(a) Interpretation: How the given compound can be synthesized from two different alkenes is to be shown. Concept introduction: Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Question

Practice: Draw all possible products using the reagents on the previous page 1+ DH H₂O* HBr, ROOR 1) Hg(OAc)2. H₂O 2) NaBH HR HX 1) O 2) DMS 1) OsO 1) BH, ⚫ THF 2) H₂O₂, NaOH PL H₁₂O⭑ HBr. ROOR 1) Hg(OAc)2. H₂O 2) NaBH4 1) BH₁ - THF 2) H₂O₂, NaOH Brz 2) NaHSO H₂O KMnO4 NaOH, cold 1) RCO₂H 2) H₂O* Br₂, H₂O na 1) O 1) OsO 2) DMS bro HX 2) NaHSO H₂O KMnO4 fa Bra NaOH, cold 1) RCO₂H 2) H₂O* Br₂, H₂O 11.5 not

Answer 1

Question

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

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Practice: Draw all possible products using the reagents on the previous page 1+ DH H₂O* HBr, ROOR 1) Hg(OAc)2. H₂O 2) NaBH HR HX 1) O 2) DMS 1) OsO 1) BH, ⚫ THF 2) H₂O₂, NaOH PL H₁₂O⭑ HBr. ROOR 1) Hg(OAc)2. H₂O 2) NaBH4 1) BH₁ - THF 2) H₂O₂, NaOH Brz 2) NaHSO H₂O KMnO4 NaOH, cold 1) RCO₂H 2) H₂O* Br₂, H₂O na 1) O 1) OsO 2) DMS bro HX 2) NaHSO H₂O KMnO4 fa Bra NaOH, cold 1) RCO₂H 2) H₂O* Br₂, H₂O 11.5 not

Please correct answer and don't used hand raiting

Identify the indicated sets of protons as unrelated, homotopic, enantiotopic, or diastereotopic. H HA

Answer 2

Question

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

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Answer 3

Question

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

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Answer 4

Question

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

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Answer 5

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 6

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 7

Chapter 11, Problem 11.5P

Interpretation Introduction

(a)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 8

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 9

Interpretation Introduction

(b)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 10

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 11

Interpretation Introduction

(c)

Interpretation:

How the given compound can be synthesized from two different alkenes is to be shown.

Concept introduction:

Bronsted acids add across a C - C double bond. The mechanism involves the electrophilic addition of the acid’s proton to the electron-rich π bond in step one. The proton adds to the less substituted carbon of the initial double bond so that the most substituted, and hence, the most stable carbocation forms. Step two is a coordination step in which the conjugate base forms a bond to the carbocation. The major product of an electrophilic addition of a Bronsted acid to an alkene is the one that proceeds through the more stable carbocation intermediate.

Answer 12

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Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains how Bronsted acids add across a C - C double bond. The proton adds to the less substituted carbon of the initial bond so that the most stable carboc

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