EBK ORGANIC AND BIOLOGICAL CHEMISTRY
7th Edition
ISBN: 9780100547742
Author: STOKER
Publisher: YUZU
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Chapter 14, Problem 14.54EP
Interpretation Introduction
Interpretation:
The total yield of ATP molecules that ultimately result from further processing of the products from the second turn of the β-oxidation pathway through the common
Concept introduction:
ATP is the currency of energy. It is a molecule that stores energy for carrying out vital activities in the body. ATP molecules can be generated by mainly three processes, which are glycolysis, the citric acid cycle, and β-oxidation. The β-oxidation process involves breaking down long fatty acid chains that have been converted to acyl CoA chains into smaller fatty acyl CoA chains. The end products of this metabolic process are acetyl CoA, FADH2and NADH.
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Identifying electron-donating and electron-withdrawing effects on benzene
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Inductive Effects
Resonance Effects
Overall Electron-Density
Molecule
CF3
O donating
O donating
O withdrawing
O withdrawing
O no inductive effects
O no resonance effects
electron-rich
electron-deficient
O similar to benzene
CH3
O donating
O withdrawing
O no inductive effects
O donating
O withdrawing
Ono resonance effects
O electron-rich
O electron-deficient
O similar to benzene
Explanation
Check
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* Hint: Think back to Chem 1 solubility rules.
Follow Up Questions for Part B
12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant
for the forward reaction? Explain. (4 pts)
a) Changing the concentration of a reactant or product. (2 pts)
b) Changing the temperature of an exothermic reaction. (2 pts)
of
Draw TWO general chemical equation to prepare Symmetrical and non-Symmetrical ethers
Draw 1 chemical reaction of an ether
Chapter 14 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
Ch. 14.1 - Which of the following statements about digestion...Ch. 14.1 - Prob. 2QQCh. 14.1 - The major function of bile released during...Ch. 14.1 - The two major products of triacylglycerol...Ch. 14.1 - Prob. 5QQCh. 14.2 - Hormone-sensitive lipase needed for...Ch. 14.2 - Prob. 2QQCh. 14.2 - Which of the following is not a product of...Ch. 14.3 - Prob. 1QQCh. 14.3 - What is the intermediate compound in the two-step...
Ch. 14.3 - Prob. 3QQCh. 14.4 - In the oxidation of fatty acids, what two...Ch. 14.4 - Prob. 2QQCh. 14.4 - Prob. 3QQCh. 14.4 - Prob. 4QQCh. 14.4 - Prob. 5QQCh. 14.4 - Prob. 6QQCh. 14.5 - Prob. 1QQCh. 14.5 - Prob. 2QQCh. 14.5 - Prob. 3QQCh. 14.6 - Prob. 1QQCh. 14.6 - Prob. 2QQCh. 14.6 - Prob. 3QQCh. 14.6 - Prob. 4QQCh. 14.6 - Prob. 5QQCh. 14.6 - Prob. 6QQCh. 14.7 - The process of lipogenesis occurs in the a....Ch. 14.7 - Prob. 2QQCh. 14.7 - Prob. 3QQCh. 14.7 - Prob. 4QQCh. 14.7 - The reducing agent needed in the process of...Ch. 14.7 - Prob. 6QQCh. 14.8 - Prob. 1QQCh. 14.8 - Prob. 2QQCh. 14.9 - Prob. 1QQCh. 14.9 - Prob. 2QQCh. 14.9 - Prob. 3QQCh. 14.9 - Prob. 4QQCh. 14.10 - Which of the following substances cannot be...Ch. 14.10 - Prob. 2QQCh. 14.10 - Prob. 3QQCh. 14.11 - Prob. 1QQCh. 14.11 - Which of the following B-vitamin-containing...Ch. 14.11 - Prob. 3QQCh. 14 - Indicate whether each of the following aspects of...Ch. 14 - Indicate whether each of the following aspects of...Ch. 14 - Prob. 14.3EPCh. 14 - Prob. 14.4EPCh. 14 - Indicate whether each of the following statements...Ch. 14 - Prob. 14.6EPCh. 14 - Prob. 14.7EPCh. 14 - Prob. 14.8EPCh. 14 - Prob. 14.9EPCh. 14 - Prob. 14.10EPCh. 14 - At what location are free fatty acids and...Ch. 14 - Prob. 14.12EPCh. 14 - Prob. 14.13EPCh. 14 - What is the major metabolic function of adipose...Ch. 14 - What is triacylglycerol mobilization?Ch. 14 - Prob. 14.16EPCh. 14 - Prob. 14.17EPCh. 14 - Triacylglycerols in adipose tissue do not enter...Ch. 14 - In which step of glycerol metabolism does each of...Ch. 14 - Prob. 14.20EPCh. 14 - Prob. 14.21EPCh. 14 - How does the structure of dihydroxyacetone...Ch. 14 - Prob. 14.23EPCh. 14 - Prob. 14.24EPCh. 14 - Prob. 14.25EPCh. 14 - Prob. 14.26EPCh. 14 - Prob. 14.27EPCh. 14 - Identify the oxidizing agent needed in Step 3 of a...Ch. 14 - Prob. 14.29EPCh. 14 - Prob. 14.30EPCh. 14 - Prob. 14.31EPCh. 14 - Prob. 14.32EPCh. 14 - Prob. 14.33EPCh. 14 - Prob. 14.34EPCh. 14 - Prob. 14.35EPCh. 14 - Prob. 14.36EPCh. 14 - Prob. 14.37EPCh. 14 - Prob. 14.38EPCh. 14 - Prob. 14.39EPCh. 14 - Prob. 14.40EPCh. 14 - Prob. 14.41EPCh. 14 - Prob. 14.42EPCh. 14 - How many turns of the -oxidation pathway would be...Ch. 14 - How many turns of the -oxidation pathway would be...Ch. 14 - Prob. 14.45EPCh. 14 - Prob. 14.46EPCh. 14 - Prob. 14.47EPCh. 14 - Prob. 14.48EPCh. 14 - Prob. 14.49EPCh. 14 - Prob. 14.50EPCh. 14 - Prob. 14.51EPCh. 14 - Prob. 14.52EPCh. 14 - Prob. 14.53EPCh. 14 - Prob. 14.54EPCh. 14 - Prob. 14.55EPCh. 14 - Prob. 14.56EPCh. 14 - Prob. 14.57EPCh. 14 - Which yield more NADH, saturated or unsaturated...Ch. 14 - Prob. 14.59EPCh. 14 - Prob. 14.60EPCh. 14 - Prob. 14.61EPCh. 14 - Why does a deficiency of carbohydrates in the diet...Ch. 14 - Prob. 14.63EPCh. 14 - Prob. 14.64EPCh. 14 - Prob. 14.65EPCh. 14 - Prob. 14.66EPCh. 14 - Prob. 14.67EPCh. 14 - Prob. 14.68EPCh. 14 - Prob. 14.69EPCh. 14 - Prob. 14.70EPCh. 14 - Prob. 14.71EPCh. 14 - Prob. 14.72EPCh. 14 - Prob. 14.73EPCh. 14 - Prob. 14.74EPCh. 14 - Prob. 14.75EPCh. 14 - Severe ketosis situations produce acidosis....Ch. 14 - Prob. 14.77EPCh. 14 - Prob. 14.78EPCh. 14 - Prob. 14.79EPCh. 14 - Prob. 14.80EPCh. 14 - Prob. 14.81EPCh. 14 - Prob. 14.82EPCh. 14 - Prob. 14.83EPCh. 14 - Prob. 14.84EPCh. 14 - Prob. 14.85EPCh. 14 - Prob. 14.86EPCh. 14 - Prob. 14.87EPCh. 14 - Prob. 14.88EPCh. 14 - Prob. 14.89EPCh. 14 - Prob. 14.90EPCh. 14 - Prob. 14.91EPCh. 14 - Prob. 14.92EPCh. 14 - Prob. 14.93EPCh. 14 - Prob. 14.94EPCh. 14 - What role does molecular oxygen, O2, play in fatty...Ch. 14 - Prob. 14.96EPCh. 14 - Prob. 14.97EPCh. 14 - Prob. 14.98EPCh. 14 - Prob. 14.99EPCh. 14 - Prob. 14.100EPCh. 14 - Prob. 14.101EPCh. 14 - Prob. 14.102EPCh. 14 - Prob. 14.103EPCh. 14 - Prob. 14.104EPCh. 14 - Prob. 14.105EPCh. 14 - Prob. 14.106EPCh. 14 - Prob. 14.107EPCh. 14 - Prob. 14.108EPCh. 14 - Prob. 14.109EPCh. 14 - Prob. 14.110EPCh. 14 - Prob. 14.111EPCh. 14 - Prob. 14.112EPCh. 14 - Prob. 14.113EPCh. 14 - Prob. 14.114EP
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- Give the chemical equation for the preparation of: -Any aldehyde -Any keytonearrow_forward+ C8H16O2 (Fatty acid) + 11 02 → 8 CO2 a. Which of the above are the reactants? b. Which of the above are the products? H2o CO₂ c. Which reactant is the electron donor? Futty acid d. Which reactant is the electron acceptor? e. Which of the product is now reduced? f. Which of the products is now oxidized? 02 #20 102 8 H₂O g. Where was the carbon initially in this chemical reaction and where is it now that it is finished? 2 h. Where were the electrons initially in this chemical reaction and where is it now that it is finished?arrow_forward→ Acetyl-CoA + 3NAD+ + 1FAD + 1ADP 2CO2 + CoA + 3NADH + 1FADH2 + 1ATP a. Which of the above are the reactants? b. Which of the above are the products? c. Which reactant is the electron donor? d. Which reactants are the electron acceptors? e. Which of the products are now reduced? f. Which product is now oxidized? g. Which process was used to produce the ATP? h. Where was the energy initially in this chemical reaction and where is it now that it is finished? i. Where was the carbon initially in this chemical reaction and where is it now that it is finished? j. Where were the electrons initially in this chemical reaction and where is it now that it is finished?arrow_forward
- Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. OCH 3 (Choose one) OH (Choose one) Br (Choose one) Explanation Check NO2 (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Aarrow_forwardFor each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects O donating O withdrawing O no inductive effects Resonance Effects Overall Electron-Density ○ donating ○ withdrawing O no resonance effects O electron-rich O electron-deficient O similar to benzene Cl O donating O withdrawing ○ donating ○ withdrawing O no inductive effects O no resonance effects O Explanation Check O electron-rich O electron-deficient similar to benzene X © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessarrow_forwardIdentifying electron-donating and For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects NH2 ○ donating NO2 Explanation Check withdrawing no inductive effects Resonance Effects Overall Electron-Density ○ donating O withdrawing O no resonance effects O donating O withdrawing O donating withdrawing O no inductive effects Ono resonance effects O electron-rich electron-deficient O similar to benzene O electron-rich O electron-deficient O similar to benzene olo 18 Ar 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forward
- Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation Check Х (Choose one) OH (Choose one) OCH3 (Choose one) OH (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forwardAssign R or S to all the chiral centers in each compound drawn below porat bg 9 Br Brarrow_forwarddescrive the energy levels of an atom and howan electron moces between themarrow_forward
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