The product for the given reactions has to be determined. Concept introduction: Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group. Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H 2 O . Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Answer 5

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 6

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 7

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - Prob. 1P Ch. 12.1 - Name the following compounds:Ch. 12.1 - Prob. 3P Ch. 12.1 - Prob. 4P Ch. 12.2 - Prob. 5P Ch. 12.4 - Draw the structure for each of the following: a....Ch. 12.4 - Prob. 7P Ch. 12.5 - What products are formed when the following...Ch. 12.5 - Prob. 9P Ch. 12.5 - Prob. 10P

Solution Summary: The author explains that amines are nitrogen-containing organic compounds that react with carbonyl compounds like ketone to form an imine or an enamine.

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Chapter 12 Solutions