(a) Interpretation: The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms: Concept Introduction : To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom. The following table should be used while determining the shape around a carbon atom. Number of groups Number of atoms Number of lone pairs Shape Bond angle 2 2 0 Linear 180 ° C 3 3 0 Trigonal planar 120 ° C 4 4 0 Tetrahedral 109.5 ° C 4 3 1 Trigonal pyramidal 109.5 ° C 4 2 2 Bent 109.5 ° C

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Answer 1

Question

Chapter 11, Problem 25P

Interpretation Introduction

(a)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Interpretation Introduction

(b)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

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Pheromone G of the maize stalk borer, chilo partelus, can be synthesized based on the partial scheme shown below. Complete the scheme by identifying the structures of the intermediate compounds A, B, C, D, E, F and pheromone G. Indicate stereochemistry where relevant

Answer 2

Question

Chapter 11, Problem 25P

Interpretation Introduction

(a)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Interpretation Introduction

(b)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

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Answer 3

Question

Chapter 11, Problem 25P

Interpretation Introduction

(a)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Interpretation Introduction

(b)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

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Answer 4

Question

Chapter 11, Problem 25P

Interpretation Introduction

(a)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Interpretation Introduction

(b)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

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Answer 5

Chapter 11, Problem 25P

Interpretation Introduction

(a)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Interpretation Introduction

(b)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Answer 6

Chapter 11, Problem 25P

Interpretation Introduction

(a)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Answer 7

Chapter 11, Problem 25P

Interpretation Introduction

(a)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Answer 8

Interpretation Introduction

(b)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Answer 9

Interpretation Introduction

(b)

Interpretation:

The shape around the indicated atoms in the following compound should be determined and the lone pairs should be added to the heteroatoms:

Concept Introduction:

To add lone pair to an atom, first find the valence electron of the particular atom. After that find how many electrons are used in bond formation and then put the remaining valence electron on that particular atom.

The following table should be used while determining the shape around a carbon atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11.1 - Prob. 11.1P Ch. 11.2 - Fill in all H's and lone pairs in each compound.Ch. 11.3 - Prob. 11.2PP Ch. 11.3 - Prob. 11.2P Ch. 11.3 - Prob. 11.3P Ch. 11.3 - Prob. 11.3PP Ch. 11.3 - How many lone pairs are present in lidocaine, the...Ch. 11.4 - Convert each compound to a condensed formula.Ch. 11.4 - Convert each condensed formula to a complete...Ch. 11.4 - Convert each skeletal structure to a complete...

Solution Summary: The author explains how lone pairs should be added to the heteroatoms.

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Chapter 11 Solutions

Number of groups	Number of atoms	Number of lone pairs	Shape	Bond angle
2	2	0	Linear	180 °C
3	3	0	Trigonal planar	120 °C
4	4	0	Tetrahedral	109.5 °C
4	3	1	Trigonal pyramidal	109.5 °C
4	2	2	Bent	109.5 °C