One reaction involved in the sequence of reactions leading to the destruction of ozone is NO 2 ( g ) +O ( g ) → NO ( g ) +O 2 ( g ) Calculate Δ r H ° for this reaction by using the thermodynamic data in Appendix D. Use your Δ r H ° value, plus data from Table 10.3, to estimate the nitrogen-oxygen bond energy in N O 2 . (Hint: The structure of nitrogen dioxide, N O 2 , is best represented as a resonance hybrid of two equivalent Lewis structures.)
One reaction involved in the sequence of reactions leading to the destruction of ozone is NO 2 ( g ) +O ( g ) → NO ( g ) +O 2 ( g ) Calculate Δ r H ° for this reaction by using the thermodynamic data in Appendix D. Use your Δ r H ° value, plus data from Table 10.3, to estimate the nitrogen-oxygen bond energy in N O 2 . (Hint: The structure of nitrogen dioxide, N O 2 , is best represented as a resonance hybrid of two equivalent Lewis structures.)
Solution Summary: The author explains how the nitrogen-oxygen bond energy should be estimated based on Hess's law.
One reaction involved in the sequence of reactions leading to the destruction of ozone is
NO
2
(
g
)
+O
(
g
)
→
NO
(
g
)
+O
2
(
g
)
Calculate
Δ
r
H
°
for this reaction by using the thermodynamic data in Appendix D. Use your
Δ
r
H
°
value, plus data from Table 10.3, to estimate the nitrogen-oxygen bond energy in
N
O
2
. (Hint: The structure of nitrogen dioxide,
N
O
2
, is best represented as a resonance hybrid of two equivalent Lewis structures.)
Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.
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6. Consider the following exothermic reaction below.
2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq)
a. If Cul is added, there will be a shift left/shift right/no shift (circle one).
b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one).
c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one).
d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle
one). Hint: one of the reaction species is more soluble in hexane than in water.
e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one).
f. Which of the changes above will change the equilibrium constant, K?
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Chapter 10 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
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