The difference between the terms ‘ K ’ and ‘ K p ’ is to be stated. The condition when these are equal and when they are unequal is to be determined. The new value of K if the coefficients in a reaction are tripled and the new value of K p if an equation is reversed is to be determined. Concept introduction: When the equilibrium constant is expressed in terms of concentration, it is represented as K . When the equilibrium constant is expressed in terms of pressure, it is represented as K p . To determine: The difference between the terms ‘ K ’ and ‘ K p ’; the condition when these are equal and when they are unequal and the new value of K if the coefficients in a reaction are tripled and the new value of K p if an equation is reversed.
The difference between the terms ‘ K ’ and ‘ K p ’ is to be stated. The condition when these are equal and when they are unequal is to be determined. The new value of K if the coefficients in a reaction are tripled and the new value of K p if an equation is reversed is to be determined. Concept introduction: When the equilibrium constant is expressed in terms of concentration, it is represented as K . When the equilibrium constant is expressed in terms of pressure, it is represented as K p . To determine: The difference between the terms ‘ K ’ and ‘ K p ’; the condition when these are equal and when they are unequal and the new value of K if the coefficients in a reaction are tripled and the new value of K p if an equation is reversed.
Solution Summary: The author explains the difference between the terms K and K_p.
Interpretation: The difference between the terms ‘
K’ and ‘
Kp’ is to be stated. The condition when these are equal and when they are unequal is to be determined. The new value of
K if the coefficients in a reaction are tripled and the new value of
Kp if an equation is reversed is to be determined.
Concept introduction: When the equilibrium constant is expressed in terms of concentration, it is represented as
K. When the equilibrium constant is expressed in terms of pressure, it is represented as
Kp.
To determine: The difference between the terms ‘
K’ and ‘
Kp’; the condition when these are equal and when they are unequal and the new value of
K if the coefficients in a reaction are tripled and the new value of
Kp if an equation is reversed.
22.22 For each compound, indicate which group on the ring is more strongly activating and then
draw a structural formula of the major product formed by nitration of the compound.
Br
CHO
(a)
CH3
(b)
(c)
CHO
CH3
SO₂H
(d)
☑
OCHS
NO₂
(e)
(f)
CO₂H
NHCOCH3
NHCOCH,
(h)
CHS
22.23 The following molecules each contain two aromatic rings.
(b)
000-100-
H3C
(a)
(c)
Which ring in each undergoes electrophilic aromatic substitution more readily? Draw
the major product formed on nitration.
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