General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 10, Problem 102IAE
Interpretation Introduction
(a)
Interpretation:
Need to criticize the statement “Lewis structures with formal charges are incorrect.”
Concept introduction:
Lewis structures with formal charges are not incorrect.
Interpretation Introduction
(b)
Interpretation:
Need to criticize the statement “triatomic molecules have a planer shape.”
Concept introduction:
Triatomic molecules do not have a planer shape.
Interpretation Introduction
(c)
Interpretation:
Need to criticize the statement “Molecules in which there is an electronegativity difference between the bonded atoms are polar.”
Concept introduction:
Molecules in which there is an electronegativity difference between the bonded atoms are not always polar.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The element sulphur has atomic number 16. Sulphur forms a molecular compound with chloride with a molecular formula SCl2. The atomic number of chlorine is 17.
a. Write down the electronic configuration of a sulphur atom and a chlorine atom.
b. Draw a Lewis structure of an SCl2 molecule, by showing the electrons in the outer shells of the atoms.
c. State how many bond pairs and lone pairs of electrons are arranged around the sulphur atoms in SCl2 molecule.
d. Sketch the shape and state the molecular geometry of SCl2 molecule.
e. Explain the hybridisation of the central atom in SCl2 molecule.
f.Explain the intermolecular forces exists in SCl2 molecule.
Question 39 and 40 are two different questions.
With regard to resonance structures that are drawn for a real species, which of
the following statements is NOT TRUE?
Select one:
A. Resonance structures differ in the location of their electrons, not the
positions of their atoms.
B. Resonance structures are only drawings; each structure alone does
not represent an existing molecule.
O C. Resonance structures are real molecules that co-exist in equilibrium
with each other.
O D. Resonance structures all have electron localized structures, while
the real species that is described by them has delocalized electrons.
Chapter 10 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 10 - Write Lewis symbols for the following atoms. (a)...Ch. 10 - Write Lewis symbols for the following ions. (a)...Ch. 10 - Write plausible Lewis structures for the following...Ch. 10 - Each of the following molecules contains at least...Ch. 10 - By means of Lewis structures, represent bonding...Ch. 10 - Which of the following have Lewis structures that...Ch. 10 - Prob. 7ECh. 10 - Suggest reasons why the following do not exist as...Ch. 10 - Describe what is wrong with each of the following...Ch. 10 - Describe what is wrong with each of the following...
Ch. 10 - Prob. 11ECh. 10 - Indicate what is wrong with each of the following...Ch. 10 - Write Lewis structures for the following ionic...Ch. 10 - Under appropriate conditions, both hydrogen and...Ch. 10 - Derive the correct formulas for the following...Ch. 10 - Each of the following ionic compounds consists of...Ch. 10 - Assign formal charges to each of the atoms in the...Ch. 10 - Assign formal charges to each of the atoms in the...Ch. 10 - Both oxidation state and formal charge involve...Ch. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Assign formal charges to the atoms in the...Ch. 10 - Prob. 23ECh. 10 - Show that the idea of minimizing the formal...Ch. 10 - Write acceptable Lewis structures for the...Ch. 10 - Two molecules that have the same formulas but...Ch. 10 - The following polyatomic anions involve covalent...Ch. 10 - Represent the following ionic compounds by Lewis...Ch. 10 - Write a plausible Lewis structure for...Ch. 10 - Prob. 30ECh. 10 - Write Lewis structures for the molecules...Ch. 10 - Write Lewis structures for the molecules...Ch. 10 - Write Lewis structures for the molecules...Ch. 10 - Write Lewis structures for the molecules...Ch. 10 - Identify the main group that the element X belongs...Ch. 10 - Prob. 36ECh. 10 - Use your knowledge of electronegativities, but do...Ch. 10 - Which of the blowing molecules would you expect to...Ch. 10 - What is the percent ionic character of each of the...Ch. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Use a cross-base arrow () to represent the...Ch. 10 - Which electrostatic potential map corresponds to...Ch. 10 - Prob. 44ECh. 10 - Two electrostatic potential maps are shown, one...Ch. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Which of the following species requires a...Ch. 10 - Dinitrogen oxide (nitrous oxide, or "laughing...Ch. 10 - The Lewis structure of nitric acid, HONO2, is a...Ch. 10 - Draw Lewis structures for the following species,...Ch. 10 - Draw Lewis structures for the following species,...Ch. 10 - Write plausible Lewis structures for the following...Ch. 10 - Write plausible Lewis structures for the following...Ch. 10 - Which of the following species would you expect to...Ch. 10 - Write a plausible Lewis structure for NO2 , and...Ch. 10 - In which of the following species is it necessary...Ch. 10 - Prob. 58ECh. 10 - Use VSEPR theory to predict the geometric shapes...Ch. 10 - Use VSEPR theory to predict the geometric shapes...Ch. 10 - Each of the following is either linear, angular...Ch. 10 - Predict the geometric shapes of (a) CO ; (b)...Ch. 10 - One of the following ions has a trigonal-planer...Ch. 10 - Two of the following have the same shape. Which...Ch. 10 - Prob. 65ECh. 10 - Sketch the probable geometric shape of molecule of...Ch. 10 - Use the VSEPR theory to predict the shapes of the...Ch. 10 - Use the VSEPR theory to predict the shape of (a)...Ch. 10 - The molecular shape of BF2 is planar (see Table...Ch. 10 - Explain why it is not necessary to find the Lewis...Ch. 10 - Comment on the similarities and differences in the...Ch. 10 - Comment on the similarities and differences in the...Ch. 10 - Draw a plausible Lewis structure for the following...Ch. 10 - Draw a plausible Lewis structure for the following...Ch. 10 - Sketch the propyne molecule, CH2CCH. Indicate the...Ch. 10 - Sketch the propene molecule, CH2CHCH2. Indicate...Ch. 10 - Lactic acid has the formula CH2CH(OH)COOH. Sketch...Ch. 10 - Levulinic acid has the formula CH2(CO)CH2CH2COOH....Ch. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - Predict the shapes of the following molecules, and...Ch. 10 - Which of the blowing molecules would you expect to...Ch. 10 - The molecule H2O2 has a resultant dipole moment of...Ch. 10 - Prob. 84ECh. 10 - Without referring to tables in the text, indicate...Ch. 10 - Estimate the lengths of the blowing bonds and...Ch. 10 - A relationship between bond lengths and...Ch. 10 - In which of the following molecules would you...Ch. 10 - Prob. 89ECh. 10 - Prob. 90ECh. 10 - A reaction involved in the formation of ozone the...Ch. 10 - Use data from Table 10.3, but without performing...Ch. 10 - Use data from Table 10.3 to estimate the enthalpy...Ch. 10 - One of the chemical reactions that occurs in the...Ch. 10 - Estimate the standard enthalpies of formation at...Ch. 10 - Prob. 96ECh. 10 - Use bond energies from Table 10.3 to estimate rH...Ch. 10 - Equations (1) end (2) can be combined to yield the...Ch. 10 - One reaction involved in the sequence of reactions...Ch. 10 - Prob. 100ECh. 10 - Given the bond-dissociation energies:...Ch. 10 - Prob. 102IAECh. 10 - Prob. 103IAECh. 10 - Prob. 104IAECh. 10 - Prob. 105IAECh. 10 - Draw Lewis structures for two different molecules...Ch. 10 - Sodium azide, NaN2 is the nitrogen gas-forming...Ch. 10 - Prob. 108IAECh. 10 - Prob. 109IAECh. 10 - A few years ago the synthesis of a salt containing...Ch. 10 - Prob. 111IAECh. 10 - In certain polar solvents, PCI, undergoes an...Ch. 10 - Prob. 113IAECh. 10 - Prob. 114IAECh. 10 - Use the VSEPR theory to predict a probable shape...Ch. 10 - The standard enthalpy of formation of...Ch. 10 - Prob. 117IAECh. 10 - Prob. 118IAECh. 10 - Prob. 119IAECh. 10 - R. S. Mulliken proposed that the electronegativity...Ch. 10 - When molten sulfur reacts with chlorine gas, a...Ch. 10 - Hydrogen azide, HN2 , can exist in two forms. One...Ch. 10 - Prob. 123IAECh. 10 - Prob. 124IAECh. 10 - Prob. 125IAECh. 10 - One of the allotropes of sulfur is a ring of eight...Ch. 10 - One of the allotropes of phosphorus consists of...Ch. 10 - In this problem, we examine the basis of three...Ch. 10 - Prob. 129FPCh. 10 - Prob. 130FPCh. 10 - Prob. 131SAECh. 10 - Briefly describe each of the following ideas: (a)...Ch. 10 - Explain the important distinctions between (a)...Ch. 10 - Prob. 134SAECh. 10 - The formal charges on the O atoms in the ion...Ch. 10 - Which molecule is nonlinear?...Ch. 10 - Which molecule is nonpolar?...Ch. 10 - The highest bond-dissociation energy is found in...Ch. 10 - The greatest bond length is found in...Ch. 10 - Draw plausible Lewis structures for the blowing...Ch. 10 - Predict the shapes of the following...Ch. 10 - Which of the following ionic compounds is composed...Ch. 10 - Which of the following molecules does not obey the...Ch. 10 - Which of the following molecules has no polar...Ch. 10 - The electron-group geometry of H2O is (a)...Ch. 10 - For each of the following compounds, give the...Ch. 10 - Use bond enthalpies from Table 10.3 to determine...Ch. 10 - Prob. 148SAECh. 10 - Prob. 149SAECh. 10 - What is the VSEPR theory? On what physical basis...Ch. 10 - Prob. 151SAECh. 10 - Prob. 152SAECh. 10 - Prob. 153SAECh. 10 - Prob. 154SAE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What is the most polar bond in the molecule?arrow_forwardIn the Lewis structure for chloromethane, the chlorine atom is sharing _____ electron pair and “owns” _____ of those electrons. Also, the chlorine atom possesses two electrons from each of _____ unshared pairs. The total number of electrons that belong to chlorine is 7 . Chlorine is a Group ____ element. The formal charge on chlorine in chloromethane is ____.arrow_forwardWhy do covalent bonds form? 1. Because atoms always want to share electrons. II. Because electrons from one atom are attracted to the nucleus of another atom. III. Because the formation of a bond results in a stable system that would require the input of energy to change. IV. Because atoms always want an octet of electrons around them. 1. I only 2. II and IV 3. Ill only 4. I and II 5. II and III O O O O 1 3 2 5 4arrow_forward
- Choose the INCORRECT statement. Select one: a. The central atom is typically the atom with the highest electronegativity. b. Resonance is when more than one equally plausible structure can be written c. In a molecule, hydrogen and halogen atoms are always at terminal positions d. In a Lewis structure, the number of valence electrons shown is one more for each negative charge. e. Formal charges are apparent charges associated with atoms in a Lewis structure.arrow_forwardUse the References to access important values if needed for this question Draw (on paper) a Lewis structure for XeOF4 and answer the following questions based on your drawing. 1. For the central xenon atom: The number of lone pairs %3D The number of single bonds The number of double bonds 2. The central xenon atom A. obeys the octet rule. B. has an inccnplete octet. C. has an expanded octet. Submit Answer 5 question attempts remainingarrow_forwardGive detailed Solution with explanation neededarrow_forward
- Which statement(s) is/are true about the use of the images? Image 1 A. Only statement I is correct. B Statements I and II are correct. Image 2 1. Image 1 depicts a nonpolar molecule. II. Image 2 depicts a polar molecule. III. Atom B in both has a greater charge density than atom A. IV. Atom A in both images would likely have a smaller electronegativity value than atom B. C. Statements I and III are correct. D. Statements I and IV are correct. A Barrow_forwardA. State the Octet Rule.B. Write the Lewis symbol of neon. Is the neon atom stable? Does neon exist as atoms in nature? If not, how does neon exist in nature.C. Write the Lewis symbol of nitrogen. Is the nitrogen atom stable? Does nitrogen exist as atoms in nature? If not, how does nitrogen exist in nature.arrow_forwardDraw a Lewis structure for SO2 that obeys the octet rule if possible and answer the following questions based on your drawing. 1. For the central sulfur atom: - The number of lone pairs = ? - The number of single bonds = ? - The number of double bonds = ? 2. The central sulfur atom a. obeys the octet rule. b. has an incomplete octet. c. has an expanded octet.arrow_forward
- The element sulphur has atomic number 16. Sulphur forms a molecular compound with chloride with a molecular formula SCl2. The atomic number of chlorine is 17. 1. Write down the electronic configuration of a sulphur atom and a chlorine atom. 2. Draw a Lewis structure of an SCl2 molecule, by showing the electrons in the outer shells of the atoms. 3. State how many bond pairs and lone pairs of electrons are arranged around the sulphur atoms in SCl2 molecule. 4. Sketch the shape and state the molecular geometry of SCl2 molecule. 5. Explain the hybridisation of the central atom in SCl2 molecule. 6.Explain the intermolecular forces exists in SCl2 molecule.arrow_forwardStarting with question 8arrow_forwardWhen molecules absorb heat, there is an increase in A) the kinetic energy of the molecules. B) The potential energy of the molecules. C) The mass of the molecules. D) The bond energy of the molecules.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Types of bonds; Author: Edspira;https://www.youtube.com/watch?v=Jj0V01Arebk;License: Standard YouTube License, CC-BY