A gaseous material XY( g ) dissociates to some extent to produce X( g ) and Y( g ): XY ( g ) ⇌ X ( g ) + Y ( g ) A 2.00-g sample of XY (molar mass = 165 g/mol) is placed in a container with a movable piston at 25°C. The pressure is held constant at 0.967 atm. As XY begins to dissociate, the piston moves until 35.0 mole percent of the original XY has dissociated and then remains at a constant position. Assuming ideal behavior, calculate the density of the gas in the container after the piston has stopped moving, and determine the value of K for this reaction of 25°C.
A gaseous material XY( g ) dissociates to some extent to produce X( g ) and Y( g ): XY ( g ) ⇌ X ( g ) + Y ( g ) A 2.00-g sample of XY (molar mass = 165 g/mol) is placed in a container with a movable piston at 25°C. The pressure is held constant at 0.967 atm. As XY begins to dissociate, the piston moves until 35.0 mole percent of the original XY has dissociated and then remains at a constant position. Assuming ideal behavior, calculate the density of the gas in the container after the piston has stopped moving, and determine the value of K for this reaction of 25°C.
Solution Summary: The author explains how the equilibrium constant K describes the ratio of the reactant to the product on equilibrium conditions in terms of molar concentration.
A gaseous material XY(g) dissociates to some extent to produce X(g) and Y(g):
XY
(
g
)
⇌
X
(
g
)
+
Y
(
g
)
A 2.00-g sample of XY (molar mass = 165 g/mol) is placed in a container with a movable piston at 25°C. The pressure is held constant at 0.967 atm. As XY begins to dissociate, the piston moves until 35.0 mole percent of the original XY has dissociated and then remains at a constant position. Assuming ideal behavior, calculate the density of the gas in the container after the piston has stopped moving, and determine the value of K for this reaction of 25°C.
Laser. Indicate the relationship between metastable state and stimulated emission.
The table includes macrostates characterized by 4 energy levels (&) that are
equally spaced but with different degrees of occupation.
a) Calculate the energy of all the macrostates (in joules). See if they all have
the same energy and number of particles.
b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell