(a) Interpretation: The detailed mechanism for the given reaction, with major product, is to be drawn. Concept introduction: The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

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Answer 1

Question

Chapter 11, Problem 11.37P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

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9.26 Explain in detail how you would distinguish between the following sets of compounds using the indicated method of spectroscopy. 1H NMR 13 C and 1H NMR 13C NMR

9.21 How many 13C NMR signals would you predict for each of the compounds shown in Problem 9.20? OH Br OH

Answer 2

Question

Chapter 11, Problem 11.37P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

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Answer 3

Question

Chapter 11, Problem 11.37P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

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Answer 4

Question

Chapter 11, Problem 11.37P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

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Answer 5

Chapter 11, Problem 11.37P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Answer 6

Chapter 11, Problem 11.37P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Answer 7

Chapter 11, Problem 11.37P

Interpretation Introduction

(a)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The detailed mechanism for the given reaction, with major product, is to be drawn.

Concept introduction:

The alkynes are electron rich system like alkenes and can undergo electrophilic addition reaction with strong Bronsted acids just like the alkenes do. The reaction proceeds with proton transfer reaction to form a stable carbocation, followed by the action of water as a nucleophile. In excess of reagent, the reaction occurs twice, forming a geminal dihalide compound as a major product.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains the detailed mechanism for the given reaction, with major product, by showing the formation of stable carbocations and the vinylic chloride product.

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