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Interpretation:
Chemist is testing by running the reaction when different R groups on each alcohol carbons are used; the correct statement has to be identified.
Concept Introduction:
Pinacol rearrangement: For all glycols Pinacol rearrangement occurs. Unsymmetrical vicinal
Step 1: Add proton (protonation of Pinacol using acid catalyst).
Step 2: Break a bond to give a stable molecules or ions (formation of carbocation).
Step 3: 1, 2-shift (migration of substituent from
Step 4: deprotonation occurs (take a proton away).
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Chapter 10 Solutions
Organic Chemistry
- Part 1. TRUE or FALSE.Choose A if the statement is true. Choose D if the statement is false. 1. Based on a technical definition, acids are classified as nucleophiles. 2. A nucleophile is any atom or molecule which can attack positively or partially positively charged molecules or atoms. 3. Covalent bonds are directional due to repulsion of orbitals. 4. All compounds which contain carbon are classified as organic compounds. 5. The density of an organic compound is influenced by the type of chemical bond present in the compound. 6. Vitalism proposes that living organisms formed from non-living things. 7. Urea, which has been successfully synthesized in the laboratory, has the chemical formula CO2N2H4. 8. The possible mathematical values of p-orbital are: p, pz and p. 9. The ability of carbon atoms to link with each other is termed catenation. 10. Pi bonds are occupied by a maximum of two electrons. 11. Organic chemistry studies carbon atom in the context of atomic properties. 12.…arrow_forwardKINDLY HELP ME WITH THIS PROBLEM MULTIPLE CHOICE THANK YOU !arrow_forwardCan you please help me out with this problemarrow_forward
- Consider the reaction below to answer the following questions. HÇI HO H,0 HO a. The first nucleophile in the reaction is b. The catalyst in the reaction is c. The newly created functional group in the reaction is called a(n) d. The first step in the reaction mechanism is protonation of the group. e. The last step in the reaction mechanism is of the oxonium ion.arrow_forwardCan you please give an explanation for question 5 (A, B, and C)? 5 continues on the 2nd page. Thank youarrow_forwardComplete the following acid-base reactions.arrow_forward
- 78) Why are primary alcohols more acidic than tertiary alcohols, in general? Because tertiary alcohols have less acidic hydrogens. Because primary alcohols have less electron-donating groups which create more effective charge separation between oxygen and hydrogen atom, making it more acidic. Because primary alcohols are more polar than tertiary alcohols. Because primary alcohols have less electron-donating groups which decrease electron density on oxygen, making it more susceptible for H+ to depart from the structure.arrow_forwardComplete each acid-base reaction and predict whether the position of equilibrium lies toward the left or toward the right. (a) CH3CCH+CH3CH2ONa+CH3CH3OH (b) CH3CCCH2CH2OH+Na+NH2NH3(l)arrow_forwardPlease answer 6,7,8arrow_forward
- After separating the acidic and neutral compounds in a mixture, how does one recover the neutral compound from the organic solution that it is in? O 1) Treat with HCl until acidic to precipitate the neutral compound as a solid. Heat the solution on a hot plate to evaporate the organic solvent and recover O 2) the neutral compound as a solid. Wave a magic wand and speak the spell of recovery to get the neutral O 3) compound as a solid. You don't need to recover the neutral compound as a soild, toss out the O4) organic solution and clean up the lab.arrow_forwardGives five reactions that Methyl Salicylate can go through. (Name each of the reactions). The structure of Methyl Salicylate is attached.arrow_forwardHello, my Organic Chemistry 1 question is shown in the attached image.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
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