Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 11.13, Problem 24P

(a)

Interpretation Introduction

Interpretation: Two names of the given nitriles has to be written.

  Concept introduction: The naming of nitriles can be done in two different ways:

First method is used to write the systematic name of these compounds. The systematic name of nitriles is written by adding the ‘nitrile’ in the suffix of parent name of alkane chain. The carbon atom of CN group is also counted in the longest carbon chain to write the parent name of alkane

Second method is used to write the common name of these compounds. The common name of these compounds is written by replacing the “ic acid” of carboxylic acid by “nitrile”. These compounds also can be written as alkyl cyanides.

(b)

Interpretation Introduction

Interpretation:

Two names of the given nitriles is to be written.

  Concept introduction:

  The naming of nitriles can be done in two different ways:

First method is used to write the systematic name of these compounds. The systematic name of nitriles is written by adding the ‘nitrile’ in the suffix of parent name of alkane chain. The carbon atom of CN group is also counted in the longest carbon chain to write the parent name of alkane

Second method is used to write the common name of these compounds. The common name of these compounds is written by replacing the “ic acid” of carboxylic acid by “nitrile”. These compounds also can be written as alkyl cyanides.

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Naming the Alkanes a) Write the IUPAC nomenclature of the compound below b) Draw 4-isopropyl-2,4,5-trimethylheptane, identify the primary, secondary, tertiary, and quaternary carbons. c) Rank pentane, neopentane and isopentane for boiling point. pentane: H3C-CH2-CH2-CH2-CH3 neopentane: CH3 H3C-Ċ-CH3 I CH3 isopentane: CH3 H3C-CH2-CH-CH3
Which will evaporate faster, 1-Butanol or Pentane? Explain your choice.
Using the equation below, what is the rate of this reaction if the rate of disappearance of H2 is 0.44 M/sec? H2 + Br2 → 2HBr

Chapter 11 Solutions

Essential Organic Chemistry (3rd Edition)

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