Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 11.2, Problem 4P
Interpretation Introduction
Interpretation: To choose the correct option of the given statements.
Concept introduction:
Delocalization energy is nothing else it is the energy released when deloclization
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FLAVORANTS: Identify the aldehyde and ketone-containing flavoring compound from each
following sources. Choose your best answer from the choices below
A. 2-Octanone
B. Citral
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D. Vanillin
E. Cinnamaldehyde
F. a-Damascone
1. Вerry
2. Mushroom
3. Lemongrass
4. Cinnamon
5. Almonds
Idchyde or ketone formed fro
он
C-H
ÓR
Compound that contains a group like that shown above.
a. acetal
Ob. aldehyde
c. Benedict's reagent
d. carbonyl
Oe. hemiacetal
Of. hemiketal
Og. hydrolysis
h. ketal
i. ketone
Oj. Tollen's reagent
2.
OH
15. CH3-C-H
ÓCH,
The compound above is an example of a(n)
a. acetal
b. ketal
O c. hemiacetal
d. hemiketal
e. none of the above
Chapter 11 Solutions
Essential Organic Chemistry, Global Edition
Ch. 11.1 - The aromas of many flowers and fruits are due to...Ch. 11.1 - Name the following compounds:Ch. 11.1 - Prob. 3PCh. 11.2 - Prob. 4PCh. 11.2 - Prob. 5PCh. 11.4 - a. What is the product of the reaction of acetyl...Ch. 11.4 - Prob. 7PCh. 11.5 - Using the pKa values listed in Table 11.1, predict...Ch. 11.6 - Starting with acetyl chloride, what neutral...Ch. 11.6 - Prob. 10P
Ch. 11.7 - Prob. 11PCh. 11.8 - Prob. 13PCh. 11.8 - Using the mechanism for the acidcatalyzed...Ch. 11.8 - Prob. 15PCh. 11.8 - Prob. 16PCh. 11.8 - Prob. 17PCh. 11.9 - Prob. 18PCh. 11.10 - Show how each of the following esters could be...Ch. 11.11 - Which of the following reactions would lead to the...Ch. 11.12 - Prob. 22PCh. 11.12 - Prob. 23PCh. 11.13 - Prob. 24PCh. 11.13 - Prob. 25PCh. 11.14 - Prob. 26PCh. 11.14 - Prob. 27PCh. 11.14 - Prob. 28PCh. 11.15 - Prob. 29PCh. 11.15 - How would you synthesize the following compounds...Ch. 11 - Write a structure for each of the following a. N,N...Ch. 11 - Prob. 32PCh. 11 - Which ester is more reactive, methyl acetate or...Ch. 11 - What products would be formed from the reaction of...Ch. 11 - What products would be obtained from the following...Ch. 11 - Prob. 36PCh. 11 - a. Which compound would you expect to have a...Ch. 11 - a. List the following esters in order of...Ch. 11 - D. N. Kursanov, a Russian chemist, proved that the...Ch. 11 - Prob. 40PCh. 11 - Using an alcohol for one method and an alkyl...Ch. 11 - Prob. 42PCh. 11 - Prob. 44PCh. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - Prob. 47PCh. 11 - Prob. 48PCh. 11 - Prob. 49PCh. 11 - Show how the following compounds could be prepared...Ch. 11 - Prob. 51PCh. 11 - Prob. 52PCh. 11 - Prob. 53P
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- 53. Which statement below is incorrect? а. the smallest aldehyde has the formula HCOH b. a carbonyl carbon consists of a carbon-oxygen double bond in an aldehyde, the carbonyl carbon is always bonded to a hydrogen atom с. d. Ketones are more soluble in water than alcohols with the equiva lent number of carbonsarrow_forward1. Answer Only True or False? Ketones can be oxidized by Tollen's reagent? True False Refer to the following mixtures: Mixture A: Liquid and solid mixture Mixture B. Liquid mixture whose boiling points are similar. Mixture C. Liquid mixture with high boiling point. Mixture D. Heat sensitive liquid mixture. Which of the following distillation can be applied for Mixture C? vacuum distillation fractional distillation simple distillation none of these In the experiment synthesis of acetyl salicylic acid, what is the purpose of adding water after salicylic acid and acetic anhydride reacted? the destroy the unreacted salicylic acid the destroy the unreacted acetic anhydride to increase the yield of the reaction to dilute the sulfuric acid ————— What smell/odor is expected for the complete reaction of benzyl alcohol and formic acid in the presence of catalytic amount of sulfuric acid? pineapple smell orange smell banana smell wintergreen smell finger nail polish smell…arrow_forward50. If this molecule was heated, which carboxyl group will be readily lost as carbon dioxid. C HO2C CO2H CO2H HO2C B a. b. B C. C d.arrow_forward
- 1. Which functional group is found in aldehydes? a. CHO b. -CH;OH c. -COOH d. RCOR' 2. Which functional group is found in ketones? a. -CHO CH:OH c. -COOH RCOR' 3. Which structural feature is common to aldehydes and ketones? a, an oxygen atom bonded to both a carbon atom and a hydrogen atom b. an oxygen atom bonded to two carbon atoms c. an oxygen atom double bonded to a carbon atom d. two oxygen atoms bonded to the same carbon atom 4. What is the IUPAC name for the following compound? a. I-pentaldehyde b. l-pentanal c. pentanal d. pentanealdehyde Cetoa of Fiarrow_forwardWhich is propyl propanoate? A. CH₂CH₂CH₂OOCCH₂CH; B. CH₂CH₂CH₂COOCH₂CH₂ C. CH₂CH₂CH₂COCH₂CH₂ D. CHỊCH,CH,OCH,CHỊCH, A B C Darrow_forward1. Which is more reactive? a. carboxylic acid b. acid anhydride c. acid halide d. amides e. esters 2. Removal of water? a. carboxylic acid b. acid anhydride c. acid halide d. amides e. esters 3. Condensation of alcohol and RCOOH? a. carboxylic acid b. acid anhydride c. acid halide d. amides e. estersarrow_forward
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- What is the systematic IUPAC name for the given compound? CH3 CH3 CH;CHCH,CH,CH2 -Ń-CH3 a. N-methyl-4-methylhexan-1-amine b. 2,4-dimethylhexan-1-amine c. 2,2,N-trimethylpentan-1-amine d. N,N,4-trimethylpentan-1-aminearrow_forward32. Which of these generic structures denotes a ketone? E. I RCH F. I RCOH C. R-O-R' D. R-NH-R' G. RCR A. R-CI B. R-OH 33. Which of these generic structures denotes an ester? E. I RCH F. I RCOH G. I RCR A. R-CI B. R-OH C. R-O-R' D. R-NH-R' 34. Which of these generic structures denotes an ether? C. R-O-R' Е. RCH G. RCR A. R-CI В. R-OH D. R-NH-R' RCOH 35. Which of these generic structures denotes an amine? E. RCH F. RCOH G. RCR A. R-CI В. R-OH C. R-O-R' D. R-NH-R' F.arrow_forward4. A student prepared an ester using a different alcohol and a different carboxylic acid than the one you used in lab: It H-C-C-C-OH H-C-C-Ċ -C-0H H H It butanoič acid H. propanol a. Draw the structural formula of the ester that formed. b. Name the esterarrow_forward
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