The phenomenon of resonance in nitrite ion ( NO 2 - ) with the help of Lewis strictures should be shown. Concept introduction: Resonance is a set consists of two or more than two Lewis structure of the same molecule. It shows the equivalent structure having fractional bonds and fractional charges. Two resonance structures have the same number of atoms and electrons but the arrangement of atoms can be different. These different equivalent structures obtained after shifting of the double bond in the ring. The shifting of double bonds takes place due to the shifting of electrons in it. A group which is linked to the aromatic ring may results either in withdrawing or releasing of electrons in the ring which produces the resonating structure by shifting the double bonds.
The phenomenon of resonance in nitrite ion ( NO 2 - ) with the help of Lewis strictures should be shown. Concept introduction: Resonance is a set consists of two or more than two Lewis structure of the same molecule. It shows the equivalent structure having fractional bonds and fractional charges. Two resonance structures have the same number of atoms and electrons but the arrangement of atoms can be different. These different equivalent structures obtained after shifting of the double bond in the ring. The shifting of double bonds takes place due to the shifting of electrons in it. A group which is linked to the aromatic ring may results either in withdrawing or releasing of electrons in the ring which produces the resonating structure by shifting the double bonds.
Solution Summary: The author explains the phenomenon of resonance in nitrite ion with the help of Lewis strictures.
Definition Definition Organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Aromatic organic compounds, also called arenes, are an important class of hydrocarbons under the branch of organic chemistry.
Chapter 10, Problem 47E
Interpretation Introduction
Interpretation:
The phenomenon of resonance in nitrite ion ( NO2- ) with the help of Lewis strictures should be shown.
Concept introduction:
Resonance is a set consists of two or more than two Lewis structure of the same molecule. It shows the equivalent structure having fractional bonds and fractional charges. Two resonance structures have the same number of atoms and electrons but the arrangement of atoms can be different.
These different equivalent structures obtained after shifting of the double bond in the ring. The shifting of double bonds takes place due to the shifting of electrons in it.
A group which is linked to the aromatic ring may results either in withdrawing or releasing of electrons in the ring which produces the resonating structure by shifting the double bonds.
Some chemists believe that satisfaction of the octet rule should be the top criterion
for choosing the dominant Lewis structure of a molecule or ion. Other chemists
believe that achieving the best formal charges should be the top criterion.
Consider the dihydrogen phosphate ion, HaPO, , in which the H atoms are bonded
to O atoms. (a) What is the predicted dominant Lewis structure if satisfying the
octet rule is the top eriterion? (b) What is the predicted dominant Lewis structure if
achieving the best formal charges is the top criterion?
In the nitrite ion (NO₂), Consider the implications of resonance.
Draw Lewis diagrams for the following ions. In the formula the symbol of the central atom is given first. (Hint:The valence octet may be expanded for the central atom.)(a) BrO4 - (b) PCl6 - (c) XeF6+
Chapter 10 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
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