
Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
Chapter 13, Problem 111AP
Interpretation Introduction
Interpretation:
The volume of carbon dioxide collected should be calculated.
Concept Introduction:
According to ideal gas equation:
Here, P is pressure, V is volume, n is number of moles, R is Universal gas constant and T is temperature.
The value of Universal gas constant can be taken as
Mass of gas can be calculated from number of moles and molar mass as follows:
Here, n is number of moles, m is mass and M is molar mass.
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
200
160
120
80
40
0
200
160
120
80
40
0
DEPT 135
T
200
160
120
80
40
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Draw the unknown amide.
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Chapter 13 Solutions
Introductory Chemistry: A Foundation
Ch. 13.1 - Prob. 13.1SCCh. 13.2 - Prob. 13.2SCCh. 13.3 - Prob. 1CTCh. 13.3 - trong>Exercise 13.3 A child blows a bubble that...Ch. 13.4 - Prob. 13.4SCCh. 13.5 - trong>Exercise 13.5 A weather balloon contains...Ch. 13.5 - Prob. 13.6SCCh. 13.5 - Prob. 13.7SCCh. 13.5 - trong>Exercise 13.8 A sample of argon gas with a...Ch. 13.6 - Prob. 13.9SC
Ch. 13.6 - Prob. 13.10SCCh. 13.8 - Prob. 1CTCh. 13.10 - trong>Exercise 13.11 Calculate the volume of...Ch. 13.10 - at if STP was defined as normal room temperature...Ch. 13.10 - Prob. 13.12SCCh. 13 - Prob. 1ALQCh. 13 - Prob. 2ALQCh. 13 - Prob. 3ALQCh. 13 - Prob. 4ALQCh. 13 - Prob. 5ALQCh. 13 - Prob. 6ALQCh. 13 - Prob. 7ALQCh. 13 - Prob. 8ALQCh. 13 - Prob. 9ALQCh. 13 - Prob. 10ALQCh. 13 - Prob. 11ALQCh. 13 - Prob. 12ALQCh. 13 - Prob. 13ALQCh. 13 - Draw molecular—level views than show the...Ch. 13 - Prob. 15ALQCh. 13 - Prob. 16ALQCh. 13 - Prob. 17ALQCh. 13 - Prob. 18ALQCh. 13 - Prob. 19ALQCh. 13 - Prob. 20ALQCh. 13 - You are holding two balloons of the same volume....Ch. 13 - Prob. 22ALQCh. 13 - Prob. 23ALQCh. 13 - The introduction to this chapter says that "we...Ch. 13 - Prob. 2QAPCh. 13 - Prob. 3QAPCh. 13 - Prob. 4QAPCh. 13 - Prob. 5QAPCh. 13 - Prob. 6QAPCh. 13 - Prob. 7QAPCh. 13 - Prob. 8QAPCh. 13 - Prob. 9QAPCh. 13 - Prob. 10QAPCh. 13 - Make the indicated pressure conversions....Ch. 13 - Prob. 12QAPCh. 13 - Prob. 13QAPCh. 13 - Prob. 14QAPCh. 13 - Prob. 15QAPCh. 13 - Prob. 16QAPCh. 13 - Prob. 17QAPCh. 13 - Prob. 18QAPCh. 13 - Prob. 19QAPCh. 13 - Prob. 20QAPCh. 13 - Prob. 21QAPCh. 13 - Prob. 22QAPCh. 13 - 3. A sample of helium gas with a volume of...Ch. 13 - Prob. 24QAPCh. 13 - Prob. 25QAPCh. 13 - Prob. 26QAPCh. 13 - Prob. 27QAPCh. 13 - Prob. 28QAPCh. 13 - A sample of gas in a balloon has an initial...Ch. 13 - Suppose a 375mLsample of neon gas at 78Cis cooled...Ch. 13 - For each of the following sets of...Ch. 13 - For each of the following sets of...Ch. 13 - Prob. 33QAPCh. 13 - Prob. 34QAPCh. 13 - Suppose 1.25Lof argon is cooled from 291Kto 78K....Ch. 13 - Suppose a 125mLsample of argon is cooled from...Ch. 13 - Prob. 37QAPCh. 13 - Prob. 38QAPCh. 13 - Prob. 39QAPCh. 13 - Prob. 40QAPCh. 13 - Prob. 41QAPCh. 13 - If :math>1.04gof chlorine gas occupies a volume of...Ch. 13 - If 3.25moles of argon gas occupies a volume of...Ch. 13 - Prob. 44QAPCh. 13 - Prob. 45QAPCh. 13 - Prob. 46QAPCh. 13 - Prob. 47QAPCh. 13 - Prob. 48QAPCh. 13 - Prob. 49QAPCh. 13 - Prob. 50QAPCh. 13 - Prob. 51QAPCh. 13 - Determine the pressure in a 125Ltank containing...Ch. 13 - Prob. 53QAPCh. 13 - Prob. 54QAPCh. 13 - Prob. 55QAPCh. 13 - Suppose that a 1.25gsample of neon gas is confined...Ch. 13 - At what temperature will a 1.0gsample of neon gas...Ch. 13 - Prob. 58QAPCh. 13 - What pressure exists in a 200Ltank containing...Ch. 13 - Prob. 60QAPCh. 13 - Suppose a 24.3mLsample of helium gas at 25Cand...Ch. 13 - Prob. 62QAPCh. 13 - Prob. 63QAPCh. 13 - Prob. 64QAPCh. 13 - Prob. 65QAPCh. 13 - Prob. 66QAPCh. 13 - Prob. 67QAPCh. 13 - Suppose than 1.28gof neon gas and 2.49gof argon...Ch. 13 - A tank contains a mixture of 52.5gof oxygen gas...Ch. 13 - What mass of new gas would but required to fill a...Ch. 13 - Prob. 71QAPCh. 13 - Prob. 72QAPCh. 13 - A 500mLsample of O2gas at 24Cwas prepared by...Ch. 13 - Prob. 74QAPCh. 13 - Prob. 75QAPCh. 13 - Prob. 76QAPCh. 13 - Prob. 77QAPCh. 13 - Prob. 78QAPCh. 13 - Prob. 79QAPCh. 13 - Prob. 80QAPCh. 13 - Prob. 81QAPCh. 13 - Prob. 82QAPCh. 13 - Prob. 83QAPCh. 13 - Prob. 84QAPCh. 13 - Calcium oxide can be used to “scrub" carbon...Ch. 13 - Consider the following reaction:...Ch. 13 - Consider the following reaction for the combustion...Ch. 13 - Although we: generally think of combustion...Ch. 13 - m>89. Ammonia and gaseous hydrogen chloride...Ch. 13 - Calcium carbide, CaC2, reacts with water to...Ch. 13 - Prob. 91QAPCh. 13 - Prob. 92QAPCh. 13 - What volume does a mixture of 14.2gof He and...Ch. 13 - Prob. 94QAPCh. 13 - Prob. 95QAPCh. 13 - Consider the following chemical equation:...Ch. 13 - Prob. 97QAPCh. 13 - Dinitrogen monoxide, N2O, reacts with propane,...Ch. 13 - Consider the following unbalanced chemical...Ch. 13 - Prob. 100QAPCh. 13 - Prob. 101QAPCh. 13 - Prob. 102QAPCh. 13 - Prob. 103APCh. 13 - Prob. 104APCh. 13 - Prob. 105APCh. 13 - onsider the flasks in the following diagrams. mg...Ch. 13 - Prob. 107APCh. 13 - helium tank contains 25.2Lof helium m 8.40atm...Ch. 13 - Prob. 109APCh. 13 - Prob. 110APCh. 13 - Prob. 111APCh. 13 - Prob. 112APCh. 13 - Prob. 113APCh. 13 - Prob. 114APCh. 13 - Prob. 115APCh. 13 - Prob. 116APCh. 13 - Prob. 117APCh. 13 - 2.50Lcontainer at 1.00atm and 48Cis filled with...Ch. 13 - Prob. 119APCh. 13 - Prob. 120APCh. 13 - Prob. 121APCh. 13 - Prob. 122APCh. 13 - Prob. 123APCh. 13 - f a gaseous mixture is made of 3.50gof He and...Ch. 13 - Prob. 125APCh. 13 - Prob. 126APCh. 13 - f 5.l2gof oxygen gas occupies a volume of 6.21Lat...Ch. 13 - Prob. 128APCh. 13 - Prob. 129APCh. 13 - Prob. 130APCh. 13 - Prob. 131APCh. 13 - Prob. 132APCh. 13 - t what temperature does 4.00gof helium gas have a...Ch. 13 - Prob. 134APCh. 13 - f 3.20gof nitrogen gas occupies a volume of...Ch. 13 - Prob. 136APCh. 13 - mixture at 33Ccontains H2at 325torr, N2at 475torr,...Ch. 13 - Prob. 138APCh. 13 - Prob. 139APCh. 13 - he following demonstration takes place in a...Ch. 13 - onsider the following unbalanced chemical...Ch. 13 - Prob. 142APCh. 13 - Prob. 143APCh. 13 - Prob. 144APCh. 13 - Prob. 145APCh. 13 - Prob. 146APCh. 13 - Prob. 147APCh. 13 - Prob. 148APCh. 13 - Prob. 149APCh. 13 - omplete the following table for an ideal gas. mg...Ch. 13 - Prob. 151CPCh. 13 - Prob. 152CPCh. 13 - certain flexible weather balloon contains helium...Ch. 13 - Prob. 154CPCh. 13 - Prob. 155CPCh. 13 - Prob. 156CPCh. 13 - Prob. 157CP
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