Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

Essential Organic Chemistry (3rd Edition), Chapter 12, Problem 45P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Essential Organic Chemistry (3rd Edition), Chapter 12, Problem 45P , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Essential Organic Chemistry (3rd Edition), Chapter 12, Problem 45P , additional homework tip  3

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Essential Organic Chemistry (3rd Edition), Chapter 12, Problem 45P , additional homework tip  4

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