
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Question
Chapter 11, Problem 11.61SP
Interpretation Introduction
Interpretation:
The molarity of the given solution has to be calculated.
Concept introduction:
The concentration of solution can be defined in terms of molarity as the moles of the solute to the volume of the solution.
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Give reason(s) for six from the followings [using equations if possible] a. Addition of sodium carbonate to sulfanilic acid in the Methyl Orange preparation. b. What happened if the diazotization reaction gets warmed up by mistake. c. Addition of sodium nitrite in acidified solution in MO preparation through the diazotization d. Using sodium dithionite dihydrate in the second step for Luminol preparation. e. In nitroaniline preparation, addition of the acid mixture (nitric acid and sulfuric acid) to the product of step I. f. What is the main reason of the acylation step in nitroaniline preparation g. Heating under reflux. h. Fusion of an organic compound with sodium.
HAND WRITTEN PLEASE
edict the major products of the following organic reaction:
u
A
+
?
CN
Some important notes:
• Draw the major product, or products, of the reaction in the drawing area below.
• If there aren't any products, because no reaction will take place, check the box below the drawing area instead.
Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
Explanation
Check
Click and drag to start drawing a structure.
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© 2025 McGraw Hill LLC. All Rights Reserved. Te
LMUNDARY
Sketch the intermediates for A,B,C & D.
Chapter 11 Solutions
General Chemistry: Atoms First
Ch. 11.2 - Arrange the following compounds in order of their...Ch. 11.2 - Which would you expect to have the larger (more...Ch. 11.3 - Prob. 11.3PCh. 11.3 - Prob. 11.4PCh. 11.3 - Prob. 11.5PCh. 11.3 - Prob. 11.6PCh. 11.3 - Prob. 11.7PCh. 11.3 - Prob. 11.8PCh. 11.3 - Prob. 11.9PCh. 11.3 - Prob. 11.10P
Ch. 11.4 - Prob. 11.11PCh. 11.4 - Prob. 11.12PCh. 11.6 - Prob. 11.13PCh. 11.6 - How many grams of NaBr must be added to 250 g of...Ch. 11.6 - The following diagram shows a close-up view of...Ch. 11.6 - (a) What is the vapor pressure in mm Hg of a...Ch. 11.6 - The following phase diagram shows part of the...Ch. 11.7 - What is the normal boiling point in C of a...Ch. 11.7 - What is the freezing point in C of a solution...Ch. 11.7 - Assuming complete dissociation, what is the...Ch. 11.7 - When 9.12 g of HCl was dissolved in 190 g of...Ch. 11.7 - The following phase diagram shows a close-up view...Ch. 11.8 - What osmotic pressure in atmospheres would you...Ch. 11.8 - A solution of an unknown substance in water at 300...Ch. 11.9 - A solution of 0.250 g of naphthalene (mothballs)...Ch. 11.9 - What is the molar mass of sucrose (table sugar) if...Ch. 11.10 - What is the difference between a dialysis membrane...Ch. 11 - The following phase diagram shows part of the...Ch. 11 - Prob. 11.30CPCh. 11 - The following diagram shows a close-up view of...Ch. 11 - Prob. 11.32CPCh. 11 - Prob. 11.33CPCh. 11 - Prob. 11.34CPCh. 11 - A phase diagram of temperature versus composition...Ch. 11 - The following phase diagram shows a very small...Ch. 11 - Prob. 11.38SPCh. 11 - Prob. 11.39SPCh. 11 - Prob. 11.40SPCh. 11 - Prob. 11.41SPCh. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Prob. 11.45SPCh. 11 - Prob. 11.46SPCh. 11 - Prob. 11.47SPCh. 11 - Prob. 11.48SPCh. 11 - Prob. 11.49SPCh. 11 - Prob. 11.50SPCh. 11 - Prob. 11.51SPCh. 11 - Prob. 11.52SPCh. 11 - Which of the following solutions has the higher...Ch. 11 - What is the mass percent concentration of the...Ch. 11 - Prob. 11.55SPCh. 11 - Prob. 11.56SPCh. 11 - Prob. 11.57SPCh. 11 - Prob. 11.58SPCh. 11 - Prob. 11.59SPCh. 11 - Prob. 11.60SPCh. 11 - Prob. 11.61SPCh. 11 - Prob. 11.62SPCh. 11 - Prob. 11.63SPCh. 11 - Prob. 11.64SPCh. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SPCh. 11 - Prob. 11.67SPCh. 11 - Prob. 11.68SPCh. 11 - Look at the solubility graph in Figure 11.6, and...Ch. 11 - Vinyl chloride (H2CCHCl), the starting material...Ch. 11 - Prob. 11.71SPCh. 11 - Prob. 11.72SPCh. 11 - Prob. 11.73SPCh. 11 - Sulfur hexafluoride, which is used as a...Ch. 11 - Prob. 11.75SPCh. 11 - Prob. 11.76SPCh. 11 - Prob. 11.77SPCh. 11 - Draw a phase diagram showing how the phase...Ch. 11 - Prob. 11.79SPCh. 11 - Prob. 11.80SPCh. 11 - Prob. 11.81SPCh. 11 - What is the boiling point in C of each of the...Ch. 11 - Prob. 11.83SPCh. 11 - Prob. 11.84SPCh. 11 - The vant Hoff factor for KCl is i = 1.85. What is...Ch. 11 - Heptane (C7H16) and octane (C8H18) are...Ch. 11 - Prob. 11.87SPCh. 11 - Acetone, C3H6O, and ethyl acetate, C4H8O2, are...Ch. 11 - The industrial solvents chloroform, CHCl3, and...Ch. 11 - What is the mole fraction of each component in the...Ch. 11 - Prob. 11.91SPCh. 11 - Prob. 11.92SPCh. 11 - Prob. 11.93SPCh. 11 - A solution of citric acid, C6H8O7, in 50.0 g of...Ch. 11 - What is the normal boiling point in C of ethyl...Ch. 11 - Prob. 11.96SPCh. 11 - Prob. 11.97SPCh. 11 - Prob. 11.98SPCh. 11 - Prob. 11.99SPCh. 11 - When salt is spread on snow-covered roads at 2 C,...Ch. 11 - Prob. 11.101SPCh. 11 - Prob. 11.102SPCh. 11 - Prob. 11.103SPCh. 11 - Prob. 11.104SPCh. 11 - Prob. 11.105SPCh. 11 - Prob. 11.106SPCh. 11 - Prob. 11.107SPCh. 11 - Prob. 11.108CHPCh. 11 - Prob. 11.109CHPCh. 11 - Prob. 11.110CHPCh. 11 - Silver chloride has a solubility of 0.007 mg/mL in...Ch. 11 - Prob. 11.112CHPCh. 11 - Prob. 11.113CHPCh. 11 - Prob. 11.114CHPCh. 11 - Prob. 11.115CHPCh. 11 - Prob. 11.116CHPCh. 11 - Prob. 11.117CHPCh. 11 - Rubbing alcohol is a 90 mass % solution of...Ch. 11 - Prob. 11.119CHPCh. 11 - Prob. 11.120CHPCh. 11 - What is the vant Hoff factor for K2SO4 in an...Ch. 11 - If the vant Hoff factor for LiCl in a 0.62 m...Ch. 11 - Prob. 11.123CHPCh. 11 - Prob. 11.124CHPCh. 11 - Many acids are partially dissociated into ions in...Ch. 11 - Prob. 11.126CHPCh. 11 - Prob. 11.127CHPCh. 11 - A solution of LiCl in a mixture of water and...Ch. 11 - Prob. 11.129CHPCh. 11 - Prob. 11.130CHPCh. 11 - Prob. 11.131CHPCh. 11 - Prob. 11.132CHPCh. 11 - Prob. 11.133CHPCh. 11 - Prob. 11.134CHPCh. 11 - Prob. 11.135CHPCh. 11 - A solution prepared by dissolving 100.0 g of a...Ch. 11 - Treatment of 1.385 g of an unknown metal M with an...Ch. 11 - A compound that contains only C and H was burned...Ch. 11 - Prob. 11.139MPCh. 11 - When 8.900 g of a mixture of an alkali metal...Ch. 11 - Prob. 11.141MP
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- Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? O ? A . If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. . If your answer is no, check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. ㅇ 80 F5 F6 A 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Cente FIGarrow_forwardIn methyl orange preparation, if the reaction started with 0.5 mole of sulfanilic acid to form the diazonium salt of this compound and then it converted to methyl orange [0.2 mole]. If the efficiency of the second step was 50%, Calculate: A. Equation(s) of Methyl Orange synthesis: Diazotization and coupling reactions. B. How much diazonium salt was formed in this reaction? C. The efficiency percentage of the diazotization reaction D. Efficiency percentage of the whole reaction.arrow_forwardHand written equations pleasearrow_forward
- Hand written equations pleasearrow_forward> each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that: 1. the rate of substitution doesn't depend on nucleophile concentration and 2. the products are a roughly 50/50 mixture of enantiomers. Substrate A Substrate B Faster Rate X Ś CI (Choose one) (Choose one) CI Br Explanation Check Br (Choose one) © 2025 McGraw Hill LLC. All Rights Farrow_forwardNMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at 4.1 ppm? Select the single best answer. The H O HỌC—C—0—CH, CH, 2 A ethyl acetate H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm Check OA B OC ch B C Save For Later Submit Ass © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center |arrow_forward
- How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red Note for advanced students: In this question, any multiplet is counted as one signal. 1 Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. Check For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. O ✓ No additional Hs to color in top molecule ง No additional Hs to color in bottom…arrow_forwardin the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstantarrow_forwardtrue or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY