Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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These are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. Il a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material(s)! H ?
These are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material(s)! hi ?
These are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material(s)! ? عنی
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