(a) Interpretation: The product formed when p-xylene is treated with Cl 2 , FeCl 3 needs to be identified. Concept Introduction: Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups. Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO 2 or -SO 3 H group, respectively.

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Answer 1

Question

Chapter 13, Problem 77P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

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By malonic or acetylacetic synthesis, synthesize 2-methylbutanoic acid (indicate the formulas of the compounds).

Obtain 2-methylbutanoic acid by malonic or acetylacetic synthesis (indicate the formulas of the compounds involved).

EFFICIENTS SAMPLE READINGS CONCENTRATIONS Pigiadient) TOMATO SAUCE (REGULAR) TOMATO (REDUCED SALT) TOMATO SAUCE (REGULAR) TOMATO (REDUCED SALT) 58 6.274 3.898 301.7 151.2 14150 5.277 3.865 348.9 254.8 B 5.136 3.639 193.7 85.9 605 4.655 3.041 308.6 199.6 05 5.135 3.664 339.5 241.4 0139 4.676 3.662 160.6 87.6 90148 5.086 3.677 337.7 242.5 0092 6.348 3.775 464.7 186.4 PART3 5.081 3.908 223.5 155.8 5.558 3.861 370.5 257.1 4.922 3.66 326.6 242.9 4.752 3.641 327.5 253.3 50 5.018 3.815 336.1 256.0 84 4.959 3.605 317.9 216.6 38 4.96 3.652 203.8 108.7 $3 5.052 3.664 329.8 239.0 17 5.043 3.767 221.9 149.7 052 5.058 3.614 331.7 236.4 5.051 4.005 211.7 152.1 62 5.047 3.637 309.6 222.7 5.298 3.977 223.4 148.7 5.38 4.24 353.7 278.2 5 5.033 4.044 334.6 268.7 995 4.706 3.621 305.6 234.4 04 4.816 3.728 340.0 262.7 16 4.828 4.496 304.3 283.2 0.011 4.993 3.865 244.7 143.6 AVERAGE STDEV COUNT 95% CI Confidence Interval (mmol/L) [Na+] (mg/100 mL) 95% Na+ Confidence Interval (mg/100 mL)

Answer 2

Question

Chapter 13, Problem 77P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

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Answer 3

Question

Chapter 13, Problem 77P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

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Answer 4

Question

Chapter 13, Problem 77P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

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Answer 5

Chapter 13, Problem 77P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

Answer 6

Chapter 13, Problem 77P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Answer 7

Chapter 13, Problem 77P

Interpretation Introduction

(a)

Interpretation:

The product formed when p-xylene is treated with Cl₂, FeCl₃ needs to be identified.

Concept Introduction:

Aromatic compoundsundergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed when p-xylene is treated with HNO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group, respectively.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product formed when p-xylene is treated with SO₃, H₂SO₄ needs to be identified.

Concept Introduction:

Aromatic compounds undergo substitution reactions in which one of the hydrogen in the benzene ring is replaced by another atom or groups.

Chlorination, nitration, and sulfonation are common substitution reactions wherein one of the H atoms is replaced by a -Cl, -NO₂ or -SO₃H group respectively.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.1P Ch. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.2PP Ch. 13.2 - Prob. 13.3P Ch. 13.2 - Prob. 13.3PP Ch. 13.2 - Prob. 13.4PP Ch. 13.3 - Prob. 13.5PP Ch. 13.3 - Prob. 13.4P Ch. 13.3 - Prob. 13.6PP

Solution Summary: The author explains that aromatic compounds undergo substitution reactions in which one of thehydrogens in the benzene ring is replaced by another atom or groups.

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Chapter 13 Solutions