The product of the given reaction has to be identified. Concept Introduction: Acetals: Acetals are used to protect the ketone and aldehyde (carbonyl group). In this reaction acetone is protected as acetal by using ethylene glycol. Acetals are less stable compound. In acidic condition, an aldehyde or a ketone reacts with two molecules of alcohol or a molecule of diol to form acetal or cyclic acetal respectively. General scheme:

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Answer 1

Question

Chapter 12, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Acetals:

Acetals are used to protect the ketone and aldehyde (carbonyl group).

In this reaction acetone is protected as acetal by using ethylene glycol. Acetals are less stable compound.

In acidic condition, an aldehyde or a ketone reacts with two molecules of alcohol or a molecule of diol to form acetal or cyclic acetal respectively.

General scheme:

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Complete the spectroscopy with structure

Answer 2

Question

Chapter 12, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Acetals:

Acetals are used to protect the ketone and aldehyde (carbonyl group).

In this reaction acetone is protected as acetal by using ethylene glycol. Acetals are less stable compound.

In acidic condition, an aldehyde or a ketone reacts with two molecules of alcohol or a molecule of diol to form acetal or cyclic acetal respectively.

General scheme:

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.

Expert Solution & Answer

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Answer 3

Question

Chapter 12, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Acetals:

Acetals are used to protect the ketone and aldehyde (carbonyl group).

In this reaction acetone is protected as acetal by using ethylene glycol. Acetals are less stable compound.

In acidic condition, an aldehyde or a ketone reacts with two molecules of alcohol or a molecule of diol to form acetal or cyclic acetal respectively.

General scheme:

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.

Expert Solution & Answer

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Answer 4

Question

Chapter 12, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Acetals:

Acetals are used to protect the ketone and aldehyde (carbonyl group).

In this reaction acetone is protected as acetal by using ethylene glycol. Acetals are less stable compound.

In acidic condition, an aldehyde or a ketone reacts with two molecules of alcohol or a molecule of diol to form acetal or cyclic acetal respectively.

General scheme:

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.

Expert Solution & Answer

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Answer 5

Chapter 12, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Acetals:

Acetals are used to protect the ketone and aldehyde (carbonyl group).

In this reaction acetone is protected as acetal by using ethylene glycol. Acetals are less stable compound.

In acidic condition, an aldehyde or a ketone reacts with two molecules of alcohol or a molecule of diol to form acetal or cyclic acetal respectively.

General scheme:

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.

Answer 6

Chapter 12, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Acetals:

Acetals are used to protect the ketone and aldehyde (carbonyl group).

In this reaction acetone is protected as acetal by using ethylene glycol. Acetals are less stable compound.

In acidic condition, an aldehyde or a ketone reacts with two molecules of alcohol or a molecule of diol to form acetal or cyclic acetal respectively.

General scheme:

Answer 7

Chapter 12, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Acetals:

Acetals are used to protect the ketone and aldehyde (carbonyl group).

In this reaction acetone is protected as acetal by using ethylene glycol. Acetals are less stable compound.

In acidic condition, an aldehyde or a ketone reacts with two molecules of alcohol or a molecule of diol to form acetal or cyclic acetal respectively.

General scheme:

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Imine formation:

Aldehyde or ketone reacts with a primary amine and forms imine in mildly acidic conditions.

Example for the formation of imine is shown here:

Imines contain C=N .

Imines are also called as Schiff bases, named after Hugo Schiff who described their formation.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 12.1 - Prob. 1P Ch. 12.1 - Name the following compounds:Ch. 12.1 - Prob. 3P Ch. 12.1 - Prob. 4P Ch. 12.2 - Prob. 5P Ch. 12.4 - Draw the structure for each of the following: a....Ch. 12.4 - Prob. 7P Ch. 12.5 - What products are formed when the following...Ch. 12.5 - Prob. 9P Ch. 12.5 - Prob. 10P

Solution Summary: The author explains that the product of the given reaction has to be identified.

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.

Want to see the full answer?

Chapter 12 Solutions

Solution Summary: The author explains that the product of the given reaction has to be identified.

Interpretation: The product of the given reaction has to be identified. Concept Introduction: NaBH4 - Sodium borohydride is a reducing agent. It reduces aldehydes, ketones and carboxylic acids into alcohols.

Interpretation: The product of the given reaction has to be identified. Concept Introduction: Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.

Want to see the full answer?

Chapter 12 Solutions

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

NaBH4 - Sodium borohydride is a reducing agent.

It reduces aldehydes, ketones and carboxylic acids into alcohols.

Interpretation:

The product of the given reaction has to be identified.

Concept Introduction:

Carbonyl compounds on treatment with sodium cyanide give cyanohydrin which on further dilution with acid result in carboxylic acid.