Interpretation:
The general mechanistic acronym that represents the given reaction at the best has to be described.
Concept Introduction:
Oxidation of alcohols: Oxidation of primary alcohol gives an
Oxidation of alcohols by
E2 reaction: In the reaction, a base abstract a proton, forcing the electrons to make a double bond and the leaving group leaves the substrate simultaneously.
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Organic Chemistry
- There are two mechanisms by which each of the C1 atoms in the following molecule can be replaced by another group: ⚫ Mechanism 1: The C1 atom can be replaced with a concerted, bimolecular step. Mechanism 2: The C1 atom can be replaced in several steps, the slowest of which is unimolecular. Highlight in red the C1 atom that would be replaced the fastest if the reaction went Mechanism 1. Highlight in blue the C1 atom that would be replaced the fastest if the reaction went Mechanism 2. If you would choose the same C1 to be replaced fastest by both mechanisms, highlight it in green instead. C1 cl. C1arrow_forward2-Chloro-2-methylpropane reacts with water in three steps to yield 2- methyl-2-propanol. The first step is slower than the second, which in turn is much slower than the third. The reaction takes place slowly at room temperature, and the equilibrium constant is approximately 1. a. Give approximate values for ΔG and ΔG° that are consistent with the above information. b. Draw an energy diagram for the reaction, labeling all points of interest and making sure that the relative energy levels on the diagram are consistent with the informationarrow_forwardchemistry drawing questions need helparrow_forward
- Consider the following overall reaction that uses liquid acetone (CH;COCH3) as a reactant to produce a compound with two different functional groups. The reaction follows this mechanism: 2 f.,,.e f.....f .. + H2O (1) + :OH 6.. :OH མེན་གྱིས་ འབུ་ ིམ་མི་ ོ་ ེ་ ི་ ་ :OH What is true for the first step in the this mechanism? O AH > o ( Endothermic) AH o ( Exothermic)arrow_forward5. Classify the following reagents as either nucleophiles or electrophiles: Zn2* , CH3NH2 , HS , OH2 , CH3COOH, H2SO4arrow_forwardSECTION 6: Show the mechanism of each reactions with arrows and intermediates form as in a. b. C. HBr Br₂ Cl₂, H₂O Br Br CI Br OHarrow_forward
- Provide the mechanism and products of the reactionsarrow_forward0. What is the difference between general acid-base catalysis and specific acid-base catalysis? (Assume that the solvent is water.)arrow_forward2. The bromination of 2-butene is an exergonic reaction. Br H3C. Br2 CH3 CH3 Br a. Draw the mechanism for the reaction (you may ignore the stereochemistry for this question). b. In the mechanism drawn above, identify any intermediates. C. How many transition states are involved in the above mechanism? Without drawing the transition state(s), indicate where they occur in the mechanism. d. Which of the following reaction co-ordinate diagrams best illustrates this reaction? Explain briefly. On the diagram, draw the structures of the reactants, products and intermediates at the correct locations on the diagram and indicate which position(s) correspond to the transition state(s). Page 18 of 19 EYRERIMENT 7: BROMINATION OF CINNAMIC ACID WINTER 2022arrow_forward
- The conversion of acetyl chloride to methyl acetate occurs via the following two-step mechanism: a.Add curved arrows to show the movement of the electrons in each step. b.Write the rate equation for this reaction, assuming the first step is ratedetermining. c.If the concentration of −OCH3 were increased 10 times, what would happen to the rate of the reaction? d.If the concentrations of both CH3COCl and −OCH3 were increased 10 times, what would happen to the rate of the reaction? e.Classify the conversion of acetyl chloride to methyl acetate as an addition, elimination, or substitution.arrow_forward19. Which of the following represents the transition state of the rate-determining step in the SN1 reaction between tert-butyl chloride and water? (see attached screenshot) A. 1 B. 2 C. 3 D. 4arrow_forwardConsider the following two-step reaction: a.How many bonds are broken and formed in Step [1]? Would you predict the ΔHo of Step [1] to be positive or negative? b.How many bonds are broken and formed in Step [2]? Would you predict the ΔHo of Step [2] to be positive or negative? c.Which step is rate-determining? d.Draw the structure for the transition state in both steps of the mechanism. e.If ΔHooverall is negative for this two-step reaction, draw an energy diagram illustrating all of the information in parts (a)–(d).arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning