Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 10.8, Problem DQ
Why does nature use a reagent as complex as NAD+ to perform an oxidation?
- 1. Nature binds the oxidizing agent in an enzyme in proximity to the alcohol being oxidized.
- 2. Nature cannot use strong bases in an aqueous environment.
- 3. Nature cannot use toxic heavy metals.
- 4. All of the above are true.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Why are antioxidants important to the body?
O They increase the likelihood of cancer.
O They slow the oxidation process.
They help to break down glucose.
O They help blood flow.
1. Secondary structures of proteins are held
together by hydrogen bonding
Select one:
a. from one a-amino groups of the protein
backbone to another a-amino group of the
protein backbone.
b. between a-amino groups and carbonyl
groups of the protein backbone.
c. from one carbonyl group of the protein
backbone to another carbonyl group of the
protein backbone.
d. between side chain R groups.
2. What is the primary organic product of
oxidation of the following molecule?
Select one:
a. 4-methyl-2-hexanone
b. 4-methyl-2-hexanal
C. 4-methyl-2-hexanoic acid
d. No reaction
Consider the molecule shown below. Which statement is FALSE?
H
H
HO
H-
CHO
-OH
-OH
-H
-OH
CH₂OH
This is an aldohexose.
This is a D isomer
This molecule has five chiral carbons.
This is a monosaccharide.
Humans can easily digest this compound.
Chapter 10 Solutions
Organic Chemistry
Ch. 10.1 - Write IUPAC names for these alcohols and include...Ch. 10.1 - Classify each alcohol as primary, secondary, or...Ch. 10.1 - Write IUPAC names for these unsaturated alcohols.Ch. 10.2 - Arrange these compounds in order of increasing...Ch. 10.2 - Prob. 10.5PCh. 10.4 - Predict the position of equilibrium for this...Ch. 10.5 - Show how to convert (R)-2-pentanol to...Ch. 10.6 - Draw structural formulas for the alkenes formed by...Ch. 10.6 - Propose a mechanism to account for this...Ch. 10.7 - Propose a mechanism to account for the following...
Ch. 10.7 - Prob. AQCh. 10.7 - Prob. BQCh. 10.7 - Prob. CQCh. 10.7 - Prob. DQCh. 10.7 - Which step in the reaction would you expect to be...Ch. 10.7 - Prob. FQCh. 10.7 - Prob. GQCh. 10.8 - Prob. 10.11PCh. 10.8 - Prob. AQCh. 10.8 - Prob. BQCh. 10.8 - Prob. CQCh. 10.8 - Why does nature use a reagent as complex as NAD+...Ch. 10.8 - -Hydroxyketones and -hydroxyaldehydes are also...Ch. 10.9 - Write IUPAC names for these thiols.Ch. 10 - Which are secondary alcohols?Ch. 10 - Name each compound.Ch. 10 - Prob. 10.16PCh. 10 - Name and draw structural formulas for the eight...Ch. 10 - Arrange these compounds in order of increasing...Ch. 10 - Arrange these compounds in order of increasing...Ch. 10 - Prob. 10.20PCh. 10 - Prob. 10.21PCh. 10 - Arrange the compounds in each set in order of...Ch. 10 - Prob. 10.23PCh. 10 - The decalinols A and B can be equilibrated using...Ch. 10 - Prob. 10.25PCh. 10 - Select the stronger acid from each pair and...Ch. 10 - Prob. 10.27PCh. 10 - In each equilibrium, label the stronger acid, the...Ch. 10 - Write equations for the reaction of 1-butanol with...Ch. 10 - Write equations for the reaction of 2-butanol with...Ch. 10 - Prob. 10.31PCh. 10 - When (R)-2-butanol is left standing in aqueous...Ch. 10 - Two diastereomeric sets of enantiomers, A/B and...Ch. 10 - Acid-catalyzed dehydration of 3-methyl-2-butanol...Ch. 10 - Show how you might bring about the following...Ch. 10 - Propose a mechanism for the following pinacol...Ch. 10 - Prob. 10.37PCh. 10 - Show how each alcohol or diol can be prepared from...Ch. 10 - Dihydropyran is synthesized by treating...Ch. 10 - Show how to convert propene to each of these...Ch. 10 - Prob. 10.41PCh. 10 - Prob. 10.42PCh. 10 - The tosylate of a primary alcohol normally...Ch. 10 - Prob. 10.44PCh. 10 - Show how to convert cyclohexene to each compound...Ch. 10 - Prob. 10.46PCh. 10 - Ethanol (CH3CH2OH) and dimethyl ether (CH3OCH3)...Ch. 10 - Prob. 10.48PCh. 10 - Prob. 10.49PCh. 10 - Prob. 10.50PCh. 10 - Write the products of the following sequences of...Ch. 10 - Alcohols are important for organic synthesis,...Ch. 10 - Using your reaction roadmap as a guide, show how...Ch. 10 - Using your reaction roadmap as a guide, show how...Ch. 10 - Using your reaction roadmap as a guide, show how...Ch. 10 - Using your reaction roadmap as a guide, show how...Ch. 10 - Prob. 10.57PCh. 10 - Prob. 10.58PCh. 10 - Prob. 10.59P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What is the basis for deciding if a substance is a lipid?arrow_forward1. what reaction is cl2/hu in a chemical equation?2. what is the flourinating agent used in the synthesis of sevoflurane?arrow_forwardC12H22O11 + H2O → C6H12O6 What type of reaction is this? Is the lactose to glucose reaction a redox reaction?arrow_forward
- 22 The oxidation of glucose with a weak oxidizing agent (Benedict) results in the formation of a primary alcohol on carbon #1 (CH,OH) a carboxylic acid at carbon #6 (COOH) O a bydrogenated carbon at carbon #1 (CH,OH) a carboxylic acid at carbon #1 (COOH) a carboxylic acid at both carbons #1 and #6 (COOH)arrow_forwardDetermine whether the statements are true or false and could you please leave a short explanation in order for me to understand? Thank you so much! 1. Vitamins are useful in the body in great amounts.2. Vitamins don't have a common sturcture3. There is one type of vitamin B.4. Vitamin D is usually found in citrus fruits.5. There are vitamins that can be produced by the skin with the aid of sunlight.6. Vitamin K can solve fertility problems.7. Some vitamins can be synthesized by the human body.8. Before taking multivitamins, consultation with a doctor is important.9. All vitamins are water-soluble.10. Too much vitamins may be toxic to the body.arrow_forwardWhat is the principle employed in the test for glucose? A. Reduction of glucose oxidizes another metabolite that gives the color reaction. B. Oxidation of hydroxyl groups to aldehyde changes its property resulting in the absorption of light in the visible range of wavelengths. C. Oxidation of carbonyl carbons causes it to change the wavelength at which the carbonyl compound absorbs maximally. D. Oxidation of glucose reduces the electron receiver converting it to another compound responsible for the color reaction. E. Glucose has carbonyl carbons and hydroxyl groups that react with specific reagents to give a colored product.arrow_forward
- Take a look at this molecule, and then answer the questions in the table below it. OH CH₂OH -I 5. H HOCH2 H H OH H OH H O H Is this a reducing sugar? H OH H OH Does this molecule contain a glycosidic bond? If you said this molecule does contain a glycosidic bond, write the symbol describing it. yes If you said this molecule does contain a glycosidic bond, write the common names (including anomer and enantiomer labels) of the molecules that would be released if that bond were hydrolyzed. 0 If there's more than one molecule, separate each name with a comma. no yes no 0-0arrow_forwardChapter 8- Carbohydrates (pages 221 - 223) 1. What are carbohydrates and what are the three elements that make them up? What is the general formula of carbohydrates? 2. One of the simplest carbohydrate is glyceraldehyde. Glyceraldehyde (number of carbons) carbon sugar. is a 3. Draw the structure of D-glyceraldehyde (Fig. 8-1, page 222) in the space below. 4. Monosaccharides can be aldoses or ketoses, depending on the position of the carbonyl group. Describe aldoses and ketoses: a. Aldoses: H b. Ketoses*: *IMPORTANT NOTE: The most common ketoses have the ketone function at carbon 2. 5. Circle the carbonyl group in the structures below and specify if the structures correspond to an aldose or ketoses. CH₂OH H-C-OH CH₂OH C=O 1 CH₂OHarrow_forwardWhat do amino acids, fatty acids, and sugars (monosaccharides) have in common? O They are used to make lipids. O They are made of carbon, oxygen, and hydrogen. O They are used to make proteins. O They are made of carbon, oxygen, and nitrogen.arrow_forward
- The process of extraction of plant starch seems to be simpler than that of the glycogen. Give an explanation for such difference?arrow_forwardIdentify the organic functional groups and reaction type for the following reaction.The reactant is a(n)a. ketohexoseb. alcohol hexosec. aldohexosed. carboxylic acid pentosee. deoxyhexoseThe product is a(n)a. alcohol pyranosesb. etherc. ester d. hemiacetals (anomers)e. acetals (disaccharide)The reaction type is:a. hemiacetal formationb. mutarotationc. hydrolysisd. oxidation (benedict's)e. hemiacetal formationf. reduction (hydrogenation)arrow_forwardPRODUCTS. Match the name of the product with the biochemical reaction. Products may be used more than once. Tests may require more than one answer.a. 2,3-butanediol 1.catalase b. ammonia 2.phenylalanine deamination c.fatty acids 3.triglyceride hydrolysis d. indole 4.tryptophan degradation e.molecular oxygen 5.urea hydrolysis f. phenylpyruvic acid 6.Voges-Proskauer testarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Introduction to Coordination ComplexesWave Function for Hydrogen atom # All Vital Topics # Quantum Mechanics part -21; Author: Priyanka Jain;https://www.youtube.com/watch?v=GKgNV9dmUHo;License: Standard YouTube License, CC-BY
CBSE Class 12 Chemistry || The d & f Block Elements Part 1 || Full Chapter || By Shiksha House; Author: Best for NEET;https://www.youtube.com/watch?v=LzZWHSdYaxw;License: Standard Youtube License