Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
2nd Edition
ISBN: 9780393655551
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter 11, Problem 11.49P
Interpretation Introduction

Interpretation:

The mechanism for the biosynthesis of γ-curcumene from farnesyl pyrophosphate is to be drawn.

Concept introduction:

Many natural products like essential oils and steroids are terpenes or terpenoids. These contain a carbon backbone made up of isoprene units linked by the terminal carbons. An isoprene unit has the same carbon backbone as 2-methylbutane. The synthesis of many terpenes starts with an isoprene unit attached to a pyrophosphate ion. The addition of another isoprene unit gives the ten carbon geranyl pyrophosphate. This can react in a number of ways to produce different terpenes

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Chapter 11 Solutions

Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

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