The product formed on reduction of below compound has to be drawn. Concept introduction: Reduction of disulfides: Thiols are organic compounds which contain a sulfhydryl group (SH group) bonded to atetrahedral carbon. Thiols differ from alcohols, as they are incapable of intermolecular hydrogen bonding. This gives thiols lower boiling points and melting points than alcohols even though having the same size and shape. In the presence of hydrogen, disulfides are reduced to thiols by gaining hydrogen atoms.

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Answer 1

Question

Chapter 12, Problem 12.72AP

a.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn.

Concept introduction:

Reduction of disulfides:

Thiols are organic compounds which contain a sulfhydryl group (SH group) bonded to atetrahedral carbon. Thiols differ from alcohols, as they are incapable of intermolecular hydrogen bonding. This gives thiols lower boiling points and melting points than alcohols even though having the same size and shape.

In the presence of hydrogen, disulfides are reduced to thiols by gaining hydrogen atoms.

b.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn

Concept introduction:

Refer to part “a.”.

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Answer 2

Question

Chapter 12, Problem 12.72AP

a.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn.

Concept introduction:

Reduction of disulfides:

Thiols are organic compounds which contain a sulfhydryl group (SH group) bonded to atetrahedral carbon. Thiols differ from alcohols, as they are incapable of intermolecular hydrogen bonding. This gives thiols lower boiling points and melting points than alcohols even though having the same size and shape.

In the presence of hydrogen, disulfides are reduced to thiols by gaining hydrogen atoms.

b.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn

Concept introduction:

Refer to part “a.”.

Expert Solution & Answer

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Answer 3

Question

Chapter 12, Problem 12.72AP

a.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn.

Concept introduction:

Reduction of disulfides:

Thiols are organic compounds which contain a sulfhydryl group (SH group) bonded to atetrahedral carbon. Thiols differ from alcohols, as they are incapable of intermolecular hydrogen bonding. This gives thiols lower boiling points and melting points than alcohols even though having the same size and shape.

In the presence of hydrogen, disulfides are reduced to thiols by gaining hydrogen atoms.

b.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn

Concept introduction:

Refer to part “a.”.

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Answer 4

Question

Chapter 12, Problem 12.72AP

a.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn.

Concept introduction:

Reduction of disulfides:

Thiols are organic compounds which contain a sulfhydryl group (SH group) bonded to atetrahedral carbon. Thiols differ from alcohols, as they are incapable of intermolecular hydrogen bonding. This gives thiols lower boiling points and melting points than alcohols even though having the same size and shape.

In the presence of hydrogen, disulfides are reduced to thiols by gaining hydrogen atoms.

b.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn

Concept introduction:

Refer to part “a.”.

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Answer 5

Chapter 12, Problem 12.72AP

a.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn.

Concept introduction:

Reduction of disulfides:

Thiols are organic compounds which contain a sulfhydryl group (SH group) bonded to atetrahedral carbon. Thiols differ from alcohols, as they are incapable of intermolecular hydrogen bonding. This gives thiols lower boiling points and melting points than alcohols even though having the same size and shape.

In the presence of hydrogen, disulfides are reduced to thiols by gaining hydrogen atoms.

b.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn

Concept introduction:

Refer to part “a.”.

Answer 6

Chapter 12, Problem 12.72AP

a.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn.

Concept introduction:

Reduction of disulfides:

Thiols are organic compounds which contain a sulfhydryl group (SH group) bonded to atetrahedral carbon. Thiols differ from alcohols, as they are incapable of intermolecular hydrogen bonding. This gives thiols lower boiling points and melting points than alcohols even though having the same size and shape.

In the presence of hydrogen, disulfides are reduced to thiols by gaining hydrogen atoms.

Answer 7

Chapter 12, Problem 12.72AP

a.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn.

Concept introduction:

Reduction of disulfides:

Thiols are organic compounds which contain a sulfhydryl group (SH group) bonded to atetrahedral carbon. Thiols differ from alcohols, as they are incapable of intermolecular hydrogen bonding. This gives thiols lower boiling points and melting points than alcohols even though having the same size and shape.

In the presence of hydrogen, disulfides are reduced to thiols by gaining hydrogen atoms.

Answer 8

b.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn

Concept introduction:

Refer to part “a.”.

Answer 9

b.

Interpretation Introduction

Interpretation:

The product formed on reduction of below compound has to be drawn

Concept introduction:

Refer to part “a.”.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - a. Label the hydroxyl groups, thiols, halogens,...Ch. 12.1 - Draw out each compound to clearly show what groups...Ch. 12.2 - Classify each alcohol as 1, 2, or 3.Ch. 12.2 - Classify each hydroxyl group in sorbitol as 1, 2,...Ch. 12.2 - Which compound in each pair has the higher boiling...Ch. 12.2 - Label each compound as water soluble or water...Ch. 12.2 - Give the IUPAC name for each compound.Ch. 12.2 - Give the structure corresponding to each name. a....Ch. 12.3 - Name each ether. a. CH3OCH2CH2CH2CH3 b....Ch. 12.3 - Prob. 12.10P

Interpretation: The product formed on reduction of below compound has to be drawn Concept introduction: Refer to part “a.”.

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Chapter 12 Solutions

Interpretation:

The product formed on reduction of below compound has to be drawn

Concept introduction:

Refer to part “a.”.