The phenomenon of resonance in nitrite ion ( NO 2 - ) with the help of Lewis strictures should be shown. Concept introduction: Resonance is a set consists of two or more than two Lewis structure of the same molecule. It shows the equivalent structure having fractional bonds and fractional charges. Two resonance structures have the same number of atoms and electrons but the arrangement of atoms can be different. These different equivalent structures obtained after shifting of the double bond in the ring. The shifting of double bonds takes place due to the shifting of electrons in it. A group which is linked to the aromatic ring may results either in withdrawing or releasing of electrons in the ring which produces the resonating structure by shifting the double bonds.
The phenomenon of resonance in nitrite ion ( NO 2 - ) with the help of Lewis strictures should be shown. Concept introduction: Resonance is a set consists of two or more than two Lewis structure of the same molecule. It shows the equivalent structure having fractional bonds and fractional charges. Two resonance structures have the same number of atoms and electrons but the arrangement of atoms can be different. These different equivalent structures obtained after shifting of the double bond in the ring. The shifting of double bonds takes place due to the shifting of electrons in it. A group which is linked to the aromatic ring may results either in withdrawing or releasing of electrons in the ring which produces the resonating structure by shifting the double bonds.
Solution Summary: The author explains the phenomenon of resonance in nitrite ion with the help of Lewis strictures.
Definition Definition Organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Aromatic organic compounds, also called arenes, are an important class of hydrocarbons under the branch of organic chemistry.
Chapter 10, Problem 47E
Interpretation Introduction
Interpretation:
The phenomenon of resonance in nitrite ion ( NO2- ) with the help of Lewis strictures should be shown.
Concept introduction:
Resonance is a set consists of two or more than two Lewis structure of the same molecule. It shows the equivalent structure having fractional bonds and fractional charges. Two resonance structures have the same number of atoms and electrons but the arrangement of atoms can be different.
These different equivalent structures obtained after shifting of the double bond in the ring. The shifting of double bonds takes place due to the shifting of electrons in it.
A group which is linked to the aromatic ring may results either in withdrawing or releasing of electrons in the ring which produces the resonating structure by shifting the double bonds.
3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting
material (SM) into the Target molecule. For each FGI in your proposed synthesis,
specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT
INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent
sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O;
ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI.
FGI 1.
Me
Starting Material
Source of all carbons
in the Target molecule
(can use multiple copies)
Me
Me
Target molecule
+ enantiomer
curved arrows are used to illustate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction mechanism steps
Chapter 10 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
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