The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found. Concept Introduction: Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups. Example: The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

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Answer 1

Question

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

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In the video, we looked at the absorbance of a certain substance and how it varies depending on what wavelength of light we are looking at. Below is a similar scan of a different substance. What color BEST describes how this substance will appear? Absorbance (AU) Violet Blue Green Orange 1.2 1.0- 0.8- 0.6- 0.4- 0.2 0.0 450 500 550 600 650 700 Wavelength (nm) violet indigo blue green yellow orange red Red O Cannot tell from this information In the above graph, what causes -450 nm wavelength of light to have a higher absorbance than light with a -550 nm wavelength? Check all that are true. The distance the light travels is different The different data points are for different substances The concentration is different at different times in the experiment Epsilon (molar absortivity) is different at different wavelengths

5. a. Data were collected for Trial 1 to determine the molar mass of a nonvolatile solid solute when dissolved in cyclo- hexane. Complete the table for the analysis (See Report Sheet). Record calculated values with the correct number of significant figures. B. Freezing Point of Cyclohexane plus Calculation Zone Unknown Solute 2. Mass of cyclohexane (g) 10.14 Part C.4 3. Mass of added solute (g) 0.255 C. Calculations 1. k; for cyclohexane (°C⚫ kg/mol) 20.0 2. Freezing point change, AT, (°C) 3.04 Part C.6 3. Mass of cyclohexane in solution (kg) 4. Moles of solute, total (mol) Show calculation. 5. Mass of solute in solution, total (g) 6. Molar mass of solute (g/mol) Show calculation.

Answer 2

Question

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

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Answer 3

Question

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

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Answer 4

Question

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

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Answer 5

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

Answer 6

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

Answer 7

Chapter 11.14, Problem 28P

(a)

Interpretation Introduction

Interpretation:

The acyl chloride and carboxylate ion that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

The acetyl chloride and carboxylate ion that could be used to form any given mixed anhydride can be analysed using the simple retro analysis as shown here:

Answer 8

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

Answer 9

(b)

Interpretation Introduction

Interpretation:

The other reagents that could be used to form the given mixed anhydride have to be found.

Concept Introduction:

Mixed anhydrides are unsymmetrical anhydrides which have different alkyl groups.

Example:

Any anhydride can be obtained using the following two pairs of reagents:

1. Acetyl chloride and a carboxylate ion.

2. Two different carboxylic acids if mixed or unsymmetrical anhydride has to be formed or two same carboxylic acids if symmetrical anhydride has to be formed.

For any simple anhydride, the two carboxylic acids from which it has been formed can be found by the simple retro analysis as shown here:

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11.1 - The aromas of many flowers and fruits are due to...Ch. 11.1 - Name the following compounds:Ch. 11.1 - Prob. 3P Ch. 11.2 - Prob. 4P Ch. 11.2 - Prob. 5P Ch. 11.4 - a. What is the product of the reaction of acetyl...Ch. 11.4 - Prob. 7P Ch. 11.5 - Using the pKa values listed in Table 11.1, predict...Ch. 11.6 - Starting with acetyl chloride, what neutral...Ch. 11.6 - Prob. 10P

Solution Summary: The author explains how acetyl chloride and carboxylate ion can be used to form a mixed anhydride.

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