Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 12, Problem 48P
12-58 Show how to convert ethylene to these compounds (a) Ethane(b) Ethanol (c) Bromoethane(d) 1,2-Dibromoethane (e) Chloroethane
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13 Draw a structural formula for each compound.
(a) 3-Chloropropene
(b) 3-Methylcyclohexene
(c) 1,2-Dimethylcyclohexene
(d) trans-3,4-Dimethyl-3-heptene
(e) Cyclopropene
(f) 3-Hexyne
Identify the alcohols in Problem 1 as primary, secondary, or tertiary.
3-39
The following names are all incorrect or incomplete, but they represent real structures. Draw each structure and name it
correctly.
(a) 2-ethylpentane
(d) 2-dimethylbutane
(b) 3-isopropylhexane
(e) 2-cyclohexylbutane
(c) 5-chloro-4-methylhexane
(f) 2,3-diethylcyclopentane
Chapter 12 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 12.3 - Prob. 12.1QCCh. 12.3 - Prob. 12.2QCCh. 12.3 - Problem 12-3 Write the IUPAC name for each...Ch. 12.3 - Problem 12-4 Draw structural formulas for the...Ch. 12.3 - Problem 12-5 How many stereoisomers are possible...Ch. 12.5 - Prob. 12.6QCCh. 12.5 - Problem 12-7 Propose a two-step mechanism for the...Ch. 12.5 - Prob. 12.8QCCh. 12.5 - Problem 12-9 Propose a three-step reaction...Ch. 12.5 - Prob. 12.10QC
Ch. 12.8 - Prob. 12.11QCCh. 12 - Prob. 1PCh. 12 - Answer true or false. Both ethylene and acetylene...Ch. 12 - 12-13 What is the difference in structure between...Ch. 12 - There are three compounds with the molecular...Ch. 12 - 12-15 Name and draw structural formulas for all...Ch. 12 - Prob. 6PCh. 12 - Draw a structural formula for at least one...Ch. 12 - Each carbon atom in ethane and in ethylene is...Ch. 12 - Prob. 9PCh. 12 - Prob. 10PCh. 12 - Prob. 11PCh. 12 - 12*22 Draw a structural formula for each compound....Ch. 12 - 12-23 Draw a structural formula for each compound....Ch. 12 - Prob. 14PCh. 12 - 12-25 Write the IUPAC name for each unsaturated...Ch. 12 - Explain why each name is incorrect and then write...Ch. 12 - 12-27 Explain why each name is incorrect and then...Ch. 12 - Prob. 18PCh. 12 - 12-29 Which of these alkenes show cis-trans...Ch. 12 - 12-30 Which of these alkenes shows cis-trans...Ch. 12 - 12-31 Cyclodecene exists as both cis and trans...Ch. 12 - Arachidonic acid is a naturally occurring C„o...Ch. 12 - Prob. 23PCh. 12 - If you examine the structural formulas for the...Ch. 12 - 12*35 For each molecule that shows eis-trans...Ch. 12 - Name and draw structural formulas for all...Ch. 12 - /3-Ocimene, a triene found in the fragrance of...Ch. 12 - Answer true or false. Alkenes and alkynes are...Ch. 12 - Prob. 29PCh. 12 - 12-40 Define alkene addition reaction. Write an...Ch. 12 - Prob. 31PCh. 12 - 12-42 Complete these equations.Ch. 12 - Draw structural formulas for all possible...Ch. 12 - Prob. 34PCh. 12 - 12-45 Draw a structural formula for the product of...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - 12-47 Draw a structural formula for an alkene with...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - Prob. 39PCh. 12 - 12-50 Draw the structural formula of an alkene...Ch. 12 - Prob. 41PCh. 12 - Prob. 42PCh. 12 - Following is the structural formula of...Ch. 12 - Propose an explanation for the following...Ch. 12 - There are nine alkenes with the molecular formula...Ch. 12 - Prob. 46PCh. 12 - 12-57 Hydrocarbon A, Cf,Hs, reacts with 2 moles of...Ch. 12 - 12-58 Show how to convert ethylene to these...Ch. 12 - 12-59 Show how to convert 1-butene to these...Ch. 12 - Prob. 50PCh. 12 - 12-61 (Chemical Connections 12A) What is one...Ch. 12 - Prob. 52PCh. 12 - Prob. 53PCh. 12 - 12-64 (Chemical Connections 120 What is the...Ch. 12 - (Chemical Connections 120 Assume that 1 X IO-12 g...Ch. 12 - Prob. 56PCh. 12 - Prob. 57PCh. 12 - Prob. 58PCh. 12 - Prob. 59PCh. 12 - Prob. 60PCh. 12 - Prob. 61PCh. 12 - Suppose you have unlabeled bottles of benzene and...Ch. 12 - Prob. 63PCh. 12 - Prob. 64PCh. 12 - Answer true or false. (a) Phenols and alcohols...Ch. 12 - Prob. 66PCh. 12 - Prob. 67PCh. 12 - Prob. 68PCh. 12 - Prob. 69PCh. 12 - 12-67 (Chemical Connections 12D ) In which isomer...Ch. 12 - Prob. 71PCh. 12 - Prob. 72PCh. 12 - Prob. 73PCh. 12 - Prob. 74PCh. 12 - Prob. 75PCh. 12 - Prob. 76PCh. 12 - Prob. 77PCh. 12 - Prob. 78PCh. 12 - Prob. 79PCh. 12 - Prob. 80PCh. 12 - Prob. 81PCh. 12 - Prob. 82PCh. 12 - Prob. 83PCh. 12 - Prob. 84PCh. 12 - Prob. 85PCh. 12 - Prob. 86PCh. 12 - Propose a structural formula for the product!s)...Ch. 12 - Prob. 88PCh. 12 - Draw the structural formula of an alkene that...Ch. 12 - 12-77 Show how to convert cyclopentene into these...Ch. 12 - Prob. 91PCh. 12 - Prob. 92PCh. 12 - Prob. 93PCh. 12 - Prob. 94PCh. 12 - Prob. 95PCh. 12 - In omega-3 fatty adds, the last carbon of the last...Ch. 12 - Prob. 97PCh. 12 - Prob. 98P
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- Following is the structural formula of hexabromocyclododecane. This compound was at one time used as a flame retardant in polystyrene foam insulation in buildings, but has now been banned because it had been shown to be toxic to aquatic organisms, and can disrupt thyroid hormone levels in laboratory test animals. In addition, it persists in the environment. Show how this flame retardant could be synthesized from a cycloalkatriene and write the structural formula and IUPAC name of this starting material. Br Hexabromocyclododecanearrow_forward12-77 Show how to convert cyclopentene into these compounds. 1,2-Dibromocyclopentane Cyclopentanol Iodocyclopentane Cyclopentanearrow_forward13-10 Account for the fact that the six-membered ring in benzene is planar but the six-membered ring in cyclohexane is not.arrow_forward
- 8arrow_forward[10] 10] Q1. Do the following conversions as directed. Write the complete reaction equation. (a) Benzaldehyde to Benzoic Acid. (b) Propanal to 1-propanal (c) Cyclohexanone to Cyclohexanol (d) Acetaldehyde to Ethyl alcohol (e) Acetone to Iso-propyl alcoholarrow_forward3. The following alkenes can be prepared by dehydration of an appropriate alcohol. Show the structure of the alcohol in each case. If the alkene can arise from dehydration of more than one alcohol, show all possibilities. CH3CH2 C=CH2 CH3CH2 a) сH-с—снCH,CHз CH3 b) c) 3-hexene d) 1,3-butadienearrow_forward
- please do 13-18arrow_forwardGive the systematic (IUPAC) names of the following alkenes. (а) СH— CH— CH— CH(CH3)2 (b) CH3(CH2)3¬C-CH2CH3 CH2 (c) CH2=CH-CH,–CH=CH2 (d) CH, —С—CH—CH—СH, CH3 (е) (f) (g) CH3 CH2 CH3 (h) .CH3 (j)arrow_forwardDraw a structural formula of an alkene that undergoes acid-catalyzed hydration to give each alcohol as the major product (more than one alkene may give each alcohol as the major product). (a) 3-Hexanol (b) 1-Methylcyclobutanol (c) 2-Methyl-2-butanol (d) 2-Propanolarrow_forward
- 10) What is the name of the major organic product of the following reaction? CH2=CHC(CH3)3 H*, H₂O A) 2,3-dimethyl-1-butanol B) 4-methyl-2-pentanol C) 3,3-dimethyl-1-butanol D) 2,3-dimethyl-2-butanol E) 3,3-dimethyl-2-butanolarrow_forward49 Show how to convert 1-butene to these compounds. (a) Butane (c) 2-Bromobutane (b) 2-Butanol (d) 1,2-Dibromobutanearrow_forward12-14arrow_forward
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