has higher melting point than decanoic acid. Explain why salicylic acid has higher melting point than benzoic acid. Explain why benzoic acid has higher melting point than stearic acid. Explain why octane has a higher melting point than isooctane. Explain why 2,2,3,3-tetramethylbutane has the highest melting point among the three isomers of C8H18arrow_forward
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