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Concept explainers
(a)
Interpretation:
The product formed in the reaction of 1-Hexanol with chromic acid has to be drawn.
Concept Introduction:
Oxidation of alcohols: Oxidation of primary alcohol gives an
Chromic acid Oxidation of an Alcohol:
Step 1: Reaction of alcohol and chromic acid gives an alkyl chromate. No change in oxidation state of both Carbon and Chromium.
Step 2: Take a proton away and simultaneously break bonds to give stable molecules or ions. Reaction of the alkyl chromate with a base (here water molecule) results in cleavage of a
(b)
Interpretation:
The product formed in the reaction of 2-Hexanol with chromic acid has to be drawn.
Concept Introduction:
Oxidation of alcohols: Oxidation of primary alcohol gives an aldehyde or a carboxylic acid, depending on experimental conditions.
Chromic acid Oxidation of an Alcohol:
Step 1: Reaction of alcohol and chromic acid gives an alkyl chromate. No change in oxidation state of both Carbon and Chromium.
Step 2: Take a proton away and simultaneously break bonds to give stable molecules or ions. Reaction of the alkyl chromate with a base (here water molecule) results in cleavage of a
(c)
Interpretation:
The product formed in the reaction of Cyclohexanol with chromic acid has to be drawn.
Concept Introduction:
Oxidation of alcohols: Oxidation of primary alcohol gives an aldehyde or a carboxylic acid, depending on experimental conditions.
Chromic acid Oxidation of an Alcohol:
Step 1: Reaction of alcohol and chromic acid gives an alkyl chromate. No change in oxidation state of both Carbon and Chromium.
Step 2: Take a proton away and simultaneously break bonds to give stable molecules or ions. Reaction of the alkyl chromate with a base (here water molecule) results in cleavage of a
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Chapter 10 Solutions
Organic Chemistry
- Draw the structures that correspond to their IUPAC or common name. (c) 4-mercapto-1-butanol (d) trans-1,3-diethoxycyclopentanearrow_forward4. Which of the following has a higher boiling point? Explain your answer:(a) 2-propanol or 2-butanol(b) Dimethyl ether or ethanolarrow_forward2. Draw one enol tautomer of each of the following ketones and aldehydes. a) b) c) of مل G Harrow_forward
- The cis ketone A is isomerized to a trans ketone B with aqueous NaOH. A similar isomerization does not occur with ketone C. (a) Draw the structure of B using a chair cyclohexane. (b) Label the substituents in C as cis or trans, and explain the difference in reactivity.arrow_forwardFor each pair of compounds, predict which compound has a higher boiling point. then explain why that compound has a higher boiling point. (a) isopropyl bromide and n-butyl bromide (b) isopropyl chloride and tert-butyl bromide (c) 1-bromobutane and 1-chlorobutanearrow_forward6. Show how the following alcohols below can be distinguished. a) butanol and 2- butanol b) 2-propanol and 3- hexanolarrow_forward
- Arrange these compounds in order of increasing boiling point (values in °C are -42, -24, 78, and 118). (a) CH,CH,OH (b) CH,OCH, (c) CH,CH,CH, (d) CH,COOHarrow_forward6. Show how to prepare each compound from 2-methyl-1-propanol. (a) 2-Methylpropene (b) 2-Methyl-2-propanol (c) 2-Methylpropanoic acidarrow_forwardGive the IUPAC name for each compound (a)-(e)arrow_forward
- 1).For each of the following, draw one structural formula that meets all stated requirements, then name each structure you drew according to either IUPAC or common nomenclature.arrow_forwardDraw the structure of the following compounds all showing C and H atoms.(a) 2-methyl -3-iso propyl heptanes(b) Dicyclopropyl methane.arrow_forwardProvide the classification (alcohol or ether) and provide the correct IUPAC name of each molecule. CH3 H3C. ОН b) Namena 1a) Classification: CH3 H3C. b) Namena 2a) Classification: CH3 H3C CH3 b) Nameina 3a) Classification: CH3 H3C он b) Namena 4a) Classification: CI H3C. CH3 OH ÓH CI b) Namena 5a) Classification:arrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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