GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Chapter 13.2, Problem 13.2PP
Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the following alkene should be determined:

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 13.2, Problem 13.2PP , additional homework tip  1

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the following alkene should be determined:

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 13.2, Problem 13.2PP , additional homework tip  2

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the following alkene should be determined:

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 13.2, Problem 13.2PP , additional homework tip  3

Concept Introduction:

Alkenes are named in the same way as alkanes, but the alkenes are identified by the suffix −ene, replaced instead of the ending of the name of the parent alkane. The longest carbon chain should be numbered in a way that gives the double bond the lower number. Then the compound should be named using the first number assigned to the double bond. The names of the substituents should be written first in the alphabetic order with their position on the chain.

Interpretation Introduction

(d)

Interpretation:

The IUPAC name for the following alkene should be determined:

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 13.2, Problem 13.2PP , additional homework tip  4

Concept Introduction:

In the nomenclature of cycloalkenes, the double bond is always located between C-1 and C-2. And 1 is not mentioned in the name. the ring is then numbered in a way that the first substituent getting the lowest number.

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1,4-Dimethyl-1,3-cyclohexadiene can undergo 1,2- or 1,4-addition with hydrogen halides. (a) 1,2-Addition i. Draw the carbocation intermediate(s) formed during the 1,2-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,2-addition product formed during the reaction in (i)? (b) 1,4-Addition i. Draw the carbocation intermediate(s) formed during the 1,4-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,4-addition product formed from the reaction in (i)? (c) What is the kinetic product from the reaction of one mole of hydrobromic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (d) What is the thermodynamic product from the reaction of one mole of hydrobro-mic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (e) What major product will result when 1,4-dimethyl-1,3-cyclohexadiene is treated with one mole of hydrobromic acid at - 78 deg * C ? Explain your reasoning.
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Five isomeric alkenes. A through each undergo catalytic hydrogenation to give 2-methylpentane The IR spectra of these five alkenes have the key absorptions (in cm Compound Compound A –912. (§), 994 (5), 1643 (%), 3077 (1) Compound B 833 (3), 1667 (W), 3050 (weak shoulder on C-Habsorption) Compound C Compound D) –714 (5), 1665 (w), 3010 (m) 885 (3), 1650 (m), 3086 (m) 967 (5), no aharption 1600 to 1700, 3040 (m) Compound K Match each compound to the data presented. Compound A Compound B Compound C Compound D Compound

Chapter 13 Solutions

GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES

Ch. 13.3 - Prob. 13.5PCh. 13.3 - Prob. 13.6PCh. 13.3 - Prob. 13.7PCh. 13.3 - Prob. 13.8PCh. 13.6 - Prob. 13.7PPCh. 13.6 - Prob. 13.9PCh. 13.6 - What products is formed in each of the following...Ch. 13.6 - Prob. 13.9PPCh. 13.6 - What product is formed when l-pentene (CH3CH2CH2CH...Ch. 13.7 - Prob. 13.11PCh. 13.8 - Prob. 13.10PPCh. 13.8 - Prob. 13.12PCh. 13.8 - Prob. 13.13PCh. 13.10 - Prob. 13.11PPCh. 13.10 - Prob. 13.14PCh. 13.11 - Prob. 13.15PCh. 13.12 - Prob. 13.16PCh. 13.13 - Prob. 13.17PCh. 13.13 - Prob. 13.18PCh. 13 - Anethole, the major constituent of anise oil, is...Ch. 13 - Prob. 20PCh. 13 - What is the molecular formula for a hydrocarbon...Ch. 13 - Prob. 22PCh. 13 - Prob. 23PCh. 13 - Prob. 24PCh. 13 - Prob. 25PCh. 13 - Prob. 26PCh. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each compound. a....Ch. 13 - Give the IUPAC name for each compound. d....Ch. 13 - Give the IUPAC name for each alkene.Ch. 13 - Give the I UP AC name for each alkene.Ch. 13 - Give the IUPAC name for each cyclic compound.Ch. 13 - Give the IUPAC name for each cyclic compound.Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 36PCh. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Label the carbon-carbon double bond as cis or...Ch. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Prob. 47PCh. 13 - Prob. 48PCh. 13 - Prob. 49PCh. 13 - Prob. 50PCh. 13 - Prob. 51PCh. 13 - Prob. 52PCh. 13 - Prob. 53PCh. 13 - Prob. 54PCh. 13 - What alkyd halide is formed when each alkene is...Ch. 13 - Prob. 56PCh. 13 - Prob. 57PCh. 13 - Prob. 58PCh. 13 - What alkene is needed as a starting material to...Ch. 13 - Prob. 60PCh. 13 - Prob. 61PCh. 13 - Prob. 62PCh. 13 - Prob. 63PCh. 13 - Prob. 64PCh. 13 - Prob. 65PCh. 13 - Prob. 66PCh. 13 - Prob. 67PCh. 13 - Prob. 68PCh. 13 - Prob. 69PCh. 13 - Prob. 70PCh. 13 - Prob. 71PCh. 13 - Prob. 72PCh. 13 - Prob. 73PCh. 13 - Are o-bromochlorobenzene and m-bromochlorobenzene...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 77PCh. 13 - Prob. 78PCh. 13 - Prob. 79PCh. 13 - Prob. 80PCh. 13 - Prob. 81PCh. 13 - Prob. 82PCh. 13 - Prob. 83PCh. 13 - Prob. 84PCh. 13 - Prob. 85PCh. 13 - Eleostearic acid is an unsaturated fatty acid...Ch. 13 - Prob. 87PCh. 13 - Prob. 88PCh. 13 - Prob. 89PCh. 13 - Prob. 90PCh. 13 - Prob. 91PCh. 13 - Prob. 92PCh. 13 - Prob. 93PCh. 13 - Prob. 94PCh. 13 - Answer the following questions about compound A,...Ch. 13 - Prob. 96PCh. 13 - Answer the following questions about alkene C,...Ch. 13 - Prob. 98PCh. 13 - Prob. 99PCh. 13 - Prob. 100PCh. 13 - Prob. 101CPCh. 13 - Prob. 102CP
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