
(a)
Interpretation: To identify the products of following reactions when new groups in tetrahedral intermediate is a stronger base than the group that attached group in acyl group.
Concept introduction: The
The basicity comparison can be done by using the
(b)
Interpretation: To identify the products of following reactions when new groups in tetrahedral intermediate is a weaker base than the group that attached group in acyl group.
Concept introduction: The carboxylic acid and its derivatives undergo nucleophilic acyl substitution reaction. The incoming group is called as nucleophile and the substituent that departs from molecule is known as leaving group. If the attacking group is a good base as compared to the substiuent that is already present than attacking group will replace the existing substituent.
The basicity comparison can be done by using the
(c)
Interpretation: To identify the products of following reactions when new groups in tetrahedral intermediate is similar in basicity to the group that attached group in acyl group
Concept introduction: The carboxylic acid and its derivatives undergo nucleophilic acyl substitution reaction. The incoming group is called as nucleophile and the substituent that departs from molecule is known as leaving group. If the attacking group is a good base as compared to the substiuent that is already present than attacking group will replace the existing substituent.
The basicity comparison can be done by using the

Want to see the full answer?
Check out a sample textbook solution
Chapter 11 Solutions
Essential Organic Chemistry (3rd Edition)
- Calculate the ionization energy of He+ and Li²+ ions in their ground states. Thannnxxxxx sirrr Ahehehehehejh27278283-4;*; shebehebbw $+$;$-;$-28283773838 hahhehdvaarrow_forwardPlleeaasseee solllveeee question 3 andd thankss sirr, don't solve it by AI plleeaasseee don't use AIarrow_forwardCalculate the chemical shifts in 13C and 1H NMR for 4-chloropropiophenone ? Write structure and label hydrogens and carbonsarrow_forward
- 4. Read paragraph 4.15 from your textbook, use your calculated lattice energy values for CuO, CuCO3 and Cu(OH)2 an explain thermal decomposition reaction of malachite: Cu2CO3(OH)2 →2CuO + H2O + CO2 (3 points)arrow_forwardPlease sirrr soollveee these parts pleaseeee and thank youuuuuarrow_forwardIII O Organic Chemistry Using wedges and dashes in skeletal structures Draw a skeletal ("line") structure for each of the molecules below. Be sure your structures show the important difference between the molecules. key O O O O O CHON Cl jiii iiiiiiii You can drag the slider to rotate the molecules. Explanation Check Click and drag to start drawing a structure. Q Search X G ©2025 McGraw Hill LLC. All Rights Reserved. Terms of Use F 3 W C 3/5arrow_forward
- 3. Use Kapustinskii's equation and data from Table 4.10 in your textbook to calculate lattice energies of Cu(OH)2 and CuCO3 (4 points)arrow_forward2. Copper (II) oxide crystalizes in monoclinic unit cell (included below; blue spheres 2+ represent Cu²+, red - O²-). Use Kapustinski's equation (4.5) to calculate lattice energy for CuO. You will need some data from Resource section of your textbook (p.901). (4 points) CuOarrow_forwardWhat is the IUPAC name of the following compound? OH (2S, 4R)-4-chloropentan-2-ol O (2R, 4R)-4-chloropentan-2-ol O (2R, 4S)-4-chloropentan-2-ol O(2S, 4S)-4-chloropentan-2-olarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
