For a given ketone compound, IUPAC name has to be derived. Concept Introduction: Naming of ketones : Firstly, the functional group from the below structure will be identified as ketone and –one is added as the suffix. Subsequently find the longest carbon chain, which is bonded with the ketone group. In case of the cyclic compounds, numbering starts with ketone group attached carbon, which is considered a primary carbon. Prefix changes if any other substituents are present in the structure other than ketone group. In case of more than one substituents naming will be given in alphabetical order.

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Answer 1

Question

Chapter 12.8, Problem 12.21P

a.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept Introduction:

Naming of ketones:

Firstly, the functional group from the below structure will be identified as ketone and –one is added as the suffix. Subsequently find the longest carbon chain, which is bonded with the ketone group. In case of the cyclic compounds, numbering starts with ketone group attached carbon, which is considered a primary carbon. Prefix changes if any other substituents are present in the structure other than ketone group. In case of more than one substituents naming will be given in alphabetical order.

b.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 12.8, Problem 12.21P

a.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept Introduction:

Naming of ketones:

Firstly, the functional group from the below structure will be identified as ketone and –one is added as the suffix. Subsequently find the longest carbon chain, which is bonded with the ketone group. In case of the cyclic compounds, numbering starts with ketone group attached carbon, which is considered a primary carbon. Prefix changes if any other substituents are present in the structure other than ketone group. In case of more than one substituents naming will be given in alphabetical order.

b.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

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Answer 3

Question

Chapter 12.8, Problem 12.21P

a.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept Introduction:

Naming of ketones:

Firstly, the functional group from the below structure will be identified as ketone and –one is added as the suffix. Subsequently find the longest carbon chain, which is bonded with the ketone group. In case of the cyclic compounds, numbering starts with ketone group attached carbon, which is considered a primary carbon. Prefix changes if any other substituents are present in the structure other than ketone group. In case of more than one substituents naming will be given in alphabetical order.

b.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

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Answer 4

Question

Chapter 12.8, Problem 12.21P

a.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept Introduction:

Naming of ketones:

Firstly, the functional group from the below structure will be identified as ketone and –one is added as the suffix. Subsequently find the longest carbon chain, which is bonded with the ketone group. In case of the cyclic compounds, numbering starts with ketone group attached carbon, which is considered a primary carbon. Prefix changes if any other substituents are present in the structure other than ketone group. In case of more than one substituents naming will be given in alphabetical order.

b.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

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Answer 5

Chapter 12.8, Problem 12.21P

a.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept Introduction:

Naming of ketones:

Firstly, the functional group from the below structure will be identified as ketone and –one is added as the suffix. Subsequently find the longest carbon chain, which is bonded with the ketone group. In case of the cyclic compounds, numbering starts with ketone group attached carbon, which is considered a primary carbon. Prefix changes if any other substituents are present in the structure other than ketone group. In case of more than one substituents naming will be given in alphabetical order.

b.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

c.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

Answer 6

Chapter 12.8, Problem 12.21P

a.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept Introduction:

Naming of ketones:

Firstly, the functional group from the below structure will be identified as ketone and –one is added as the suffix. Subsequently find the longest carbon chain, which is bonded with the ketone group. In case of the cyclic compounds, numbering starts with ketone group attached carbon, which is considered a primary carbon. Prefix changes if any other substituents are present in the structure other than ketone group. In case of more than one substituents naming will be given in alphabetical order.

Answer 7

Chapter 12.8, Problem 12.21P

a.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept Introduction:

Naming of ketones:

Firstly, the functional group from the below structure will be identified as ketone and –one is added as the suffix. Subsequently find the longest carbon chain, which is bonded with the ketone group. In case of the cyclic compounds, numbering starts with ketone group attached carbon, which is considered a primary carbon. Prefix changes if any other substituents are present in the structure other than ketone group. In case of more than one substituents naming will be given in alphabetical order.

Answer 8

b.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

Answer 9

b.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

Answer 10

c.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

Answer 11

c.

Interpretation Introduction

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 12.1 - a. Label the hydroxyl groups, thiols, halogens,...Ch. 12.1 - Draw out each compound to clearly show what groups...Ch. 12.2 - Classify each alcohol as 1, 2, or 3.Ch. 12.2 - Classify each hydroxyl group in sorbitol as 1, 2,...Ch. 12.2 - Which compound in each pair has the higher boiling...Ch. 12.2 - Label each compound as water soluble or water...Ch. 12.2 - Give the IUPAC name for each compound.Ch. 12.2 - Give the structure corresponding to each name. a....Ch. 12.3 - Name each ether. a. CH3OCH2CH2CH2CH3 b....Ch. 12.3 - Prob. 12.10P

Solution Summary: The author explains how the IUPAC name is derived for a given ketone compound.

Videos

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

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Chapter 12 Solutions

Solution Summary: The author explains how the IUPAC name is derived for a given ketone compound.

Videos

Interpretation: For a given ketone compound, IUPAC name has to be derived. Concept introduction: Refer to part a.

Interpretation: For a given ketone compound, IUPAC name has to be derived. Concept introduction: Refer to part a.

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Chapter 12 Solutions

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.

Interpretation:

For a given ketone compound, IUPAC name has to be derived.

Concept introduction:

Refer to part a.