Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 13, Problem 148AP
Interpretation Introduction
Interpretation:
To calculate the amount of sodium azide that releases 70.0 L of gas at STP through decomposition.
Concept Introduction:
Sodium azide decomposes to form sodium and nitrogen gas that inflates the air bags.
The chemical equation is given by:
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Students have asked these similar questions
Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 13 Solutions
Introductory Chemistry: A Foundation
Ch. 13.1 - Prob. 13.1SCCh. 13.2 - Prob. 13.2SCCh. 13.3 - Prob. 1CTCh. 13.3 - trong>Exercise 13.3 A child blows a bubble that...Ch. 13.4 - Prob. 13.4SCCh. 13.5 - trong>Exercise 13.5 A weather balloon contains...Ch. 13.5 - Prob. 13.6SCCh. 13.5 - Prob. 13.7SCCh. 13.5 - trong>Exercise 13.8 A sample of argon gas with a...Ch. 13.6 - Prob. 13.9SC
Ch. 13.6 - Prob. 13.10SCCh. 13.8 - Prob. 1CTCh. 13.10 - trong>Exercise 13.11 Calculate the volume of...Ch. 13.10 - at if STP was defined as normal room temperature...Ch. 13.10 - Prob. 13.12SCCh. 13 - Prob. 1ALQCh. 13 - Prob. 2ALQCh. 13 - Prob. 3ALQCh. 13 - Prob. 4ALQCh. 13 - Prob. 5ALQCh. 13 - Prob. 6ALQCh. 13 - Prob. 7ALQCh. 13 - Prob. 8ALQCh. 13 - Prob. 9ALQCh. 13 - Prob. 10ALQCh. 13 - Prob. 11ALQCh. 13 - Prob. 12ALQCh. 13 - Prob. 13ALQCh. 13 - Draw molecular—level views than show the...Ch. 13 - Prob. 15ALQCh. 13 - Prob. 16ALQCh. 13 - Prob. 17ALQCh. 13 - Prob. 18ALQCh. 13 - Prob. 19ALQCh. 13 - Prob. 20ALQCh. 13 - You are holding two balloons of the same volume....Ch. 13 - Prob. 22ALQCh. 13 - Prob. 23ALQCh. 13 - The introduction to this chapter says that "we...Ch. 13 - Prob. 2QAPCh. 13 - Prob. 3QAPCh. 13 - Prob. 4QAPCh. 13 - Prob. 5QAPCh. 13 - Prob. 6QAPCh. 13 - Prob. 7QAPCh. 13 - Prob. 8QAPCh. 13 - Prob. 9QAPCh. 13 - Prob. 10QAPCh. 13 - Make the indicated pressure conversions....Ch. 13 - Prob. 12QAPCh. 13 - Prob. 13QAPCh. 13 - Prob. 14QAPCh. 13 - Prob. 15QAPCh. 13 - Prob. 16QAPCh. 13 - Prob. 17QAPCh. 13 - Prob. 18QAPCh. 13 - Prob. 19QAPCh. 13 - Prob. 20QAPCh. 13 - Prob. 21QAPCh. 13 - Prob. 22QAPCh. 13 - 3. A sample of helium gas with a volume of...Ch. 13 - Prob. 24QAPCh. 13 - Prob. 25QAPCh. 13 - Prob. 26QAPCh. 13 - Prob. 27QAPCh. 13 - Prob. 28QAPCh. 13 - A sample of gas in a balloon has an initial...Ch. 13 - Suppose a 375mLsample of neon gas at 78Cis cooled...Ch. 13 - For each of the following sets of...Ch. 13 - For each of the following sets of...Ch. 13 - Prob. 33QAPCh. 13 - Prob. 34QAPCh. 13 - Suppose 1.25Lof argon is cooled from 291Kto 78K....Ch. 13 - Suppose a 125mLsample of argon is cooled from...Ch. 13 - Prob. 37QAPCh. 13 - Prob. 38QAPCh. 13 - Prob. 39QAPCh. 13 - Prob. 40QAPCh. 13 - Prob. 41QAPCh. 13 - If :math>1.04gof chlorine gas occupies a volume of...Ch. 13 - If 3.25moles of argon gas occupies a volume of...Ch. 13 - Prob. 44QAPCh. 13 - Prob. 45QAPCh. 13 - Prob. 46QAPCh. 13 - Prob. 47QAPCh. 13 - Prob. 48QAPCh. 13 - Prob. 49QAPCh. 13 - Prob. 50QAPCh. 13 - Prob. 51QAPCh. 13 - Determine the pressure in a 125Ltank containing...Ch. 13 - Prob. 53QAPCh. 13 - Prob. 54QAPCh. 13 - Prob. 55QAPCh. 13 - Suppose that a 1.25gsample of neon gas is confined...Ch. 13 - At what temperature will a 1.0gsample of neon gas...Ch. 13 - Prob. 58QAPCh. 13 - What pressure exists in a 200Ltank containing...Ch. 13 - Prob. 60QAPCh. 13 - Suppose a 24.3mLsample of helium gas at 25Cand...Ch. 13 - Prob. 62QAPCh. 13 - Prob. 63QAPCh. 13 - Prob. 64QAPCh. 13 - Prob. 65QAPCh. 13 - Prob. 66QAPCh. 13 - Prob. 67QAPCh. 13 - Suppose than 1.28gof neon gas and 2.49gof argon...Ch. 13 - A tank contains a mixture of 52.5gof oxygen gas...Ch. 13 - What mass of new gas would but required to fill a...Ch. 13 - Prob. 71QAPCh. 13 - Prob. 72QAPCh. 13 - A 500mLsample of O2gas at 24Cwas prepared by...Ch. 13 - Prob. 74QAPCh. 13 - Prob. 75QAPCh. 13 - Prob. 76QAPCh. 13 - Prob. 77QAPCh. 13 - Prob. 78QAPCh. 13 - Prob. 79QAPCh. 13 - Prob. 80QAPCh. 13 - Prob. 81QAPCh. 13 - Prob. 82QAPCh. 13 - Prob. 83QAPCh. 13 - Prob. 84QAPCh. 13 - Calcium oxide can be used to “scrub" carbon...Ch. 13 - Consider the following reaction:...Ch. 13 - Consider the following reaction for the combustion...Ch. 13 - Although we: generally think of combustion...Ch. 13 - m>89. Ammonia and gaseous hydrogen chloride...Ch. 13 - Calcium carbide, CaC2, reacts with water to...Ch. 13 - Prob. 91QAPCh. 13 - Prob. 92QAPCh. 13 - What volume does a mixture of 14.2gof He and...Ch. 13 - Prob. 94QAPCh. 13 - Prob. 95QAPCh. 13 - Consider the following chemical equation:...Ch. 13 - Prob. 97QAPCh. 13 - Dinitrogen monoxide, N2O, reacts with propane,...Ch. 13 - Consider the following unbalanced chemical...Ch. 13 - Prob. 100QAPCh. 13 - Prob. 101QAPCh. 13 - Prob. 102QAPCh. 13 - Prob. 103APCh. 13 - Prob. 104APCh. 13 - Prob. 105APCh. 13 - onsider the flasks in the following diagrams. mg...Ch. 13 - Prob. 107APCh. 13 - helium tank contains 25.2Lof helium m 8.40atm...Ch. 13 - Prob. 109APCh. 13 - Prob. 110APCh. 13 - Prob. 111APCh. 13 - Prob. 112APCh. 13 - Prob. 113APCh. 13 - Prob. 114APCh. 13 - Prob. 115APCh. 13 - Prob. 116APCh. 13 - Prob. 117APCh. 13 - 2.50Lcontainer at 1.00atm and 48Cis filled with...Ch. 13 - Prob. 119APCh. 13 - Prob. 120APCh. 13 - Prob. 121APCh. 13 - Prob. 122APCh. 13 - Prob. 123APCh. 13 - f a gaseous mixture is made of 3.50gof He and...Ch. 13 - Prob. 125APCh. 13 - Prob. 126APCh. 13 - f 5.l2gof oxygen gas occupies a volume of 6.21Lat...Ch. 13 - Prob. 128APCh. 13 - Prob. 129APCh. 13 - Prob. 130APCh. 13 - Prob. 131APCh. 13 - Prob. 132APCh. 13 - t what temperature does 4.00gof helium gas have a...Ch. 13 - Prob. 134APCh. 13 - f 3.20gof nitrogen gas occupies a volume of...Ch. 13 - Prob. 136APCh. 13 - mixture at 33Ccontains H2at 325torr, N2at 475torr,...Ch. 13 - Prob. 138APCh. 13 - Prob. 139APCh. 13 - he following demonstration takes place in a...Ch. 13 - onsider the following unbalanced chemical...Ch. 13 - Prob. 142APCh. 13 - Prob. 143APCh. 13 - Prob. 144APCh. 13 - Prob. 145APCh. 13 - Prob. 146APCh. 13 - Prob. 147APCh. 13 - Prob. 148APCh. 13 - Prob. 149APCh. 13 - omplete the following table for an ideal gas. mg...Ch. 13 - Prob. 151CPCh. 13 - Prob. 152CPCh. 13 - certain flexible weather balloon contains helium...Ch. 13 - Prob. 154CPCh. 13 - Prob. 155CPCh. 13 - Prob. 156CPCh. 13 - Prob. 157CP
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- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 1 2 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Explanation Check Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Priva ×arrow_forwardPredict the products of this organic reaction: Explanation Check IN NaBH3CN H+ ? Click and drag to start drawing a structure. D 5 C +arrow_forwardPredict the products of this organic reaction: H3O+ + ? • Draw all the reasonable products in the drawing area below. If there are no products, because no reaction will occur, check the box under the drawing area. • Include both major and minor products, if some of the products will be more common than others. • Be sure to use wedge and dash bonds if you need to distinguish between enantiomers. No reaction. Click and drag to start drawing a structure. dmarrow_forward
- Iarrow_forwardDraw the anti-Markovnikov product of the hydration of this alkene. this problem. Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for esc esc ☐ Explanation Check F1 1 2 F2 # 3 F3 + $ 14 × 1. BH THE BH3 2. H O NaOH '2 2' Click and drag to start drawing a structure. F4 Q W E R A S D % 905 LL F5 F6 F7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility < & 6 7 27 8 T Y U G H I F8 F9 F10 F11 F12 9 0 J K L P + // command option Z X C V B N M H H rol option commandarrow_forwardAG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, Narrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY