To draw the structural formula for C 6 acyl CoA associated with the fatty acid β − oxidation pathway. Concept introduction: The β − oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH 2 are also produced in this pathway. The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Question

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

Answer 1

Question

Chapter 14, Problem 14.33EP

(a)

Interpretation Introduction

Interpretation: To draw the structural formula for C6 acyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(b)

Interpretation Introduction

Interpretation: To draw the structural formula for C4 hydroxyacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(c)

Interpretation Introduction

Interpretation: To draw the structural formula for C8 enoyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(d)

Interpretation Introduction

Interpretation: To draw the structural formula for C10 ketoacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

with full details solution please

Answer 2

Question

Chapter 14, Problem 14.33EP

(a)

Interpretation Introduction

Interpretation: To draw the structural formula for C6 acyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(b)

Interpretation Introduction

Interpretation: To draw the structural formula for C4 hydroxyacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(c)

Interpretation Introduction

Interpretation: To draw the structural formula for C8 enoyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(d)

Interpretation Introduction

Interpretation: To draw the structural formula for C10 ketoacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

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Answer 3

Question

Chapter 14, Problem 14.33EP

(a)

Interpretation Introduction

Interpretation: To draw the structural formula for C6 acyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(b)

Interpretation Introduction

Interpretation: To draw the structural formula for C4 hydroxyacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(c)

Interpretation Introduction

Interpretation: To draw the structural formula for C8 enoyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(d)

Interpretation Introduction

Interpretation: To draw the structural formula for C10 ketoacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

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Answer 4

Question

Chapter 14, Problem 14.33EP

(a)

Interpretation Introduction

Interpretation: To draw the structural formula for C6 acyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(b)

Interpretation Introduction

Interpretation: To draw the structural formula for C4 hydroxyacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(c)

Interpretation Introduction

Interpretation: To draw the structural formula for C8 enoyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(d)

Interpretation Introduction

Interpretation: To draw the structural formula for C10 ketoacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

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Answer 5

Chapter 14, Problem 14.33EP

(a)

Interpretation Introduction

Interpretation: To draw the structural formula for C6 acyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(b)

Interpretation Introduction

Interpretation: To draw the structural formula for C4 hydroxyacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(c)

Interpretation Introduction

Interpretation: To draw the structural formula for C8 enoyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

(d)

Interpretation Introduction

Interpretation: To draw the structural formula for C10 ketoacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Answer 6

Chapter 14, Problem 14.33EP

(a)

Interpretation Introduction

Interpretation: To draw the structural formula for C6 acyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Answer 7

Chapter 14, Problem 14.33EP

(a)

Interpretation Introduction

Interpretation: To draw the structural formula for C6 acyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Answer 8

(b)

Interpretation Introduction

Interpretation: To draw the structural formula for C4 hydroxyacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation: To draw the structural formula for C4 hydroxyacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Answer 10

(c)

Interpretation Introduction

Interpretation: To draw the structural formula for C8 enoyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation: To draw the structural formula for C8 enoyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Answer 12

(d)

Interpretation Introduction

Interpretation: To draw the structural formula for C10 ketoacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Answer 13

(d)

Interpretation Introduction

Interpretation: To draw the structural formula for C10 ketoacyl CoA associated with the fatty acid β−oxidation pathway.

Concept introduction: The β−oxidation pathway is defined as a repetitive series of four biochemical reactions in which acyl CoA is degraded to acetyl CoA by the removal of two carbon atoms at a time. NADH and FADH2 are also produced in this pathway.

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

Answer 14

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Ch. 14.1 - Which of the following statements about digestion...Ch. 14.1 - Prob. 2QQ Ch. 14.1 - The major function of bile released during...Ch. 14.1 - The two major products of triacylglycerol...Ch. 14.1 - Prob. 5QQ Ch. 14.2 - Hormone-sensitive lipase needed for...Ch. 14.2 - Prob. 2QQ Ch. 14.2 - Which of the following is not a product of...Ch. 14.3 - Prob. 1QQ Ch. 14.3 - What is the intermediate compound in the two-step...

Solution Summary: The author explains the structure of C_6 acyl CoA, which is a simplified model that represents the arrangement of atoms and bonds.

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Chapter 14 Solutions