![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9781305580350/9781305580350_largeCoverImage.gif)
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 10, Problem 10.24P
The decalinols A and B can be equilibrated using aluminum isopropoxide in 2-propanol (isopropyl alcohol) containing a small amount of acetone.
Assuming a value of ΔG0 (equatorial to axial) for cyclohexanol is 4.0 kJ (0.95 kcal)/mol, calculate the percent of each decalinol in the equilibrium mixture at 25°C.
Expert Solution & Answer
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Students have asked these similar questions
The reaction
N2O4−⇀↽−2NO2
is allowed to reach equilibrium in a chloroform solution at 25 ∘C . The equilibrium concentrations are 0.327 mol/L N2O4 and 1.91 mol/L NO2 .
Calculate the equilibrium constant, Kc , for this reaction.
Kc= 11.16
An additional 1.00 mol NO2 is added to 1.00 L of the solution and the system is allowed to reach equilibrium again at the same temperature. Select the direction of the equilibrium shift after the NO2 is added.
towards the product
towards the reactant
no change
Determine how the addition of extra NO2 in the previous step will affect the rate constant, Kc .
Kc will increase
Kc will not change
Kc will decrease
Calculate the equilibrium concentrations of N2O4 and NO2 after the extra 1.00 mol NO2 is added to 1.00 L of solution.
[N2O4]=
mol/L
[NO2]=
mol/L
Express the equilibrium constant for the
following reaction.
2 CH 2C12 (g) +H2 (g)
2 CH 3C1(g) +C12 (g)
[CH 2C12][H2]
[CH 3CI][Cl2]
(CH2C12]?{H2]
к
[CH3C1]2[Cl2]
(CH3C1]?{C12]
[CH 2C12]2[H2]
[CH 3CI][Cl2]
K
[CH 2C12][H2]
[CH3C1]1/2{Cl2]
к
%3D
[CH2C121/2на
Acetaldehyde (CH3CHO) is an important chemical both industrially and biologically. For instance, it is a (somewhat toxic) intermediate in the body's metabolism of ethanol into acetic acid, and thus is possibly implicated in the "hungover" symptoms of someone who has had too much to drink the night before. In aqueous solution, it establishes an equilibrium with a hydrated form, shown below.
CH3CHO (aq) + H2O (l) <--> CH3CH(OH)2 (aq)
You start with an aqueous sample, already at equilibrium, with the CH3CH(OH)2 (the hydrated form) at a concentration of 2.60 M. You have no information about how much, if any, of the anhydrous form (CH3CHO) is initially in the flask. If you add 2.0 M of CH3CHO to the reaction flask, and as the equilibrium is being restored the amount of CH3CH(OH)2 changes by 1.13 M, what is the final amount of CH3CHO?
Chapter 10 Solutions
Organic Chemistry
Ch. 10.1 - Write IUPAC names for these alcohols and include...Ch. 10.1 - Classify each alcohol as primary, secondary, or...Ch. 10.1 - Write IUPAC names for these unsaturated alcohols.Ch. 10.2 - Arrange these compounds in order of increasing...Ch. 10.2 - Prob. 10.5PCh. 10.4 - Predict the position of equilibrium for this...Ch. 10.5 - Show how to convert (R)-2-pentanol to...Ch. 10.6 - Draw structural formulas for the alkenes formed by...Ch. 10.6 - Propose a mechanism to account for this...Ch. 10.7 - Propose a mechanism to account for the following...
Ch. 10.7 - Prob. AQCh. 10.7 - Prob. BQCh. 10.7 - Prob. CQCh. 10.7 - Prob. DQCh. 10.7 - Which step in the reaction would you expect to be...Ch. 10.7 - Prob. FQCh. 10.7 - Prob. GQCh. 10.8 - Prob. 10.11PCh. 10.8 - Prob. AQCh. 10.8 - Prob. BQCh. 10.8 - Prob. CQCh. 10.8 - Why does nature use a reagent as complex as NAD+...Ch. 10.8 - -Hydroxyketones and -hydroxyaldehydes are also...Ch. 10.9 - Write IUPAC names for these thiols.Ch. 10 - Which are secondary alcohols?Ch. 10 - Name each compound.Ch. 10 - Prob. 10.16PCh. 10 - Name and draw structural formulas for the eight...Ch. 10 - Arrange these compounds in order of increasing...Ch. 10 - Arrange these compounds in order of increasing...Ch. 10 - Prob. 10.20PCh. 10 - Prob. 10.21PCh. 10 - Arrange the compounds in each set in order of...Ch. 10 - Prob. 10.23PCh. 10 - The decalinols A and B can be equilibrated using...Ch. 10 - Prob. 10.25PCh. 10 - Select the stronger acid from each pair and...Ch. 10 - Prob. 10.27PCh. 10 - In each equilibrium, label the stronger acid, the...Ch. 10 - Write equations for the reaction of 1-butanol with...Ch. 10 - Write equations for the reaction of 2-butanol with...Ch. 10 - Prob. 10.31PCh. 10 - When (R)-2-butanol is left standing in aqueous...Ch. 10 - Two diastereomeric sets of enantiomers, A/B and...Ch. 10 - Acid-catalyzed dehydration of 3-methyl-2-butanol...Ch. 10 - Show how you might bring about the following...Ch. 10 - Propose a mechanism for the following pinacol...Ch. 10 - Prob. 10.37PCh. 10 - Show how each alcohol or diol can be prepared from...Ch. 10 - Dihydropyran is synthesized by treating...Ch. 10 - Show how to convert propene to each of these...Ch. 10 - Prob. 10.41PCh. 10 - Prob. 10.42PCh. 10 - The tosylate of a primary alcohol normally...Ch. 10 - Prob. 10.44PCh. 10 - Show how to convert cyclohexene to each compound...Ch. 10 - Prob. 10.46PCh. 10 - Ethanol (CH3CH2OH) and dimethyl ether (CH3OCH3)...Ch. 10 - Prob. 10.48PCh. 10 - Prob. 10.49PCh. 10 - Prob. 10.50PCh. 10 - Write the products of the following sequences of...Ch. 10 - Alcohols are important for organic synthesis,...Ch. 10 - Using your reaction roadmap as a guide, show how...Ch. 10 - Using your reaction roadmap as a guide, show how...Ch. 10 - Using your reaction roadmap as a guide, show how...Ch. 10 - Using your reaction roadmap as a guide, show how...Ch. 10 - Prob. 10.57PCh. 10 - Prob. 10.58PCh. 10 - Prob. 10.59P
Additional Science Textbook Solutions
Find more solutions based on key concepts
What is the pH range for acidic solutions? For basic solutions?
EBK INTRODUCTION TO CHEMISTRY
Draw a Lewis structure for each of the following species: a. H2CO3 b. CO32 c. CH2O d. CO2
Essential Organic Chemistry (3rd Edition)
Consider a sample of ideal gas initially in a volume V at temperature T and pressure P. Does the entropy of thi...
General Chemistry: Principles and Modern Applications (11th Edition)
Q2. Which statement best defines chemistry?
a. The science that studies solvents, drugs, and insecticides
b. Th...
Introductory Chemistry (5th Edition) (Standalone Book)
Calculate the lattice energy of CaCl2 using a Born-Haber cycle and data from Appendices F and L and Table 7.5. ...
Chemistry & Chemical Reactivity
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A2.arrow_forwardConsider the following equilibrium reaction: 2 CH3OH + CH2O ⇌CH2(OCH3)2+ H2O ΔH = + 46 indicate the direction that the equilibrium will shift when the following changes are made.(No states are provided because the solvent for the reaction is not water, so aq for aqueous would not be appropriate.) (a)Concentration of CH3OH increases (b)H2O is removed from the reaction (c)Reaction is heatedarrow_forward3. Answer all sections (i) - (iv). 1 mole of ethanol (C2H5OH) and 1 mole of ethanoic acid (CH;COOH) were reacted at 25 °C, in a non- aqueous solvent, until equilibrium was reached. It was subsequently determined that 0.33 moles of ethanol remained at equilibrium. (i) Write an equation for the reaction. (ii) Write an expression for the equilibrium constant, Kc, for the reaction and calculate its value. Subsequently a further 3 moles of C2H5OH was added to the solution. (ii) Determine the concentrations of all the species present when equilibrium is restored.arrow_forward
- Kc=?arrow_forwardBe sure to answer all parts.The equilibrium constant (K) for the formation of nitrosyl chloride, an orange-yellow compound, from nitric oxide and molecular chlorine 2NO(g) + Cl,(g)= 2NOCI(g) is 5 x 10° at a certain temperature. In an experiment, 2.10 × 10-2 mole of NO, 2.10 x 10-3 mole of Cl, and 2.80 moles of NOCI are mixed in a 2.20-L flask. What is Q, for the experiment? × 10 (Enter your answer in scientific notation.) In which direction will the system proceed to reach equilibrium? The reaction will proceed to the left. The reaction will proceed to the right. The reaction is at equilibrium.arrow_forwardCS2 (g) + 4 H2 (g) <====> CH4 (g) + 2 H2S (g) Calculate the value of Keq if the equilibrium concentrations are [CS2] = 0.140, [H2] = 0.250, [CH4] = 0.0200, and [H2S] = 0.0400.arrow_forward
- Be sure to answer all parts. Consider the formation of ammonia in two experiments. (a) To a 1.00-L container at 727°C, 1.30 mol of N₂ and 1.65 mol of H₂ are added. At equilibrium, 0.100 mol of NH3 is present. Calculate the equilibrium concentrations of N₂ and H₂ and find Ke for the reaction: [N₂ leq = [H₂ leq 2 NH3(g) = N₂(g) + 3 H₂(g) Kc = ㅈ = M Kc = (b) In a different 1.00-L container at the same temperature, equilibrium is established with -2 8.34 × 10² mol of NH3, 1.50 mol of N2, and 1.25 mol of H₂ present. Calculate Ke for the reaction: M 3 NH3(g) = N₂(g) + H₂(g) 2 2 C C < Prev *********** 18 of 20 MacBook Pro Search or type URL Next *********** ☆arrow_forwardConsider the following reaction: 2CH₂Cl₂ (9) ⇒ CH4 (9) + CCl4 (9) If 0.436 moles of CH₂ Cl2 (g), 0.335 moles of CH4, and 0.406 moles of CC14 are at equilibrium in a 17.4 L container at 599 K, the value of the equilibrium constant, Ke, isarrow_forward3. In the following reaction, acetic acid and ethanol react together to form ethyl ethanoate and water. Use the following concentrations under equilibrium to calculate the equilibrium constant, K. CH,COOH (I) + CH,CH,OH (1) = CH,COOC,H¿(1) + H,O (1) Species Concentration (mol dm) CH;CH,OH 0.30 CH;COOH 0.13 H,0 0.39 CH,COOC,H; 0.39arrow_forward
- Be sure to answer all parts. The equilibrium constant (K) for the formation of nitrosyl chloride, an orange-yellow compound, from nitric oxide and molecular chlorine 2NO(g) + Cl₂(g) = 2NOCI(g) is 5 × 105 at a certain temperature. In an experiment, 8.40 × 102 mole of NO, 2.10 × 10-3 mole of Cl₂, and 7.60 moles of NOCI are mixed in a 1.10-L flask. What is Qe for the experiment? 9.823 (Enter your answer in scientific notation.) In which direction will the system proceed to reach equilibrium? The reaction is at equilibrium. O The reaction will proceed to the left. The reaction will proceed to the right.arrow_forwardCalculate K'p for the following reaction: 3CH3OH(g) 3CO(g) + 6H2(g)arrow_forward4 (a) Calculate the value of Kc for the reaction: PC15 ( PC13 ( + Cl2 (g) AH = Positive Given that when 8.4 mol of PC15 (g) is mixed with 1.8 mol of PC13 (g) and allowed to come to equilibrium in a 10 dm³ container the amount of PC15 (g) at equilibrium is 7.2 mol. Kc = (b) Explain the effect of the following changes below on the value of Kc: (i) Increasing temperature (ii) Lowering the concentration of chlorine (Cl₂) (iii) Addition of a catalystarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
![Text book image](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Chemical Equilibria and Reaction Quotients; Author: Professor Dave Explains;https://www.youtube.com/watch?v=1GiZzCzmO5Q;License: Standard YouTube License, CC-BY