Essential Organic Chemistry (3rd Edition)

3rd Edition

ISBN: 9780321937711

Author: Paula Yurkanis Bruice

Publisher: PEARSON

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Textbook Question

Chapter 11.4, Problem 6P

a. What is the product of the reaction of acetyl chloride with HO−? The pK_a of HCl is −7; the pK_a of H₂O is 15.7.
b. What is the product of the reaction of acetamide with HO−? The pK_a of NH₃ is 36; the pK_a of H₂O is 15.7.

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Chapter 11.2, Problem 5P

Chapter 11.4, Problem 7P

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Chapter 11 Solutions

Essential Organic Chemistry (3rd Edition)

Ch. 11.1 - The aromas of many flowers and fruits are due to...Ch. 11.1 - Name the following compounds:Ch. 11.1 - Prob. 3P Ch. 11.2 - Prob. 4P Ch. 11.2 - Prob. 5P Ch. 11.4 - a. What is the product of the reaction of acetyl...Ch. 11.4 - Prob. 7P Ch. 11.5 - Using the pKa values listed in Table 11.1, predict...Ch. 11.6 - Starting with acetyl chloride, what neutral...Ch. 11.6 - Prob. 10P

Ch. 11.7 - Prob. 11P Ch. 11.8 - Prob. 13P Ch. 11.8 - Using the mechanism for the acidcatalyzed...Ch. 11.8 - Prob. 15P Ch. 11.8 - Prob. 16P Ch. 11.8 - Prob. 17P Ch. 11.9 - Prob. 18P Ch. 11.10 - Show how each of the following esters could be...Ch. 11.11 - Which of the following reactions would lead to the...Ch. 11.12 - Prob. 22P Ch. 11.12 - Prob. 23P Ch. 11.13 - Prob. 24P Ch. 11.13 - Prob. 25P Ch. 11.14 - Prob. 26P Ch. 11.14 - Prob. 27P Ch. 11.14 - Prob. 28P Ch. 11.15 - Prob. 29P Ch. 11.15 - How would you synthesize the following compounds...Ch. 11 - Write a structure for each of the following a. N,N...Ch. 11 - Prob. 32P Ch. 11 - Which ester is more reactive, methyl acetate or...Ch. 11 - What products would be formed from the reaction of...Ch. 11 - What products would be obtained from the following...Ch. 11 - Prob. 36P Ch. 11 - a. Which compound would you expect to have a...Ch. 11 - a. List the following esters in order of...Ch. 11 - D. N. Kursanov, a Russian chemist, proved that the...Ch. 11 - Prob. 40P Ch. 11 - Using an alcohol for one method and an alkyl...Ch. 11 - Prob. 42P Ch. 11 - Prob. 44P Ch. 11 - Prob. 45P Ch. 11 - Prob. 46P Ch. 11 - Prob. 47P Ch. 11 - Prob. 48P Ch. 11 - Prob. 49P Ch. 11 - Show how the following compounds could be prepared...Ch. 11 - Prob. 51P Ch. 11 - Prob. 52P Ch. 11 - Prob. 53P

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a. What is the product of the reaction of acetyl chloride with HO−? The p K a of HCl is −7; the p K a of H 2 O is 15.7. b. What is the product of the reaction of acetamide with HO−? The p K a of NH 3 is 36; the p K a of H 2 O is 15.7.

Solution Summary: The author explains that the products of the reaction between acetyl chloride and OH- are to be identified.

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Chapter 11 Solutions