GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Question
Chapter 13, Problem 94P
Interpretation Introduction
Interpretation:
Nonpolarity of p-dichlorobenzene and polarity of o-dichlorobenzene should be explained.
Concept Introduction:
Polarity of a chemical compound occurs due to the different separation of electric charge of the atoms which leads to having an electric dipole moment to the whole molecule.
When two substituents are attached to a benzene ring, prefix -ortho (o), -para (p) and -meta (m) can be used to designate the relative position of the two substituents.
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Students have asked these similar questions
Part II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization
of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm").
Determine the following:
(a) molecular Formula and Degree of unsaturation of compound Brian
(b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts
(ii) integration, ciii) multiplicity and (iv) interferences made for each signal
(c) Draw the structure of compound Brian.
)
ΕΙ
43
41
27
71
114 (M+)
Hmmm
20
30
40
50 60
70
80
90 100 110 120
1H NMR spectrum
300 MHz in CDCl3
2.0
alle
1.0
The iron-iron carbide phase diagram.
In the diagram, the letter L indicates that it
is a liquid. Indicate what its components
are.
Temperature (°C)
1600
10
Composition (at% C)
15
25
1538°C
-1493°C
8
1400
1200
1394°C
y+L
L
2500
1147°C
y. Austenite
2.14
4.30
2000
1000
912°C
y + Fe3C
800ㅏ
0.76
0.022
600
a, Ferrite
a + Fe3C
400
0
(Fe)
Composition (wt% C)
727°C
1500
Cementite (Fe3C)
1000
6
6.70
Temperature (°F)
Part V. Choose which isomer would give the 1H-NMR spectrum below. Justify your reasoning by assigning important signals to the
Corresponding protons of the correct molecule.
A
D
on of of of
H
H
88
2
90
7.8
7.6
7.4
80
5
6 [ppm]
7.2
6.8
6.6
6.4
ō [ppm]
Chapter 13 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.1PCh. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.2PPCh. 13.2 - Prob. 13.3PCh. 13.2 - Prob. 13.3PPCh. 13.2 - Prob. 13.4PPCh. 13.3 - Prob. 13.5PPCh. 13.3 - Prob. 13.4PCh. 13.3 - Prob. 13.6PP
Ch. 13.3 - Prob. 13.5PCh. 13.3 - Prob. 13.6PCh. 13.3 - Prob. 13.7PCh. 13.3 - Prob. 13.8PCh. 13.6 - Prob. 13.7PPCh. 13.6 - Prob. 13.9PCh. 13.6 - What products is formed in each of the following...Ch. 13.6 - Prob. 13.9PPCh. 13.6 - What product is formed when l-pentene (CH3CH2CH2CH...Ch. 13.7 - Prob. 13.11PCh. 13.8 - Prob. 13.10PPCh. 13.8 - Prob. 13.12PCh. 13.8 - Prob. 13.13PCh. 13.10 - Prob. 13.11PPCh. 13.10 - Prob. 13.14PCh. 13.11 - Prob. 13.15PCh. 13.12 - Prob. 13.16PCh. 13.13 - Prob. 13.17PCh. 13.13 - Prob. 13.18PCh. 13 - Anethole, the major constituent of anise oil, is...Ch. 13 - Prob. 20PCh. 13 - What is the molecular formula for a hydrocarbon...Ch. 13 - Prob. 22PCh. 13 - Prob. 23PCh. 13 - Prob. 24PCh. 13 - Prob. 25PCh. 13 - Prob. 26PCh. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each compound. a....Ch. 13 - Give the IUPAC name for each compound. d....Ch. 13 - Give the IUPAC name for each alkene.Ch. 13 - Give the I UP AC name for each alkene.Ch. 13 - Give the IUPAC name for each cyclic compound.Ch. 13 - Give the IUPAC name for each cyclic compound.Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 36PCh. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Label the carbon-carbon double bond as cis or...Ch. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Prob. 47PCh. 13 - Prob. 48PCh. 13 - Prob. 49PCh. 13 - Prob. 50PCh. 13 - Prob. 51PCh. 13 - Prob. 52PCh. 13 - Prob. 53PCh. 13 - Prob. 54PCh. 13 - What alkyd halide is formed when each alkene is...Ch. 13 - Prob. 56PCh. 13 - Prob. 57PCh. 13 - Prob. 58PCh. 13 - What alkene is needed as a starting material to...Ch. 13 - Prob. 60PCh. 13 - Prob. 61PCh. 13 - Prob. 62PCh. 13 - Prob. 63PCh. 13 - Prob. 64PCh. 13 - Prob. 65PCh. 13 - Prob. 66PCh. 13 - Prob. 67PCh. 13 - Prob. 68PCh. 13 - Prob. 69PCh. 13 - Prob. 70PCh. 13 - Prob. 71PCh. 13 - Prob. 72PCh. 13 - Prob. 73PCh. 13 - Are o-bromochlorobenzene and m-bromochlorobenzene...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 77PCh. 13 - Prob. 78PCh. 13 - Prob. 79PCh. 13 - Prob. 80PCh. 13 - Prob. 81PCh. 13 - Prob. 82PCh. 13 - Prob. 83PCh. 13 - Prob. 84PCh. 13 - Prob. 85PCh. 13 - Eleostearic acid is an unsaturated fatty acid...Ch. 13 - Prob. 87PCh. 13 - Prob. 88PCh. 13 - Prob. 89PCh. 13 - Prob. 90PCh. 13 - Prob. 91PCh. 13 - Prob. 92PCh. 13 - Prob. 93PCh. 13 - Prob. 94PCh. 13 - Answer the following questions about compound A,...Ch. 13 - Prob. 96PCh. 13 - Answer the following questions about alkene C,...Ch. 13 - Prob. 98PCh. 13 - Prob. 99PCh. 13 - Prob. 100PCh. 13 - Prob. 101CPCh. 13 - Prob. 102CP
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