From the given pair, the more reactive ketone has to be identified. Concept introduction: The relative reactivity of carbonyl groups: Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile. An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen. The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.2, Problem 5P

(a)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

(b)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Applications of metal clusters.

Give the product and mechanism for the reaction below. Explain why this reaction is of significance in Forensic Chemistry HO Heat B

Give the product and mechanism for the reaction below. Br NaOEt (Base) A

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.2, Problem 5P

(a)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

(b)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.2, Problem 5P

(a)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

(b)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.2, Problem 5P

(a)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

(b)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 12.2, Problem 5P

(a)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

(b)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Answer 6

Chapter 12.2, Problem 5P

(a)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Answer 7

Chapter 12.2, Problem 5P

(a)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Answer 8

(b)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Answer 9

(b)

Interpretation Introduction

Interpretation:

From the given pair, the more reactive ketone has to be identified.

Concept introduction:

The relative reactivity of carbonyl groups:

Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.

An aldehyde has a greater partial positive charge on its carbonyl carbon than a ketone because an alkyl group is more electrons donating than hydrogen.

The ketones with small alkyl groups bonded to the carbonyl carbon are more reactive than those with large alkyl groups.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 12.1 - Prob. 1P Ch. 12.1 - Name the following compounds:Ch. 12.1 - Prob. 3P Ch. 12.1 - Prob. 4P Ch. 12.2 - Prob. 5P Ch. 12.4 - Draw the structure for each of the following: a....Ch. 12.4 - Prob. 7P Ch. 12.5 - What products are formed when the following...Ch. 12.5 - Prob. 9P Ch. 12.5 - Prob. 10P

Solution Summary: The author explains the relative reactivity of carbonyl groups, which is polar because oxygen is more electronegative than the carbon.

Want to see the full answer?

Chapter 12 Solutions