(a) Interpretation: To write the IUPAC name for given structure. Concept Introduction: The rules to write the IUPAC names are as follows- The longest carbon chain is identified, and the root name is given accordingly. All the substituents attached to the root chain are determined. The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions. The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively. All the substituents in the name are written in alphabetical order. For a cyclic hydrocarbon the prefix cyclo - is used.

Question

Q2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol‍¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.

Answer 1

Question

Chapter 12, Problem 14P

Interpretation Introduction

(a)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(b)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(c)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(d)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(e)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(f)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(g)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

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Q2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol‍¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.

13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)! Google

Print Last Name, First Name Initial Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 4th total • 6H total 래 • 4H total 21 total ZH 2H Statistical H < 3° C-H weakest - product abstraction here bund leads to thermo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Product 6 Number of Unique Mono-Chlorinated Products Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary H H-Cl Waterfox

Answer 2

Question

Chapter 12, Problem 14P

Interpretation Introduction

(a)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(b)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(c)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(d)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(e)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(f)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(g)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

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Answer 3

Question

Chapter 12, Problem 14P

Interpretation Introduction

(a)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(b)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(c)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(d)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(e)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(f)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(g)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

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Answer 4

Question

Chapter 12, Problem 14P

Interpretation Introduction

(a)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(b)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(c)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(d)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(e)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(f)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(g)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

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Answer 5

Chapter 12, Problem 14P

Interpretation Introduction

(a)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(b)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(c)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(d)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(e)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(f)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Interpretation Introduction

(g)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 6

Chapter 12, Problem 14P

Interpretation Introduction

(a)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 7

Chapter 12, Problem 14P

Interpretation Introduction

(a)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 8

Interpretation Introduction

(b)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 9

Interpretation Introduction

(b)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 10

Interpretation Introduction

(c)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 11

Interpretation Introduction

(c)

Interpretation:

To write the IUPAC name for given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 12

Interpretation Introduction

(d)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 13

Interpretation Introduction

(d)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 14

Interpretation Introduction

(e)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 15

Interpretation Introduction

(e)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 16

Interpretation Introduction

(f)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 17

Interpretation Introduction

(f)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 18

Interpretation Introduction

(g)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 19

Interpretation Introduction

(g)

Interpretation:

To write the IUPAC name for the given structure.

Concept Introduction:

The rules to write the IUPAC names are as follows-

The longest carbon chain is identified, and the root name is given accordingly.

All the substituents attached to the root chain are determined.

The position of the substituents is so assigned that the sum of their positions comes to be the least of all possible positions.

The prefix di, tri, tetra is used if the same substituent is present two, three and four times respectively.

All the substituents in the name are written in alphabetical order.

For a cyclic hydrocarbon the prefix cyclo- is used.

Answer 20

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Answer 21

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Answer 31

Ch. 12.3 - Prob. 12.1QC Ch. 12.3 - Prob. 12.2QC Ch. 12.3 - Problem 12-3 Write the IUPAC name for each...Ch. 12.3 - Problem 12-4 Draw structural formulas for the...Ch. 12.3 - Problem 12-5 How many stereoisomers are possible...Ch. 12.5 - Prob. 12.6QC Ch. 12.5 - Problem 12-7 Propose a two-step mechanism for the...Ch. 12.5 - Prob. 12.8QC Ch. 12.5 - Problem 12-9 Propose a three-step reaction...Ch. 12.5 - Prob. 12.10QC

Chapter 12 Solutions