Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 13, Problem 26QAP
Interpretation Introduction
Interpretation:
One must explain the reason why the lines in the volume/temperature date for several samples of gases seems to extrapolate to the same point at -273 0 C.
Concept Introduction:
The plots of volume vs temperature of several real gasses show a consistent behavior as shown below. One could clearly see that all the lines extrapolate to the same point at -273 0 C even though each sample of gas contains different amounts of moles spread in the plots. If you us the ambient (Kelvin) temperature scale those lines would extrapolate to 0K.The two plots can be shown as below.
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 13 Solutions
Introductory Chemistry: A Foundation
Ch. 13.1 - Prob. 13.1SCCh. 13.2 - Prob. 13.2SCCh. 13.3 - Prob. 1CTCh. 13.3 - trong>Exercise 13.3 A child blows a bubble that...Ch. 13.4 - Prob. 13.4SCCh. 13.5 - trong>Exercise 13.5 A weather balloon contains...Ch. 13.5 - Prob. 13.6SCCh. 13.5 - Prob. 13.7SCCh. 13.5 - trong>Exercise 13.8 A sample of argon gas with a...Ch. 13.6 - Prob. 13.9SC
Ch. 13.6 - Prob. 13.10SCCh. 13.8 - Prob. 1CTCh. 13.10 - trong>Exercise 13.11 Calculate the volume of...Ch. 13.10 - at if STP was defined as normal room temperature...Ch. 13.10 - Prob. 13.12SCCh. 13 - Prob. 1ALQCh. 13 - Prob. 2ALQCh. 13 - Prob. 3ALQCh. 13 - Prob. 4ALQCh. 13 - Prob. 5ALQCh. 13 - Prob. 6ALQCh. 13 - Prob. 7ALQCh. 13 - Prob. 8ALQCh. 13 - Prob. 9ALQCh. 13 - Prob. 10ALQCh. 13 - Prob. 11ALQCh. 13 - Prob. 12ALQCh. 13 - Prob. 13ALQCh. 13 - Draw molecular—level views than show the...Ch. 13 - Prob. 15ALQCh. 13 - Prob. 16ALQCh. 13 - Prob. 17ALQCh. 13 - Prob. 18ALQCh. 13 - Prob. 19ALQCh. 13 - Prob. 20ALQCh. 13 - You are holding two balloons of the same volume....Ch. 13 - Prob. 22ALQCh. 13 - Prob. 23ALQCh. 13 - The introduction to this chapter says that "we...Ch. 13 - Prob. 2QAPCh. 13 - Prob. 3QAPCh. 13 - Prob. 4QAPCh. 13 - Prob. 5QAPCh. 13 - Prob. 6QAPCh. 13 - Prob. 7QAPCh. 13 - Prob. 8QAPCh. 13 - Prob. 9QAPCh. 13 - Prob. 10QAPCh. 13 - Make the indicated pressure conversions....Ch. 13 - Prob. 12QAPCh. 13 - Prob. 13QAPCh. 13 - Prob. 14QAPCh. 13 - Prob. 15QAPCh. 13 - Prob. 16QAPCh. 13 - Prob. 17QAPCh. 13 - Prob. 18QAPCh. 13 - Prob. 19QAPCh. 13 - Prob. 20QAPCh. 13 - Prob. 21QAPCh. 13 - Prob. 22QAPCh. 13 - 3. A sample of helium gas with a volume of...Ch. 13 - Prob. 24QAPCh. 13 - Prob. 25QAPCh. 13 - Prob. 26QAPCh. 13 - Prob. 27QAPCh. 13 - Prob. 28QAPCh. 13 - A sample of gas in a balloon has an initial...Ch. 13 - Suppose a 375mLsample of neon gas at 78Cis cooled...Ch. 13 - For each of the following sets of...Ch. 13 - For each of the following sets of...Ch. 13 - Prob. 33QAPCh. 13 - Prob. 34QAPCh. 13 - Suppose 1.25Lof argon is cooled from 291Kto 78K....Ch. 13 - Suppose a 125mLsample of argon is cooled from...Ch. 13 - Prob. 37QAPCh. 13 - Prob. 38QAPCh. 13 - Prob. 39QAPCh. 13 - Prob. 40QAPCh. 13 - Prob. 41QAPCh. 13 - If :math>1.04gof chlorine gas occupies a volume of...Ch. 13 - If 3.25moles of argon gas occupies a volume of...Ch. 13 - Prob. 44QAPCh. 13 - Prob. 45QAPCh. 13 - Prob. 46QAPCh. 13 - Prob. 47QAPCh. 13 - Prob. 48QAPCh. 13 - Prob. 49QAPCh. 13 - Prob. 50QAPCh. 13 - Prob. 51QAPCh. 13 - Determine the pressure in a 125Ltank containing...Ch. 13 - Prob. 53QAPCh. 13 - Prob. 54QAPCh. 13 - Prob. 55QAPCh. 13 - Suppose that a 1.25gsample of neon gas is confined...Ch. 13 - At what temperature will a 1.0gsample of neon gas...Ch. 13 - Prob. 58QAPCh. 13 - What pressure exists in a 200Ltank containing...Ch. 13 - Prob. 60QAPCh. 13 - Suppose a 24.3mLsample of helium gas at 25Cand...Ch. 13 - Prob. 62QAPCh. 13 - Prob. 63QAPCh. 13 - Prob. 64QAPCh. 13 - Prob. 65QAPCh. 13 - Prob. 66QAPCh. 13 - Prob. 67QAPCh. 13 - Suppose than 1.28gof neon gas and 2.49gof argon...Ch. 13 - A tank contains a mixture of 52.5gof oxygen gas...Ch. 13 - What mass of new gas would but required to fill a...Ch. 13 - Prob. 71QAPCh. 13 - Prob. 72QAPCh. 13 - A 500mLsample of O2gas at 24Cwas prepared by...Ch. 13 - Prob. 74QAPCh. 13 - Prob. 75QAPCh. 13 - Prob. 76QAPCh. 13 - Prob. 77QAPCh. 13 - Prob. 78QAPCh. 13 - Prob. 79QAPCh. 13 - Prob. 80QAPCh. 13 - Prob. 81QAPCh. 13 - Prob. 82QAPCh. 13 - Prob. 83QAPCh. 13 - Prob. 84QAPCh. 13 - Calcium oxide can be used to “scrub" carbon...Ch. 13 - Consider the following reaction:...Ch. 13 - Consider the following reaction for the combustion...Ch. 13 - Although we: generally think of combustion...Ch. 13 - m>89. Ammonia and gaseous hydrogen chloride...Ch. 13 - Calcium carbide, CaC2, reacts with water to...Ch. 13 - Prob. 91QAPCh. 13 - Prob. 92QAPCh. 13 - What volume does a mixture of 14.2gof He and...Ch. 13 - Prob. 94QAPCh. 13 - Prob. 95QAPCh. 13 - Consider the following chemical equation:...Ch. 13 - Prob. 97QAPCh. 13 - Dinitrogen monoxide, N2O, reacts with propane,...Ch. 13 - Consider the following unbalanced chemical...Ch. 13 - Prob. 100QAPCh. 13 - Prob. 101QAPCh. 13 - Prob. 102QAPCh. 13 - Prob. 103APCh. 13 - Prob. 104APCh. 13 - Prob. 105APCh. 13 - onsider the flasks in the following diagrams. mg...Ch. 13 - Prob. 107APCh. 13 - helium tank contains 25.2Lof helium m 8.40atm...Ch. 13 - Prob. 109APCh. 13 - Prob. 110APCh. 13 - Prob. 111APCh. 13 - Prob. 112APCh. 13 - Prob. 113APCh. 13 - Prob. 114APCh. 13 - Prob. 115APCh. 13 - Prob. 116APCh. 13 - Prob. 117APCh. 13 - 2.50Lcontainer at 1.00atm and 48Cis filled with...Ch. 13 - Prob. 119APCh. 13 - Prob. 120APCh. 13 - Prob. 121APCh. 13 - Prob. 122APCh. 13 - Prob. 123APCh. 13 - f a gaseous mixture is made of 3.50gof He and...Ch. 13 - Prob. 125APCh. 13 - Prob. 126APCh. 13 - f 5.l2gof oxygen gas occupies a volume of 6.21Lat...Ch. 13 - Prob. 128APCh. 13 - Prob. 129APCh. 13 - Prob. 130APCh. 13 - Prob. 131APCh. 13 - Prob. 132APCh. 13 - t what temperature does 4.00gof helium gas have a...Ch. 13 - Prob. 134APCh. 13 - f 3.20gof nitrogen gas occupies a volume of...Ch. 13 - Prob. 136APCh. 13 - mixture at 33Ccontains H2at 325torr, N2at 475torr,...Ch. 13 - Prob. 138APCh. 13 - Prob. 139APCh. 13 - he following demonstration takes place in a...Ch. 13 - onsider the following unbalanced chemical...Ch. 13 - Prob. 142APCh. 13 - Prob. 143APCh. 13 - Prob. 144APCh. 13 - Prob. 145APCh. 13 - Prob. 146APCh. 13 - Prob. 147APCh. 13 - Prob. 148APCh. 13 - Prob. 149APCh. 13 - omplete the following table for an ideal gas. mg...Ch. 13 - Prob. 151CPCh. 13 - Prob. 152CPCh. 13 - certain flexible weather balloon contains helium...Ch. 13 - Prob. 154CPCh. 13 - Prob. 155CPCh. 13 - Prob. 156CPCh. 13 - Prob. 157CP
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