(a) Interpretation: The ionic charge with the help of periodic table for Na ion is to be predicted. Concept introduction: The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

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Answer 1

Question

Chapter 12, Problem 12E

Interpretation Introduction

(a)

Interpretation:

The ionic charge with the help of periodic table for Na ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(b)

Interpretation:

The ionic charge with the help of periodic table for Ba ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(c)

Interpretation:

The ionic charge with the help of periodic table for Ga ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(d)

Interpretation:

The ionic charge with the help of periodic table for Pb ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N

4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)

2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)

Answer 2

Question

Chapter 12, Problem 12E

Interpretation Introduction

(a)

Interpretation:

The ionic charge with the help of periodic table for Na ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(b)

Interpretation:

The ionic charge with the help of periodic table for Ba ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(c)

Interpretation:

The ionic charge with the help of periodic table for Ga ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(d)

Interpretation:

The ionic charge with the help of periodic table for Pb ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

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Answer 3

Question

Chapter 12, Problem 12E

Interpretation Introduction

(a)

Interpretation:

The ionic charge with the help of periodic table for Na ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(b)

Interpretation:

The ionic charge with the help of periodic table for Ba ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(c)

Interpretation:

The ionic charge with the help of periodic table for Ga ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(d)

Interpretation:

The ionic charge with the help of periodic table for Pb ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

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Answer 4

Question

Chapter 12, Problem 12E

Interpretation Introduction

(a)

Interpretation:

The ionic charge with the help of periodic table for Na ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(b)

Interpretation:

The ionic charge with the help of periodic table for Ba ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(c)

Interpretation:

The ionic charge with the help of periodic table for Ga ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(d)

Interpretation:

The ionic charge with the help of periodic table for Pb ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

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Answer 5

Chapter 12, Problem 12E

Interpretation Introduction

(a)

Interpretation:

The ionic charge with the help of periodic table for Na ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(b)

Interpretation:

The ionic charge with the help of periodic table for Ba ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(c)

Interpretation:

The ionic charge with the help of periodic table for Ga ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Interpretation Introduction

(d)

Interpretation:

The ionic charge with the help of periodic table for Pb ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Answer 6

Chapter 12, Problem 12E

Interpretation Introduction

(a)

Interpretation:

The ionic charge with the help of periodic table for Na ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Answer 7

Chapter 12, Problem 12E

Interpretation Introduction

(a)

Interpretation:

The ionic charge with the help of periodic table for Na ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The ionic charge with the help of periodic table for Ba ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The ionic charge with the help of periodic table for Ba ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The ionic charge with the help of periodic table for Ga ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The ionic charge with the help of periodic table for Ga ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The ionic charge with the help of periodic table for Pb ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The ionic charge with the help of periodic table for Pb ion is to be predicted.

Concept introduction:

The ionic charge is the electrical charge on an ion which occurs due to the gain or loss of one or more electron from an atom or group of atoms. When an atom gains an electron the negative charge develops on an atom and when it loses an electron the species become positively charged.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12 - Prob. 1CE Ch. 12 - Prob. 2CE Ch. 12 - Prob. 3CE Ch. 12 - Prob. 4CE Ch. 12 - Prob. 5CE Ch. 12 - Prob. 6CE Ch. 12 - Prob. 7CE Ch. 12 - Prob. 8CE Ch. 12 - Prob. 9CE Ch. 12 - Prob. 10CE

Solution Summary: The author explains the ionic charge with the help of periodic table for Na.

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